尖晶石型LiMn2O4正极材料目前还存在初始容量较低、容量衰减快、高温性能差等问题.表面改性是一种常用的改性方法,它能有效地改善锰酸锂的性能.主要介绍了金属氧化物、含Li化合物、聚合物、金属、氟化物、氧化物玻璃以及一些含氧盐对锰酸锂的表面改性及对其循环性能影响的研究进展,概括了锰酸锂不同表面改性方法的优缺点,并提出了可行的改进方案.
参考文献
| [1] | Thackeray M M;Johnson P J;de Picciotto L A et al.Electrochemical extraction of lithium from LiMn2O4[J].Materials Research Bulletin,1984,19(02):179. |
| [2] | Rossouw M H;de Kock A;de Picciotto L A et al.Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries[J].Materials Research Bulletin,1990,25(02):173. |
| [3] | Li Yang;Michio Takahashi;Baofeng Wang .A study on capacity fading of lithium-ion battery with manganese spinel positive electrode during cycling[J].Electrochimica Acta,2006(16):3228-3234. |
| [4] | Song Myoung Youp;Ahn Dong Su;Park Hye Ryoung .Capacity fading of spinel phase LiMn2O4 with cycling[J].Journal of Power Sources,1999,83(1-2):57. |
| [5] | Yunjian Liu;Xinhai Li;Huajun Guo;Zhixing Wang;Qiyang Hu;Wenjie Peng;Yong Yang .Electrochemical performance and capacity fading reason of LiMn_2O_4/graphite batteries stored at room temperature[J].Journal of Power Sources,2009(1):721-725. |
| [6] | Araki K;Sato N .Chemical transformation of the electrode surface of lithium-ion battery after storing at high temperature[J].Journal of Power Sources,2003,124(01):124. |
| [7] | Ouyang C Y;Shi S Q;Lei M S .Jahn-Teller distortion and electronic structure of LiMn2O4[J].Journal of Alloys and Compounds,2009,474(1-2):370. |
| [8] | Atsuo Yamada;Masahiro Tanaka;Koichi Tanaka;Koji Sekai .Jahn--Teller instability in spinel Li--Mn--O[J].Journal of Power Sources,1999(0):73-78. |
| [9] | C.L. Tan;H.J. Zhou;W.S. Li;X.H. Hou;D.S. Lue;M.Q. Xu;Q.M. Huang .Performance Improvement Of Limn_2o_4 As Cathode Material For Lithium Ion Battery With Bismuth Modification[J].Journal of Power Sources,2008(2):408-413. |
| [10] | C. Li;H. R. Zhang;H. Liu;Y. R. Wu;E. Rahm;R. Holze;H. Q. Wu .Cathode materials modified by surface coating for lithium ion batteries[J].Electrochimica Acta,2006(19):3872-3883. |
| [11] | Fu LJ;Liu H;Li C;Wu YP;Rahm E;Holze R;Wu HQ .Surface modifications of electrode materials for lithium ion batteries[J].Solid state sciences,2006(2):113-128. |
| [12] | 金超,吕东生,李伟善.尖晶石LiMn2O4的表面修饰改性[J].中国锰业,2003(03):21-25. |
| [13] | Sung Bin Park;Ho Chul Shin;Wan-Gyu Lee;Won Il Cho;Ho Jang .Improvement of capacity fading resistance of LiMn_2O_4 by amphoteric oxides[J].Journal of Power Sources,2008(1):597-601. |
| [14] | Tu J;Zhao X B;Xie J et al.Enhanced low voltage cycling stability of LiMn2O4 cathode by ZnO coating for lithium ion batteries[J].Journal of Alloys and Compounds,2007,432(1-2):313. |
| [15] | Liu Haowen;Cheng Cuixia et al.The effect of ZnO coating on LiMn2O4 cycle life in high temperature for lithium secondary batteries[J].Materials Chemistry and Physics,2007,101(2-3):276. |
| [16] | Liu Dongqiang;Liu Xingquan;He Zezhen .Surface modification by ZnO coating for improving the elevated temperature performance of LiMn2O4[J].Journal of Alloys and Compounds,2007,436(1-2):387. |
