采用FC化合物作为一种新型催化剂--NiZnAl催化剂的前驱物,以催化热解法合成出了碳纳米管.管状、竹节状、鱼骨状和分叉状等多种形态的碳纳米管均被观测到.在碳纳米管生长过程中位于其顶端的准液态金属颗粒是其形成多种形态碳纳米管的关键.Zn的添加可能使得经煅烧和还原后的Ni催化剂的活性产生了微妙的变化.
参考文献
[1] | Iijima S Helical .microtubules of graphitic carbon[J].Nature,1991,354:56-58. |
[2] | Jones JM.;Thomas KM.;Bottrell SH.;Malcolm RP. .THE ANODE DEPOSIT FORMED DURING THE CARBON-ARC EVAPORATION OF GRAPHITE FOR THE SYNTHESIS OF FULLERENES AND CARBON NANOTUBES[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(2):231-237. |
[3] | Colbert P T;Zhang J;McClure S M et al.Growth and sintering of fullerene nanotubes[J].Science,1994,266:1218-1233. |
[4] | Yacaman M J;Yoshida M M;Redon L .Catalytic growth of carbon microtubules with fullerene structure[J].Applied Physics Letters,1993,62:202-206. |
[5] | Dai H;Wong W;Lu Y et al.Synthesis and characterization of carbide nanorods[J].Nature,1995,375:769-771. |
[6] | Guo T.;Thess A.;Colbert DT.;Smalley RE.;Nikolaev P. .CATALYTIC GROWTH OF SINGLE-WALLED NANOTUBES BY LASER VAPORIZATION[J].Chemical Physics Letters,1995(1/2):49-54. |
[7] | 闫晓琦,李颖,周江宁,刘占泉,曲金秋,高学平,宋德瑛.球磨MgO·Ni2O3固溶体为负载纳米Ni催化剂前驱物催化热解法制备碳纳米纤维[J].南开大学学报(自然科学版),2003(01):55-59. |
[8] | Rodriguez N M;Chambers A;Baker RT.Catalytic engineering of carbon nanostructures[J].Lagmuir,1995(11):3862-3866. |
[9] | 马衍梅 .催化生长碳纤维的研究[D].天津大学,1999. |
[10] | Yongdan Li;Jiuling Chen;Yanmei Ma;Jinbao Zhao;Yongning Qin;Liu Chang .Formation of bamboo-like nanocarbon and evidence for the quasi-liquid state of nanosized metal particles at moderate temperatures[J].Chemical communications,1999(12):1141-1142. |
[11] | 陈久岭 .甲烷催化裂解生长纳米碳纤维及其应用的基础研究[D].天津:天津大学,1999. |
[12] | 张孝彬,甘波,杨杭生,齐仲甫,李文铸,张泽.纳米碳管的分叉结构[J].物理学报,1999(05):913-916. |
[13] | Chen J;Li Y;Ma Y.Formation of bamboo-shaped carbon filaments and dependence of morphology on catalyst composition and reaction condition[J].Carbon,2001(39):1467-1475. |
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