金属表面硫酸盐还原菌微生物膜内的反应影响金属腐蚀的机理和速度,杀灭膜内微生物是控制微生物膜腐蚀金属的重要措施.采用丝束电极技术,研究了油田污水中生物膜在Q345碳钢表面的生长规律;通过投加3种杀菌剂来灭杀生物膜内细菌,并对其杀菌效果进行了比较,获得了杀菌剂对细菌的抑制周期及最低有效浓度.结果表明:油田污水中微生物首先在Q345碳钢表面大量附着、生长,至216 h时生长完整,至360 h时开始脱落;生物膜对Q345钢的腐蚀呈现不均匀性,微生物的存在可在局部范围内降低Q345碳钢表面的腐蚀电流密度,但有促进其腐蚀的倾向;杀菌剂H GY-B1的杀菌效果优于KD-24及LC-3,投添加量为300 mg/L时,对生物膜内细菌抑制周期可达8d,最低杀菌浓度为40 mg/L.
参考文献
[1] | 岳建平,王玉春,杨暹.油田污水中硫酸盐还原菌腐蚀研究[J].榆林学院学报,2006(02):15-17. |
[2] | Hubert C;Nemati M;Jenneman G et al.Corrosion risk associated with microbial souring control using nitrate or nitrite[J].Applied Microbiology and Biotechnolody,2005,68(02):272-282. |
[3] | Licina G J;Carnery C S.Monitoring biofilm formation and incipient MIC in real time[A].San Antonio:NACE Intemational,1999:175-189. |
[4] | Franklin M J;White D C;Isaacs H S .Pitting corrosion by bacteria on carbon steel determined by the scanning vibrating electrode technique[J].Corrosion Science,1991,32(09):945-952. |
[5] | 刘靖.采用丝束电极研究硫酸盐还原菌生物膜的电化学不均匀匀性[J].腐蚀与防护,2001(08):325-327,366. |
[6] | ZeHD;WeiS;HongM R et al.Heterogeneous corrosion of mild steel under SRB-biofilm characterized by electrochemical mapping technique[J].Corrosion Science,2011,53(09):2978-2987. |
[7] | 刘宏芳,黄玲,刘涛,胡裕龙.硫酸盐还原菌杀菌剂应用现状及研究进展[J].中国腐蚀与防护学报,2009(02):154-160. |
[8] | Cord-Ruwisch R;Widdel F .Corroding iron as a hydrogen source for sulfate reduction in growing cultures of sulfate reducing bacteria[J].Applied Microbiology and Biotechnolody,1986,25(02):169-174. |
[9] | 刘靖,侯宝利,郑家燊,许立铭.硫酸盐还原菌腐蚀研究进展[J].材料保护,2001(08):8-11. |
[10] | 董泽华,郭兴蓬,刘宏芳,许立铭,郑家燊.用丝束电极研究SRB微生物诱导腐蚀的电化学特征[J].中国腐蚀与防护学报,2002(01):48-53. |
[11] | Daumas S;Massiani Y;Crosier J .Microbiological battery induced by sulfate reducing bacteria[J].British Corrosion Journal,1988,28(11):1041-1050. |
[12] | 董泽华,郭兴蓬,郑家,许立铭.用丝束电极研究16Mn钢的缝隙腐蚀行为[J].材料保护,2001(09):6-7,11. |
[13] | Sauer K;Camper AK;Ehrlich GD;Costerton JW;Davies DG .Pseudomonas aeruginosa displays multiple phenotypes during development as a biofilm[J].Journal of Bacteriology,2002(4):1140-1154. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%