Ni—ZrO_2复合镀层中界面轨道相互作用及析氢反应

材料研究学报, 1997, 11(2): 143-147.

Ni—ZrO_2复合镀层中界面轨道相互作用及析氢反应

天津大学

电子工业部第46研究所

关键词： Ni-ZrO_2复合镀层 , null , null , null , null

INTERFACIAL ORBITAL INTERACTION IN Ni-ZrO_2COMPOSITE PLATING AND HYDROGEN EVOLUTION REACTION

WANG Wei , GUO Hetong , GAO Jianping , QIN Qixiang (Tianjin University)REN Diansheng (46th Institute of Electronic Industry Ministry) , null

Keywords： Ni-ZrO_2 composite plating interfacial structure orbital interaction electrocatalysis hydrogen evolution , 界面结构 , 轨道相互作用 , 电催化 , 析氢

用XPS、UPS、ESR研究了Ni-ZrO_2复合层中基质金属Ni与ZrO_2微粒间的轨道相互作用,建立了相应的分子模型,并据此解释了Ni-ZrO_2镀层的析氢电催化活性的机制

The atomic orbital interaction existing in the interface between matrix metal Ni and ZrO_2 particles was investigated by XPS, UPS and ESR, and corresponding orbital interaction molecular model was proposed. The high electrocatalytical activity of Ni--ZrO2

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材料期刊网

Ni—ZrO_2复合镀层中界面轨道相互作用及析氢反应

INTERFACIAL ORBITAL INTERACTION IN Ni-ZrO_2COMPOSITE PLATING AND HYDROGEN EVOLUTION REACTION

参考文献