采用顶部籽晶法生长Nd3+:Na3La9O3(BO3)8 晶体.在室温下测试了吸收光谱、发射光谱和荧光寿命.应用Judd-Ofelt理论评价了Nd3+:Na3La9O3(BO3)8晶体的光谱性能.812 nm处较宽的吸收峰适合AlGaAs LD泵浦的吸收.分别计算了Nd3+离子的唯象强度、谱线强度、辐射寿命、荧光分支比和荧光量子效率.
Nd3+doped Na3La9O3(BO3)8 crystal has been grown by the top-seeded solution growth(TSSG)method.The absorption spectrum,emission spectrum and lifetime have been measured at room temperature.The Judd-Ofelt theory has been applied to the evaluation of its spectral properties.The broad absorption band around 812 nm makes it suitable for the AlGaAs laser diode pumping.The JO parameters(Ωt,t=2,4,6),the emission intensity,the radiative lifetime,the branching ratios and the radiative quantum efficiency have been calculated.
参考文献
[1] | Johnson L F;Ballman A A .Coherent Emission from Rare Earth Ions in Electro-optic Crystals[J].Journal of Applied Physics,1969,40:297. |
[2] | Brenier A. .The self-doubling and summing lasers: overview and modeling[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2000(3-4):121-132. |
[3] | Aka G;Brenier A .Self-frequency Conversion in Nonlinear Laser Crystals[J].Optical Materials,2003,22:89. |
[4] | Hemmati H. .Diode-pumped self-frequency-doubled neodymium yttrium aluminum borate (NYAB) laser[J].IEEE Journal of Quantum Electronics: A Publication of the IEEE Quantum Electronics and Applications Society,1992(4):1169-1171. |
[5] | Chen X Y;Huang M L;Luo Z D et al.Determination of the Optimum Phase-matching Directions for the Self-frequency Conversion of Nd:GdCOB and Nd:YCOB Crystals[J].Optics Communications,2001,196:299. |
[6] | Brenier A.;Majchrowski A.;Michalski E.;Lukasiewicz T. .Evaluation of GdCOB : Nd3+ for self-frequency doubling in the optimum phase matching direction[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2003(1/6):395-400. |
[7] | Aka G;Mougel F;Auge F et al.Overview of the Laser and Non-linear Optical Properties of Calcium-gadolinium-oxo-borate Ca4GdO(BO3)3[J].Journal of Alloys and Compounds,2000,303-304:401. |
[8] | Chen W Z;Wang G F;Lin Z B et al.Spectral Parameters of Nd3+ ion in β-Nd3+:LaSc3(BO3)4 Crystal[J].Optics Communications,1999,162:49. |
[9] | Brenier A;Wu Y;Fu P;Guo R;Jing F;Zu Y .Spectroscopy and self-frequency doubling of the F-4(3/2) -> I-4(13/2) laser channel in the La2CaB10O19 : Nd3+ bi-functional crystal[J].Applied physics, B. Lasers and optics,2007(4):673-676. |
[10] | Gravereau P;Chaminade J P;Pechev S et al.Na3La9O3(BO3)8,a New Oxyborate in the Ternary System Na2O-La2O3-B2O3:Preparation and Crystal Structure[J].Solid State Sciences,2002,4:993. |
[11] | Zhang G C;Wu Y C;Li Y G et al.Flux Growth and Characterization of a New Oxyborate Crystal Na3La9O3(BO3)8[J].Journal of Crystal Growth,2005,275:e1997. |
[12] | Li YG;Wu YC;Zhang GC;Fu PZ;Bai XY .Flux growth and optical properties of Na3La9O3(BO3)(8) crystals[J].Journal of Crystal Growth,2006(2):468-471. |
[13] | R. Balda;V. Jubera;C. Frayret;S. Pechev;R. Olazcuaga;P. Gravereau;J.P. Chaminade;M. Al-Saleh;J. Fernandez .First luminescence study of the new oxyborate Na_3La_9O_3(BO_3)_8:Nd~(3+)[J].Optical materials,2007(1):122-125. |
[14] | Carnall W T;Fields P R;Rajnak K .Electronic Energy Level in the Trivalent Lanthanide Aquo Ions.I.Pr3+,Nd3+,Pm3+,Sm3+,Dy3+,Ho3+,Er3+,and Tm3+[J].Journal of Chemical Physics,1968,49:4424. |
[15] | Judd B R .Optical Absorption Intensities of Rare-earth Ions[J].Physical Review,1962,127:750. |
[16] | Ofelt G S .Intensities of Crystal Spectra of Rare-earth Ions[J].Journal of Chemical Physics,1962,37:511. |
[17] | Krupke W F .Radiative Transition Probabilities Within the 4f 3 Ground Configuration of Nd:YAG[J].IEEE Journal of Quantum Electronics,1971,QE-7:153. |
[18] | Jiang H D;Wang J Y;Zhang H J et al.Optical-transition Properties of the Nd3+ Ion in Gd0.8La0.2VO4 Crystal[J].Journal of Applied Physics,2002,92:3647. |
[19] | Mougel F;Aka G;Kahn-Harari A et al.Infrared Laser Performance and Self-frequency Doubling of Nd3+:Ca4GdO(BO3)3(Nd:GdCOB)[J].Optical Materials,1997,8:161. |
[20] | Jaque D;Capmany J;Luo Z D et al.Optical Bands and Energy Levels of Nd3+ Ion in the YAl3(BO3)4 Nonlinear Laser Crystal[J].J Phys -Condens Matter,1997,9:9715. |
[21] | Guo R;Wu YC;Fu PZ;Jing FL .Optical assessment on a new self-frequency doubling crystal: neodymium-doped lanthanum calcium borate[J].Journal of the Optical Society of America, B. Optical Physics,2005(4):831-834. |
[22] | Wang G F;Lin Z B;Hu Z S et al.Crystal Growth and Optical Assessment of Nd3+:GdAl3(BO3)4 Crystal[J].Journal of Crystal Growth,2001,233:755. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%