The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams (CALPHAD) method, where the Gibbs energies of solution phases such as liquid,fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, mo lar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.
参考文献
[1] | Schumann S .The paths and strategies for increased magnesium application in vehicles[J].Materials Science Forum,2005,488-489(01) |
[2] | Yojima Y;Kamado S .Fundamental magnesium researches in Japan[J].Materials Science Forum,2005,488-489:9. |
[3] | Pan F;Yang M;Zhang D;Wang L , and Ding P .Research and development of wrought magnesium alloys in China[J].Materials Science Forum,2005,488-489:413. |
[4] | Yi D;Wang B;Fang X;Yao S , Zhou L , and Luo W .Effect of rare earth elements Y and Ce on the microstructure and mechanical properties of ZK 60 alloys[J].Materials Science Forum,2005,488-489:103. |
[5] | Sundman B;Jansson B;Anderson J O .The Thermo-Calc databank system[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1985,9:153. |
[6] | Redlich O;Kister A T .Algebraic representation of thermodynamic properties and the classification of solutions[J].Industrial and Engineering Chemistry,1948,40:354. |
[7] | Hillert M;Staffansson L I .The regular solution model for stoichiometric phases and ionic melts[J].Acta Chemica Scandinavica,1970,24:3618. |
[8] | Dinsdale A T .SGTE data for pure elements[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1991,15:317. |
[9] | Saunders N .A review and thermodynamic assess ment of the Al-Mg and Mg-Li Systems[J].Calphad-computer coupling of phase diagrams and thermochemistry,1990,14:61. |
[10] | Lukas H L.COST507-Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:48. |
[11] | Agarwal R;Fries S G;Lukas H L;Petzow G , Sommer F , Chart T G , and Effenberg G.COST507-Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:227. |
[12] | Ran Q;Lukas H L;Effenberg G;Petzow G .Thermodynamic optimization of the Mg-Y system[J].Calphad-computer coupling of phase diagrams and thermochemistry,1983,12(04):375. |
[13] | Lukas H L.COST507-Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:224. |
[14] | Fabrichnaya O B;Lukas H L;Effenberg G;Aldinger F .Thermodynamic optimization in the Mg-Y system[J].Intermetallics,2003,11:1183. |
[15] | Du Z M.Thermodynamic Assessment of the Mg-Y System[J].Private Communications,2006 |
[16] | Cacciamani G;Saccone A;Ferro R.COST507 -Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:137. |
[17] | An Mey S.COST507-Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:109. |
[18] | Ran Q;Lukas H L;Effenberg G;Petzow G .Thermodynamic optimization of the Al-Y system[J].Journal of the Less-Common Metals,1989,146:213. |
[19] | Lukas H L.COST507-Thermochemical Database for Light Metal Alloys[A].Luxembourg,1998:99. |
[20] | Liu SH;Du Y;Chen HL .A thermodynamic reassessment of the Al-Y system[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2006(3):334-340. |
[21] | Cacciamani G;Ferro R .Thermodynamic mod eling of some aluminium-rare earth binary systems:Al-La,Al-Ce and Al-Nd[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,2001,25(04):583. |
[22] | Liu X J;Wen M Z;Wang C P;Chen X , and Pan F S.Thermodynamic assessment of the Zn-Y and Al-Zn-Y systems[M].J Alloys Compd,in press |
[23] | Wang C P;Chen X;Liu X J;Pan F S.Thermodynamic assessment of the Zn-Ce and Al-Zn-Ce systems[M].J Alloys Compd,in press |
