合成了超分子化合物(C_(12)H_(10)N_4)(C_7H_6O_3)_2,并进行了元素分析、红外光谱、紫外光谱表征和单晶X射线衍射分析.构筑单元之间通过多重氢键和π-π堆积作用的协同效应形成超分子化合物,并研究了化合物的固体荧光性能.研究表明:该晶体属于单斜晶系P2_1/c空间群,晶胞参数为:a=0.3974(1) nm,b=2.0330(2) nm,c=1.4343(1) nm, β=94.892(2)°,V=1.15440(19) nm~3,d_c=1.400 g/cm~3,Z = 2,μ= 0.102 mm~(-1),F_((000))=508,R_1=0.0359,wR_2=0.0893 [I>2σ(I)].
A new supramolecular compound (C_(12)H_(10)N_4)(C_7H_6O_3)_2 was synthesized and characterized by elemental analysis, IR, UV spectroscopy and single-crystal X-ray diffraction. In the crystal structure, multiform hydrogen bonds and stacking interactions lead to a supramolecular compound. The luminescent properties of the compound in the solid state were investigated. The crystal belongs to monoclinic, space group P2_1/c with a=0.3974(1) nm, b=2.0330(2) nm, c=1.4343(1) nm, β=94.892(2)°, V=1.15440(19) nm~3, dc=1.400 g/cm~3,Z=2, μ=0.102 mm~(-1), F_((000))=508, R_1=0.0359, wR_2=0.0893 [I>2σ(I)].
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