| [17] | Halil Sahan;Hüseyin G(o)ktepe;Saban Patat et al.Effect of the Cr2O3 coating on electrochemical properties of spinel LiMn2O4 as a cathode material for lithium battery applications[J].Solid State Ionics,2010,181(31-32):1437. |
| [18] | Tu J;Zhao X B;Cao G S et al.Enhanced cycling stability of LiMn2O4 by surface modification with melting impregnation method[J].Electrochimica Acta,2006,51(28):6456. |
| [19] | 刘涛,杜荣斌,姜效军.SnO2对尖晶石LiMn2O4电极材料的改性[J].过程工程学报,2007(05):1045-1049. |
| [20] | Arumugam, D;Kalaignan, GP .Synthesis and electrochemical characterizations of Nano-SiO2-coated LiMn2O4 cathode materials for rechargeable lithium batteries[J].Journal of Electroanalytical Chemistry,2008(1/2):197-204. |
| [21] | 王洪,邓璋琼,何平.锂离子电池正极材料锰酸锂的改性[J].无机盐工业,2010(07):20-22. |
| [22] | Jung Kyu-Nam;Pyun Su-Il .Mechanism transition of cellimpedance-controlled lithium transport through Li1-δMn2O4 composite electrode caused by surface-modification and temperature variation[J].Electrochimica Acta,2007,52(17):5453. |
| [23] | J. S. Gnanaraj;V. G. Pol;A. Gedanken;D. Aurbach .Improving the high-temperature performance of LiMn_2O_4 spinel electrodes by coating the active mass with MgO via a sonochemical method[J].Electrochemistry communications,2003(11):940-945. |
| [24] | 李文,苏光耀,肖启振.尖晶石LiMn2O4的表面改性研究[J].电池,2005(02):123-125. |
| [25] | Yu Lihong;Qiu Xinping;Xi Jingyu et al.Enhanced highpotential and elevated-temperature cycling stability of LiMn2O4 cathode by TiO2 modification for Li-ion battery[J].Electrochimica Acta,2006,51(28):6406. |
| [26] | Ali Eftekhari .LiMn_2O_4 electrode prepared by gold-titanium codeposition with improved cyclability[J].Journal of Power Sources,2004(1/2):260-265. |
| [27] | Arumugam D;Kalaignan G P .Electrochemical characterizations of surface modified LiMn4 O2 cathode materials for high temperature lithium battery applications[J].Thin Solid Films,2011,520(01):338. |
| [28] | D. Arumugam;G. Paruthimal Kalaignan .Synthesis and electrochemical characterizations of nano-La_2O_3-coated nanostructure LiMn_2O_4 cathode materials for rechargeable lithium batteries[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(12):1825-1831. |
| [29] | Ha Hyung-Wook;Yun Nan Ji .Keon Kim Improvement of electrochemical stability of LiMn2O4 by CeO2 coating for lithium-ion batteries[J].Electrochimica Acta,2007,52(09):3236. |
| [30] | D. Arumugam;G. Paruthimal Kalaignan .Synthesis and electrochemical characterization of nano-CeO_2-coated nanostructure LiMn_2O_4 cathode materials for rechargeable lithium batteries[J].Electrochimica Acta,2010(28):8709-8716. |
| [31] | 王洪,祝纶宇,陈鸣才.表面包覆改性尖晶石锰酸锂正极材料[J].电源技术,2007(03):239-241. |
| [32] | Zhanxu Yang;Wensheng Yang;David G. Evans;Yingying Zhao;Xun Wei .The Effect Of A Co-al Mixed Metal Oxide Coating On The Elevated Temperature Performance Of A Limn_2o_4 Cathode Material[J].Journal of Power Sources,2009(2):1147-1153. |
| [33] | 张仁刚,赵世玺,夏君磊,刘韩星.尖晶石LiMn2O4的表面改性研究[J].电化学,2002(03):269-274. |
