渗硫层能有效降低零件的摩擦系数,提高零件的抗擦伤性能和耐磨性能,但是单纯的低温离子渗硫不能保证特定工况的生产要求,选用其它处理技术与低温离子渗硫相结合的复合处理方法可以制得表层软、亚表层硬的理想固体自润滑涂层。综述了离子多元复合渗法( S-N, S-C-N, S-O, S-Mo),两步法(喷丸和超音速纳米化处理与低温离子渗硫、预置薄膜涂层与低温离子渗硫、激光处理技术与低温离子渗硫),以及多种复合处理技术相结合法的特点和部分应用实例,着重介绍了每种复合处理技术的工艺。针对目前复合处理技术在固体自润滑薄膜制备中存在的问题,提出复合处理技术的发展方向。
Sulfurizing layer can effectively decrease the coefficient of friction, improve the anti-scratch properties and wear re-sistance of the parts, but solely low-temperature ion sulphurization cannot guarantee to meet the production requirements of specific conditions, the composite processing method of other technologies and low-temperature ion sulfurization result in ideal solid self-lu-bricating coating with soft surface and hard subsurface, which meets the needs of the production environment. This paper reviewed the characteristics and part of the research instances for the ion multiple composite infiltration method ( S-N, S-C-N, S-O, S-Mo) , two-step method ( shot peening processing, supersonic nanocrystallization processing and low temperature ion sulphurization;preset film coating and low temperature ion sulphurization;laser processing technology and low temperature ion sulphurization) , combined method involving a variety of composite processing technologies. Each process of composite processing technology was introduced in detail. The direction of development of composite processing technology was suggested based on the current problems of complex processing techniques in self-lubricating solid preparation.
参考文献
| [1] | 康嘉杰 .复合渗硫层的微观组织和摩擦学性能研究[D].河北工业大学,2008. |
| [2] | 董从林,白秀琴,严新平,袁成清.海洋环境下的材料摩擦学研究进展与展望[J].摩擦学学报,2013(03):311-320. |
| [3] | 杨威锋.固体自润滑材料及其研究趋势[J].润滑与密封,2007(12):118-120,122. |
| [4] | 欧忠文,徐滨士,马世宁,史佩京,丁培道.磨损部件自修复原理与纳米润滑材料的自修复设计构思[J].表面技术,2001(06):47-49,53. |
| [5] | 付传起,王宙.石墨/铜铁基自润滑复合材料的摩擦学性能研究[J].表面技术,2010(04):11-14. |
| [6] | 高彩桥.金属的硬度与耐磨性的关系[J].机械工程师,1981:6-8. |
| [7] | 张宁 .低温离子渗硫层的组织结构、摩擦学性能及其机理的研究[D].清华大学,2000. |
| [8] | 温诗铸.材料磨损研究的进展与思考[J].摩擦学学报,2008(01):1-5. |
| [9] | Zhang Ning;Zhuang Da-Ming;Liu Jia-Jun;Fang Xiao-Dong;Guan Ming-Xi .Wear mechanism of ion-sulphurization layer on steel under dry conditions[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2001(1):1-8. |
