利用差示扫描量热法对汽车用AA6016铝合金板材中析出相的析出行为和激活能进行分析和计算.结果表明,在10/min加热速率条件下,自然时效态和预时效处理后状态强化相β"相析出温度约为265℃和250℃,析出激活能分别为(178.21 ±4.24)和(131.87±2.91) kJ/mol.对于预时效处理后的合金施加不同程度的变形,发现当预应变量为2%时,β"相析出温度为240℃左右,进一步增大变形至5%,强化相析出温度约为230℃.经计算,预应变量为0、2%和5%合金β"相析出激活能分别为(131.87±2.91),(134.81±3.45)和(128.47 ±3.67) kJ/mol,三者相差不大.
The precipitation behavior of AA6016 aluminum alloy sheets used in automotive industry was analyzed and calculated by differential scanning calorimetry technique.The result shows that the precipitation temperature of β" phase in the alloy after natural aging and pre-aging is about 265 ℃ and 250 ℃,and the activation energy is (178.21 ±4.24) and (131.87 ± 2.91) kJ/mol,respectively.The different amounts of deformation were applied to the alloy after pre-aging,and it is found that the precipitation temperature of β" phase is 240 ℃ when the deformation is 2%,and further increasing to 5%,the precipitation temperature of strengthening phase is about 230 ℃.According to the calculation,the precipitation activation energy of β" phase for the alloy with 0,2% and 5% deformation is (131.87 ± 2.91),(134.81 ± 3.45) and (128.47 ± 3.67) kJ/mol,respectively,no significant difference is observed.
参考文献
[1] | 马鸣图;李志刚;易红亮;向晓峰;方平.汽车轻量化及铝合金的应用[J].世界有色金属,2006(10):10-14. |
[2] | 刘静安;盛春磊;刘煜.铝材在汽车上的开发应用及重点新材料研发方向[J].轻合金加工技术,2012(10):9-18. |
[3] | 王祝堂;张新华.汽车用铝合金[J].轻合金加工技术,2011(2):1-14. |
[4] | Jtirgen Hirsch.Aluminium in Innovative Light-Weight Car Design[J].Materials transactions,20115(5):818-824. |
[5] | Y. Birol.Pre-aging to improve bake hardening in a twin-roll cast Al-Mg-Si alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20051/2(1/2):175-180. |
[6] | Birol, Y..Impact of pre-ageing on age hardening response of twin-belt cast AlMg1SiCu sheet[J].Journal of Materials Science,201024(24):6727-6731. |
[7] | 商宝川;尹志民;周向;黄志其.固溶-时效对6082合金挤压棒材组织性能的影响[J].材料热处理学报,2011(1):77-81. |
[8] | A. SERIZAWA;S. HIROSAWA;T. SATO.Three-Dimensional Atom Probe Characterization of Nanoclusters Responsible for Multistep Aging Behavior of an Al-Mg-Si Alloy[J].Metallurgical and materials transactions. A, physical metallurgy and materials science,20082(2):243-251. |
[9] | Chen SP.;van der Zwaag S.;Mussert KM..Precipitation kinetics in A16061 and in an A16061-alumina particle composite[J].Journal of Materials Science,199818(18):4477-4483. |
[10] | M.A. van Huis;J.H. Chen;H.W. Zandbergen.Phase stability and structural relations of nanometer-sized, matrix-embedded precipitate phases in Al-Mg-Si alloys in the late stages of evolution[J].Acta materialia,200611(11):2945-2955. |
[11] | 杨金龙;邓运来;祁小红;万里;张新明.过饱和7050铝合金固溶体中第二相粒子的析出动力学[J].中南大学学报(自然科学版),2012(7):2528-2533. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%