研究了两种燃烧方式煤燃烧过程中金属铜的添加对多环芳烃生成的影响.结果表明:随着铜煤质量比的增加,管式炉煤燃烧多环芳烃生成浓度是减少的;流化床煤燃烧多环芳烃生成浓度是增加的,但要小于管式炉条件下两个数量级.多环芳烃生成毒性分布类似于多环芳烃生成浓度分布.而单个多环芳烃生成有着较大区别,同燃烧方式、存在状态、铜的含量等有较大关系.在燃烧温度下,铜的添加主要对高环物质的催化作用较为明显.
参考文献
[1] | Junk G A;Ford C S.A Review of Organic Emissions from Selected Combustion Processes[J].Chemosphere,1980(09):187-230. |
[2] | Charles W;Bauschlicher Jr;Alessandra Ricca .Mechanism for Polycyclic Aromatic Hydrocarbon (PAH)Growth[J].Chemical Physics Letters,2000,326:283-287. |
[3] | Henning Richter;William J.Grieco;Jack B.Howard .Formation Mechanism of Polycyclic Aromatic Hydrocarbons and Fullerenes in Premixed Benzene Flames[J].Combustion and Flame,1999(1/2):1-22. |
[4] | FEITELBERG A S;Longwell J P;Sarofim A F .Metal Enhanced Soot and PAH Formation[J].Combustion and Flame,1993,9:241-253. |
[5] | Ming-Yen Wey;Chia-Yung Chao;Ming-Chi Wei .The influence of heavy metals on partitioning of PAHs during incineration[J].Journal of hazardous materials,2000(1/3):77-87. |
[6] | Mueller J;Dongamann G .Formation of Aromatics During Pyrolysis of PVC in the Presence of Metal Chlorides[J].Journal of Analytical and Applied Pyrolysis,1998,45(01):59-74. |
[7] | Klaus Jay;Ludwig Stieglitz .On the Mechanism of Formation of Polychlorinated Aromatic Compounds with Copper (Ⅱ) Chloride[J].Chemosphere,1991,22:987-996. |
[8] | Baek S O .A Review of Atmospheric Polycyclic Aromatic Hydrocarbons: Sources, Fate and Behavior[J].Water Air and Soil Pollution,1991,60:279-300. |
[9] | Thomas R Barfknecht .Toxicology of Soot. Prog[J].Energy and Combustion Science,1983,9:199-237. |
[10] | Ming-Yen Wey;Wen-Yu Ou;Zhen-Shu Liu .Pollutants in incineration flue gas[J].Journal of hazardous materials,2001(3):247-262. |
[11] | 严建华,尤孝方,李晓东,祁明峰,倪明江,岑可法.煤中氯对多环芳烃生成的影响研究[J].工程热物理学报,2003(02):335-338. |
[12] | 尤孝方,李晓东,严建华,倪明江,岑可法.流化床焚烧塑料垃圾多环芳烃的生成特性[J].燃烧科学与技术,2003(04):376-380. |
[13] | 李晓东,祁明峰,尤孝方,严建华,池涌,倪明江,岑可法.烟煤燃烧过程中多环芳烃生成研究[J].中国电机工程学报,2002(12):127-132. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%