分别以纯丙乳液、硅丙乳液和氨基功能性单体改性的硅丙乳液为基料,多聚磷酸铵(APP)、季戊四醇(PER),三聚氰胺(MEL)为膨胀体系,钛白粉为无机填料,制备水性防火涂料A、B、C,比较了3种涂料的理化性能和防火性能.结果表明,防火涂料A的膨胀高度和发泡效果较佳,但其燃烧炭层比较疏松;防火涂料B和C有优异的理化性能;防火涂料C的燃烧炭层呈"蜂窝"状,其耐火时间为72 min,比防火涂料A.、B分别长18和9 min.其主要热分解温度峰值比防火涂料A高13.8℃.
参考文献
[1] | 李飞,余历军,张星雨,陆江丽.超薄膨胀型钢结构防火涂料的研制[J].涂料工业,2007(03):42-44. |
[2] | 郑超,杨悦,顾德明.丙烯酸树脂防火涂料基料的研制[J].消防技术与产品信息,2002(03):77-78. |
[3] | 常宝,张德震,刘斌.水性超薄膨胀型钢结构防火涂料专用乳液的制备与研究[J].涂料工业,2010(06):5-8. |
[4] | 毕伟民,周慈,赵江平,郭进平.生态型防火涂料的试验研究[J].上海涂料,2005(10):22-24. |
[5] | Zou MX;Huang FZ;Nie J;Zhang ZC;Ge XW .Preparation and characterization of polysiloxane-polyacrylates composite latices and their film properties[J].Polymer international,2005(6):861-869. |
[6] | Jun-wei Gu;Guang-cheng Zhang;Shan-lai Dong;Qiu-yu Zhang;Jie Kong .Study on preparation and fire-retardant mechanism analysis of intumescent flame-retardant coatings[J].Surface & Coatings Technology,2007(18):7835-7841. |
[7] | Wang ZY;Han EH;Ke W .An investigation into fire protection and water resistance of intumescent nano-coatings[J].Surface & Coatings Technology,2006(3/4):1528-1535. |
[8] | Jimenez M;Duquesne S;Bourbigot S .Multiscale experimental approach for developing high-performance intumescent coatings[J].Industrial & Engineering Chemistry Research,2006(13):4500-4508. |
[9] | 刘成楼.超薄型钢结构防火防腐蚀涂料的研制[J].新型建筑材料,2009(02):81-85. |
[10] | Wang ZY;Han EH;Ke W .Effect of acrylic polymer and nanocomposite with nano-SiO2 on thermal degradation and fire resistance of APP-DPER-MEL coating[J].Polymer Degradation and Stability,2006(9):1937-1947. |
[11] | Zhenyu Wang;Enhou Han;Wei Ke .Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(5):2237-2253. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%