[24] | Meng FG;Liu LB;Liu HS;Jin ZP .Thermodynamic assessment of the Ce-Y system[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2006(3):323-325. |
[25] | Liang P.;Robinson JA.;Wagner S.;Ochin P.;Harmelin MG. Seifert HJ.;Lukas HL.;Aldinger F.;Tarfa T. .Experimental investigation and thermodynamic calculation of the Al-Mg-Zn system[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1998(1/2):87-110. |
[26] | Drits M E;Padezhnova E M;Dobatkina T V.Phase equilibria in Mg-Rich Mg-Y-Al alloys[J].Russian Metallurgy,1979(03):197. |
[27] | Zarechnyuk O S;Drits M E;Rykhal R M;Kinzhibalo V V.Examination of the Mg-Al-Y system (0 to 33 at % Y) at 400℃[J].Russian Metallurgy,1980(05):214. |
[28] | Odinaev K O;Ganiev I N;Kinzhibalo V V;Kurbanov K K.Phase equilibria in the Al-Mg-Y and Al-Mg-Ce system at 673 K[J].Izvestiya Vysshikh Uchebnykh Zavedenii Chernaya Metallurgiya,1989(04):75. |
[29] | Odinaev K O;Ganiev I N.Quasibinary system and the liquidus surface of the Al-Mg-YAl2 system[J].Izvestiya Vysshikh Uchebnykh Zavedenii Chernaya Metallurgiya,1990(06):90. |
[30] | Liu X J;Wen M Z;Wang C P;Chen X , and Pan F S.Thermodynamic assessment of the Mg-Al-Y ternary system[M].J Alloys Compd,in press |
[31] | Grobner J;Kevorkov D;Schmid-Fetzer R .Thermodynamic modeling of Al-Ce-Mg phase equilibria coupled with key experiments[J].Intermetallics,2002,10:415. |
[32] | Padezhnova E M;Melnik E V;Dobatnika T V.Examination of phase equilibrium in the Mg-Y-Zn system[J].Russian Metallurgy,1979(01):4179. |
[33] | Padezhnova E M;Melnik E V;Miliyevskiy R A;Dobatnika T V , and Kinzhibalo V V.Investigation of the Mg-Y-Zn system[J].Russian Metallurgy,1982(09):185. |
[34] | Zaselyan B N;Saldau P Y;Afansyev S K.The magnesium rich corner of the Mg-Y-Zn equilibrium diagram[J].Russian Metallurgy,1968(06):130. |
[35] | Shao G;Varsani V;Fan Z .Thermodynamic modelling of the Y-Zn and Mg-Zn-Y systems[J].Calphad: Computer Coupling of Phase Diagrams and Thermochemistry,2006(3):286-295. |
[36] | Melnik E V;Kostina M F;Yarmlyuk Ya P;Zmii O F .Study of the Mg-Zn-Ce and Mg-Zn-Ca ternary system,Magnievye Splavy,Mater Vses Soveshch Issled[J].Razrab Primen Magnievyhk Splavov,1978,15:95. |
[37] | Drits M E;Drozdova E I;Korolkova I G;Kinzhibalo V V , and Tyvanchuk A T.Investigation of polythermal sections of the Mg-Zn-Ce system in themagnesium-rich region[J].Russian Metallurgy,1989(02):195. |
[38] | Wang C P;Chen X;Liu X J;Wen M Z , and PanF S.Thermodynamic assessment of the Mg-Zn-Ceternary system[M].J Alloys Compd,in press |
[39] | Flandorfer H;Giovannini M;Saccone A;Rogl P , and Ferro R .The Ce-Mg-Y system[J].Metallurgical and Materials Transactions,1997,28:265. |
[40] | Ganiev I N;Ikromov A Z;Kinzhibalo V V .Phase equilibria in Al-Y-Zn system at 573 and 773 K[J].Izv Ross Akad Nauk Metall,1993,3:230. |
[41] | Ikromov A Z;Ganiev I N;Vakhobov A V;Kinzhibalo V V .Phase equilibria in Al-Zn-Ce system at 593 K[J].Metally,1991,2:217. |
[42] | Chiotti P;Mason J T;Gill K J .Phase relations and thermodynamic properties for the Y-Zn system[J].Transactions AIME,1963,227:910. |
[43] | Mason J T;Chiotti P .Phase relations and thermodynamic properties for the Y-Zn System[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1976,7(02):287. |
[44] | Chiotti P;Mason J T .Phase relations and thermodynamic properties for the Ce-Zn system[J].Transactions of the Metallurgical Society of AIME,1965,233(04):786. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%