| [10] | 张宁,庄大明,刘家浚,方晓东,官明喜.离子渗氮和离子渗硫复合处理表面的摩察学性能[J].中国表面工程,2000(02):18-22. |
| [11] | Zhang, N;Zhuang, DM;Liu, JJ .Tribological behaviors of steel surfaces treated with ion sulphurization duplex processes[J].Surface & Coatings Technology,2009(20/21):3173-3177. |
| [12] | 李忠伟,顾敏.离子硫氮复合渗42CrMo钢的耐磨性和抗咬合性研究[J].机械工程材料,2003(05):48-50. |
| [13] | 杜明英,向楠,朱张校,武庆兰,张欣.灰铸铁离子渗氮渗硫复合处理改性层的摩擦学性能[J].金属热处理,2005(05):12-15. |
| [14] | 车延岗,袁静静,刘沅东,马向东.35CrMo钢硫氮共渗层的摩擦学性能[J].材料保护,2010(08):25-28. |
| [15] | 齐宝森;陈路宾;王忠诚.化学热处理技术[M].北京:化学工业出版社,2006 |
| [16] | 张君,吴晓春.温度对Cr12MOV钢等离子S-N-C复合共渗渗层组织的影响[J].材料热处理学报,2005(03):100-102. |
| [17] | 何杰,马世宁,胡春华.大功率柴油机缸套减摩抗划伤技术研究[J].船舶工程,2006(02):5-8. |
| [18] | 胡春华,乔玉林,马世宁,邹家平,高月德,吴淼.渗硫参数对氮碳共渗表面形成FeS固体润滑层的影响[J].金属热处理,2006(11):13-15. |
| [19] | HU Chun-hua,乔玉林,MU Ying,张伟今,SUN Xiao-feng,孟鑫.FeS固体润滑复合层在锂基脂润滑条件下的摩擦磨损性能[J].中国表面工程,2008(04):45-48. |
| [20] | 江志华,佟小军,孙枫,李志,王子君,时连卫.复合化学热处理13Cr4M04Ni4VA钢摩擦磨损性能研究[J].航空材料学报,2011(04):39-44. |
| [21] | 王海斗,庄大明,王昆林,刘家浚.高速钢离子渗硫层的摩擦磨损性能研究[J].摩擦学学报,2002(04):250-253. |
| [22] | 杨国俊,李恭.推荐一种金属表面耐磨新技术[J].现代车用动力,2002(02):41-42. |
| [23] | 钟厉,戴仲谋,邵丽.循环N/C/O/S离子共渗对316Ti钢组织及耐腐蚀性的影响[J].表面技术,2012(03):67-70. |
| [24] | 徐永礼,庞祖高,马宽猷,韦曼云,黄银燕.RE-N-C-S-V-Nb多元共渗H13钢的热疲劳性能研究[J].表面技术,2013(05):35-38,44. |
| [25] | 于东升 .钛合金表面离子渗钼及耐磨性的研究[D].北京工业大学,2010. |
| [26] | 郑文鹏,田晓东,王利捷,唐美静.Ti6Al4V钛合金表面制备二硫化钼复合涂层工艺研究[J].热加工工艺,2013(04):167-169. |
| [27] | 田晓东,王利捷,郑文鹏.TC4钛合金表面辉光离子渗Mo渗S复合处理涂层的组织和摩擦学性能[J].表面技术,2013(02):4-6. |
| [28] | 巴德玛,马世宁,李长青,李新,胡春华.Cr-Si合金钢表面纳米层对低温离子渗硫的影响[J].材料热处理学报,2008(05):160-164. |
| [29] | XU G Z;LIU J J;ZHOU Z R et al.The Fretting Wear-re-sistant Properties of Steel with and Ion-sulphuration+Shot-peening Shot-peening+Ion-sulphuration Duplex Treatments[J].Tribology International,2001,34(01):1-6. |
| [30] | Wang, H.-D.;Ma, G.-Z.;Xu, B.-S.;Si, H.-J.;Yang, D.-X. .Microstructure and vacuum tribological properties of 1Cr18Ni9Ti steel with combined surface treatments[J].Surface & Coatings Technology,2011(11):3546-3552. |
| [31] | 马国政,徐滨士,王海斗,司洪娟.表面纳米化预处理对1Cr18Ni9Ti不锈钢渗硫层摩擦学性能的影响[J].机械工程学报,2011(11):75-81. |
| [32] | 司洪娟,徐滨士,王海斗,马国政.FeCrBSi/FeS层真空辐照环境下的组织结构与摩擦学性能研究[J].真空科学与技术学报,2011(05):560-564. |