| [34] | Chang Woo Lee;Hyun-Soo Kim;Seong-In Moon .Effects on surface modification of spinel LiMn_2O_4 material for lithium-ion batteries[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2005(3):234-237. |
| [35] | Shu D.;Kumar G.;Kim KB.;Ryu KS.;Chang SH. .Surface modification of LiMn2O4 thin films at elevated temperature[J].Solid state ionics,2003(3/4):227-233. |
| [36] | Liu Zbaolin;Wang Hongbin;Fang Ling et al.Improving the high-temperature performance of LiMn2O4 spinel by micro-emulsion coating of LiCoO2[J].Journal of Power Sources,2002,104(01):101. |
| [37] | Fei-Yi Hung;Truan-Sheng Lui;Hung-Chi Liao .A study of nano-sized surface coating on LiMn_2O_4 materials[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(18):7443-7448. |
| [38] | Li Xifei;Xu Youlong;Wang Chunlei .Novel approach to preparation of LiMn2O4 core/LiNixMn2-xO4 shell composite[J].Applied Surface Science,2009,255(11):5651. |
| [39] | Park Sung-Chul;Kim You-Min;Han Sang-Cheol et al.The elevated temperature performance of LiMn2O4 coated with LiNi1-xCoxO2(X=0.2 and 1)[J].Journal of Power Sources,2002,107(01):42. |
| [40] | Yuan Y F;Wu H M;Guo S Y et al.Preparation,characteristics and electrochemical properties of surface-modified LiMn2O4 by doped LiNi0.05 Mn1.95 O4[J].Applied Surface Science,2008,255(05):2225. |
| [41] | Li Xifei;Xu Youlong;Wang Chunlei .Suppression of JahnTeller distortion of spinel LiMn2O4 cathode[J].Journal of Alloys and Compounds,2009,479(1-2):310. |
| [42] | Kitaura, H.;Hayashi, A.;Tadanaga, K.;Tatsumisago, M. .Improvement of electrochemical performance of all-solid-state lithium secondary batteries by surface modification of LiMn_2O_4 positive electrode[J].Solid state ionics,2011(1):304-307. |
| [43] | 刘东强,吁霁,孙玉恒,何泽珍,刘兴泉.LiMn2O4表面包覆Li4Ti5O12的制备及倍率特性[J].无机化学学报,2007(01):41-45. |
| [44] | Liu Dongqiang;Liu Xingquan;He Zezhen .The elevated temperature performance of LiMn2O4 coated with Li4Ti5O12 for lithium ion battery[J].Materials Chemistry and Physics,2007,105(2-3):362. |
| [45] | Naoto Kitamura;Hidenobu Iwatsuki;Yasushi Idemoto .Improvement of cathode performance of LiMn_2O_4 as a cathode active material for Li ion battery by step-by-step supersonic-wave treatments[J].Journal of Power Sources,2009(1):114-120. |
| [46] | Chan Hong-Wei;Duh Jenq-Gong;Sheen Shyang-Roeng et al.New surface modified material for LiMn2O4 cathode material in Li-ion battery[J].Surface and Coatings Technology,2005,200(5-6):1330. |
| [47] | Chan HW;Duh JG;Lee JF .Valence change by in situ XAS in surface modified LiMn2O4 for Li-ion battery[J].Electrochemistry communications,2006(11):1731-1736. |
| [48] | Kwang Hee Jung;Ho-Gi Kim;Yong Joon Park .Effects of protecting layer [Li,La]TiO_3 on electrochemical properties of LiMn_2O_4 for lithium batteries[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(12):4426-4432. |
| [49] | 周艺峰,聂王焰,陈春华,水江澜.锂离子电池正极材料LiMn2O4的改性研究[J].功能材料,2006(09):1381-1385. |
| [50] | Hu GH;Wang XB;Chen F;Zhou HY;Li RG;Deng ZH .Study of the electrochemical performance of spinel LiMn2O4 at high temperature based on the polymer modified electrode[J].Electrochemistry communications,2005(4):383-388. |
