通过自由基胶束共聚法制备了PBAM系列非离子型疏水缔合共聚物,并对聚合反应进行了研究,结果表明,丙烯酰胺的水相聚合反应动力学仍然适用于胶束共聚合过程;在聚合过程中由于表面活性剂胶束的存在,疏水单体在反应初期的嵌入率很高,而后期主要以丙烯酰胺均聚物为主,导致严重的微观结构非均匀性,而这种非均匀性时共聚物的增粘性能有很大的影响.
参考文献
[1] | Taylor K C;Nasr-El-Din H A .[J].Journal of Petroleum Science and Engineering,1998,19:265. |
[2] | Ma JT.;Cui P.;Zhao L.;Huang RH. .Synthesis and solution behavior of hydrophobic association water-soluble polymers containing arylalkyl group[J].European Polymer Journal,2002(8):1627-1633. |
[3] | Peer W J;In Glass J E.Polymers in Aqueous Media:Performance Through Association Ch 20 Advance in Chemistry 223[J].Washington D C:American Chemical Society,1989:381. |
[4] | Dawling K C;Thomas J K .[J].MACROMOLECULES,1990,23(04):1059. |
[5] | Branham K D;Middleton J C;McCormick C L .[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1991,32(01):106. |
[6] | McCormick C L;Middleton J C;Grady C E .[J].POLYMER,1992,33(19):4184. |
[7] | Hill A;Candau F;Selb J .[J].Macromolecules,1993,26:4521. |
[8] | Candau F.;Selb J. .Hydrophobically-modified polyacrylamides prepared by micellar polymerization[J].Advances in Colloid and Interface Science,1999(2/3):149-172. |
[9] | Freid J P;Alexander A E .[J].Journal of Polymer Science Part A:Polymer Chemistry,1978,6:1833. |
[10] | 李干佐,郝京诚,杜贞伟,汪汉卿,夏瑞.丙烯酰胺在胶束和微乳液中聚合动力学研究[J].科学通报,1995(09):799-802. |
[11] | Biggs S;Selb J;Candau F.[J].LANGMUIR,1992(03):838. |
[12] | Candau F.;Selb J. .Hydrophobically-modified polyacrylamides prepared by micellar polymerization[J].Advances in Colloid and Interface Science,1999(2/3):149-172. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%