高硅钢(6.5%(质量分数)Si)是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金.但高硅钢的室温脆性和低的热加工性能严重影响了其在工业领域的应用.综述了化学气相沉积、等离子体化学气相沉积、电泳沉积、熔盐电沉积、电子束物理气相沉积及激光熔覆等6种沉积扩散法制备高硅钢的工艺和参数,从工艺路线、反应机理分析和性能的改善等几方面,概述了各种方法的研究现状和主要的优缺点,并简要论述了其发展前景,指出了今后的主要研究方向.
Fe-6. 5wt%Si steel is one kind of soft magnetic materials with high permeability, low coercivity and iron loss. However, its room temperature brittleness and poor workability limit its industrial application. The prepa-ration technology and parameters of high silicon steel by deposition-diffusion are reviewed. This paper mainly intro-duces chemical vapor deposition, plasma chemical vapour deposition, electrical phoretic deposition, molten salt electro-deposition, electron beam physical vapor deposition and laser cladding. The research status and the advantages and disadvantages of these methods are summarized from the aspects of process route, reaction mechanism and improve-ment of performance. The prospect of the method is briefly discussed. The main directions for further studies in this field are suggested.
参考文献
[1] | Thant P P Phway;Anthony J Moses .Magnetostriction trend of non-oriented 6.5% Si-Fe[J].Journal of Magnetism and Magnetic Materials,2008,320(20):e611. |
[2] | 潘丽梅,金吉男,林均品,王建国,王艳丽,林志,陈国良.硼元素对Fe-6.5%(质量分数)Si合金力学性能影响的试验研究[J].功能材料,2004(06):683-685. |
[3] | 刘艳,梁永锋,叶丰,林均品,陈国良.冷轧0.02C-6.56Si高硅钢薄板的力学和磁性能[J].特殊钢,2007(03):28-29. |
[4] | 刘海明;彭长平;李玉国 .Fe-6.5%Si快速凝固极薄带[J].钢铁,1993,28(07):55. |
[5] | Baricco M;Mastrandrea E;Antonione C et al.Grain growth and texture in rapidly solidified Fe(Si)6.5wt% ribbons[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,1997,226-228:1025. |
[6] | Bolfarini C et al.Magnetic pro-perties of spray-formed Fe6.5%Si and Fe-6.5%Si-1.0%Al after rolling and heat treatment[J].Journal of Magnetism and Magnetic Materials,2008,320(20):e653. |
[7] | Yuan WJ;Li JG;Shen Q;Zhang LM .A study on magnetic properties of high Si steel obtained through powder rolling processing[J].Journal of Magnetism and Magnetic Materials,2008(1/2):76-80. |
[8] | Takada Y;Abe M;Masuda S et al.Commercial scale production of Fe-6.5wt%Si sheet and its magnetic[J].Applied Physics,1988,64(10):5367. |
[9] | Yamaji T et al.Magnetic properties and workability of 6.5%silicon steel sheet manufactured in continuous CVD siliconizing line[J].Journal of Magnetism and Magnetic Materials,1994,133(1-3):187. |
[10] | Haiji H et al.Magnetic properties and workability of 6.5%Si steel sheet[J].Journal of Magnetism and Magnetic Materials,1996,160:109. |
[11] | 卢凤喜,王爱华.6.5%Si渗硅工艺新进展[J].金属功能材料,2008(01):40-43. |
[12] | 卢凤喜,谌剑,王爱华.化学气相沉积法6.5%Si硅钢的性能及应用[J].电工材料,2008(02):27-29,34. |
[13] | 胡广勇,武保林,王刚,王轶农,左良,Esling C.CVD法制取Fe-6.5%Si薄板的扩散工艺计算机模拟[J].东北大学学报(自然科学版),1999(04):405-407. |
[14] | 胡广勇;左良 .沉积-扩散法制取Fe-6.5%Si薄板的织构研究[J].金属学报,1998,34(05):506. |
[15] | 蔡珣.表面工程技术工艺方法400种[M].北京:机械工业出版社,2006:278. |
[16] | 吴润;陈大凯.PCVD硅涂层对DW型电工钢磁性能的影响[J].金属热处理,1996(09):15. |
[17] | 王蕾,吴新杰,李平生,陈大凯.PCVD法制高Si钢片的研究[J].金属热处理,2000(12):27-29. |
[18] | 钱苗根.材料表面技术及其应用手册[M].北京:机械工业出版社,1998:757. |
[19] | 游涛,黄璞,冯大军,张恒.扩散工艺对6.5%WtSi高硅钢性能的影响[J].武汉工程职业技术学院学报,2005(03):1-3,68. |
[20] | 张少红 .高性能硅钢的研究[D].武汉冶金科技大学,1999. |
[21] | 谢刚.熔融盐理论与应用[M].北京:冶金工业出版社,1998:197. |
[22] | 蔡宗英 .熔盐电沉积法制备Fe-6.5wt﹪Si薄板研究[D].河北理工学院,2003. |
[23] | 蔡宗英,张莉霞,李运刚.电化学还原法制备Fe-6.5%Si薄板[J].湿法冶金,2005(02):83-87. |
[24] | He XD;Li X;Sun Y .Microstructure and magnetic properties of high silicon electrical steel produced by electron beam physical vapor deposition[J].Journal of Magnetism and Magnetic Materials,2008(3/4):217-221. |
[25] | 李晓,孙跃,赫晓东.高温快速退火对电子束物理气相沉积制备高硅硅钢片的影响[J].功能材料,2007(10):1603-1604,1609. |
[26] | 武洪臣,姚振中,冯建基,刘喜华,刘方军.先进的涂层技术--EB-PVD[J].航空制造技术,2005(05):28-30. |
[27] | 马李,孙跃,赫晓东,李垚.电子束物理气相沉积工艺制备超薄高温结构材料的研究[J].材料导报,2006(11):100-103. |
[28] | 李美姮,胡望宇,孙晓峰,管恒荣,胡壮麒.热障涂层的研究进展与发展趋势[J].材料导报,2005(04):41-45. |
[29] | 董丹阳,刘常升,陈岁元,张滨,苗隽.激光熔覆Fe-Si涂层的超精细结构[J].金属学报,2008(02):188-192. |
[30] | Danyang Dong,Changsheng Liu,Bin Zhang,Jun Miao.Pulsed Nd: YAG laser cladding of high silicon content coating on low silicon steel[J].北京科技大学学报(英文版),2007(04):321-326. |
[31] | 樊丁,梁泽芬,张建斌,李强.激光熔覆制备Fe-Si合金涂层显微组织分析[J].兰州理工大学学报,2009(01):6-9. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%