用水热法在较低温度较短时间内制备了NaZr2(PO4)3晶体,对其合成机制进行了讨论,采用XRD,SEM,IR,TEM和BET等方法对制备的样品进行了表征.结果表明,所合成的NaZr2(PO4)3晶体具有良好的结晶度,尺寸分布在100nm~400nm之间,晶体平均孔隙直径为7.566nm.与沸腾回流法相比较表明,此水热法是更为有效的合成方法.
参考文献
[1] | Hagman L et al.[J].Acta Chemica Scandinavica,1968,22:1822. |
[2] | Hong H Y-P .[J].Materials Bulletin,1976,11:173. |
[3] | Yue Y et al.[J].Chemical Communications,1990,25:765. |
[4] | Bois L.;Carrot F.;Trocellier P.;Gautier-Soyer M.;Guittet MJ. .Preliminary results on the leaching process of phosphate ceramics, potential hosts for actinide immobilization[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2001(2):129-137. |
[5] | Lemain E et al.[J].Materials Research Bulletin,1984,19:1451. |
[6] | Borovinskii V A et al.[J].Radiochemistry(Moscow,Russian Federation),2001,43:84. |
[7] | Itoh K et al.[J].Materials Science,2002,37:1701. |
[8] | Clearfield A .[J].Res Bull,1980,15:1603. |
[9] | 朱伟员.银、铜离子双组份无机抗菌剂[J].化工新型材料,2001(10):37-38,45. |
[10] | Albert G .[J].American Chemical Society,1978,11:163. |
[11] | Ahmad A et al.[J].Solid State Ionics,1987,24:89. |
[12] | Perthuis H et al.[J].Ceramics International,1986,30:39. |
[13] | Gould W W et al.[J].Materials Research Bulletin,1993,28:909. |
[14] | 王海增 等.[J].科学通报,1994,39:189. |
[15] | Shimanouchi-Futagami R.;Nishizawa H.;Nishimori M. .Hydrothermal synthesis and electric conductivity of the NASICON-related solid solution, Na1+2xTi2BxP3-xO12[J].Journal of Materials Science Letters,2000(5):405-407. |
[16] | Qiu S et al.[J].Zeolites,1991,11:371. |
[17] | Maclanchian D J et al.[J].Physical Chemistry,1992,96:3458. |
[18] | Benhamza H et al.[J].Journal of Materials Chemistry,1991,1:681. |
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