| [33] | 王海斗,徐滨士,刘家浚,庄大明.两步法制备固体润滑FeS薄膜的摩擦磨损性能研究[J].摩擦学学报,2005(04):303-307. |
| [34] | 王海斗,庄大明,王昆林,刘家浚,张弓.钢表面钼沉积及渗硫复合改性层的摩擦学性能[J].摩擦学学报,2003(03):188-191. |
| [35] | Kang, JJ;Wang, CB;Wang, HD;Xu, BS;Liu, JJ;Li, GL .Characterization and tribological properties of composite 3Cr13/FeS layer[J].Surface & Coatings Technology,2009(14):1927-1932. |
| [36] | Kang Jia-jie;Wang Cheng-biao;Wang Hai-dou;Xu Bin-shi;Liu Jia-jun;Li Guo-lu .Research on tribological behaviors of composite Zn/ZnS coating under dry condition[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(6):1940-1943. |
| [37] | Zhu Li-na;Wang Cheng-biao;Wang Hai-dou;Xu Bin-shi;Zhuang Da-ming;Liu Jia-jun;Li Guo-lu .Microstructure and tribological properties of WS_2/MoS_2 multilayer films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(6):1944-1948. |
| [38] | Zhu Li-na;Li Guo-lu;Wang Hai-dou;Xu Bin-shi;Liu Jia-jun .Comparative characterization to the three kinds of solid-shape FeS[J].Materials Letters,2008(1):163-166. |
| [39] | Wang Hai-dou;Xu Bin-shi;Liu Jia-jun;Zhuang Da-ming .Characterization and anti-friction on the solid lubrication MoS_2 film prepared by chemical reaction technique[J].Science and technology of advanced materials,2005(5):535-539. |
| [40] | 司洪娟,徐滨士,王海斗,马国政.复合Zn/ZnS层的组织结构及其大气与真空环境下的摩擦学性能[J].中国表面工程,2010(01):75-79. |
| [41] | 蔡健平.环境工程与可靠性工程的关系初探[J].装备环境工程,2013(01):66-69,101. |
| [42] | 张平,曾庆强,蔡志海,李奇.激光淬火渗硫复合层的抗高温摩擦磨损性能[J].装甲兵工程学院学报,2010(01):71-73,82. |
| [43] | 万盛,韩彬,王勇,薛敏鹏.激光相变硬化-离子渗硫复合改性层的性能[J].金属热处理,2012(01):68-71. |
| [44] | 杨军胜 .采用复合渗镀技术提高Ti-6Al-4V摩擦学性能[D].长安大学,2010. |
| [45] | 孙雪洁 .渗氮层与渗氮/渗硫复合层在润滑条件下的摩擦学性能研究[D].北京:中国地质大学,2011. |
| [46] | 刘沅东,王成彪,袁静静,刘家浚.固-液复合润滑对轴承钢摩擦学性能的影响[J].摩擦学学报,2009(06):537-545. |
| [47] | 刘沅东,王成彪,袁静静,刘家浚.渗硫层与FeS粉末摩擦学机理的对比研究[J].摩擦学学报,2010(03):296-302. |
| [48] | 乔玉林,胡春华,赵玉强,杨善林.连续加载条件下纳米Al2O3/FeS固体润滑复合涂层的摩擦学性能[J].摩擦学学报,2010(06):561-566. |
| [49] | 易小勇 .复合固体润滑膜的试验研究[D].江苏大学,2010. |
| [50] | 胡春华,杨春燕,刘庆存,孙志杰,马世宁,乔玉林.纳米Al2O3-Fe3O4/FeS固体润滑复合层减摩润滑机理[J].材料热处理学报,2013(06):130-135. |
| [51] | 刘洋 .等离子喷涂Ni60A/MoS2 复合润滑涂层摩擦学特性的研究[D].赣州:江西理工大学,2009. |
| [52] | 陈东,罗明波,陈晓琴,陈汉宾,张隆平.等离子喷涂NiCr-Cr3C2基复合自润滑涂层的组织及摩擦学性能[J].表面技术,2013(03):52-55. |
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