| [51] | 王小兵,胡国和,陈方,李仁贵,邓正华.提高尖晶石liMn2O4循环性能的研究[J].电源技术,2005(11):719-722. |
| [52] | 李仁贵,王璐,陈勉忠,邓正华.原位电聚合苯胺修饰LiMn2O4正极材料的研究[J].电源技术,2004(12):751-754. |
| [53] | 许名飞,李新海,陈启元.尖晶石LiMn2O4的表面改性研究[J].矿冶工程,2006(01):56-60. |
| [54] | SonJ T;Park K S;Kim H G et al.Surface-modification of LiMn2O4 with a silver-metal coating[J].Journal of Power Sources,2004,126(1-2):182. |
| [55] | Zhou Wenjia;He Benlin;Li Hulin .Synthesis,structure and dectrochemistry of Ag-modified LiMn2O4 cathode materials for lithium-ion batteries[J].Materials Research Bulletin,2008,43(8-9):2285. |
| [56] | LI Jian-gang,HE Xiang-ming,ZHAO Ru-song.Electrochemical performance of SrF2-coated LiMn2O4 cathode material for Li-ion batteries[J].中国有色金属学会会刊（英文版）,2007(06):1324-1327. |
| [57] | Wu C.;Wu F.;Chen LQ.;Huang XJ. .Fabrications and electrochemical properties of fluorine-modified spinel LiMn2O4 for lithium ion batteries[J].Solid state ionics,2002(Pt.A):327-334. |
| [58] | CAO Jina,CAO Gaoshao,YU Hongming,XIE Jian,ZHAO Xinbing.Synthesis and electrochemical performance of YF3-coated LiMn2O4 cathode materials for Li-ion batteries[J].稀有金属（英文版）,2011(01):39-43. |
| [59] | Chan Hung-Wei;Duh Jenq-Gong;Sheen Shyang-Roeng .Electrochemical performance of LBO-coated spinel lithium manganeseoxide as cathode material for Li-ion battery[J].Surface and Coatings Technology,2004,188-189:116. |
| [60] | Halil Sahan;Hüseyin G(o)ktepe;Saban Patat et al.Improvement of the electrochemical performance of LiMn2O4 cathode active material by lithium borosilicate (LBS) surface coating for lithium-ion batteries[J].Journal of Alloys and Compounds,2011,509(11):4235. |
| [61] | Chan H W;Duh J G;Sheen S R .Microstructure and electrochemical properties of LBO-coated Li-excess Li1+xMn2O4 cathode material at elevated temperature for Li-ion battery[J].Electrochimica Acta,2006,51(18):3645. |
| [62] | Halil Sahan;Htüseyin G(o)ktepe;Saban Patat et al.The effect of LBO coatirg method on electrochemical performance of LiMn2O4 cathode material[J].Solid State Ionics,2008,178(35-36):1837. |
| [63] | 李爽,张五星,杨泽,梅鑫涛,吕文中,胡先罗,袁利霞,黄云辉.磷酸铁包覆纳米锰酸锂的改性研究[J].材料导报,2011(06):53-57. |
| [64] | Chunbo Qing;Ying Bai;Jueming Yang;Weifeng Zhang .Enhanced cycling stability of LiMn_2O_4 cathode by amorphous FePO_4 coating[J].Electrochimica Acta,2011(19):6612-6618. |
| [65] | Improved electrochemical performance of AlPO_4-coated LiMn_(1.5)Ni_(0.5)O_4 electrode for lithium-ion batteries[J].Journal of Power Sources,2010(19):P.6860. |
| [66] | Dongqiang Liu;Zezhen He;Xingquan Liu .Increased cycling stability of AlPO_4-coated LiMn_2O_4 for lithium ion batteries[J].Materials Letters,2007(25):4703-4706. |
| [67] | Halil Sahan,Hüseyin G(o)ktepe,Saban Patat.A Novel Method to Improve the Electrochemical Performance of LiMn2O4 Cathode Active Material by CaCO3 Surface Coating[J].材料科学技术学报（英文版）,2011(05):415-420. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%