为了进一步提高生物医用AZ31B镁合金的耐蚀性能,在其表面制备磷化膜.采用扫描电镜、X射线衍射仪、电化学分析及模拟体液浸泡腐蚀试验分析了磷化膜的形貌、组成及耐蚀性.结果表明:磷化膜完整地分布在AZ31B镁合金表面,膜层中无规分布着微裂纹,膜厚约为9~22 μm;膜层主要成分包括MgO、Mg3(PO4)2及Zn3(PO4)2·xH2O;磷化处理能有效提高AZ31B镁合金的耐模拟体液腐蚀性能.
参考文献
[1] | Waizy, H.;Seitz, J.-M.;Reifenrath, J.;Weizbauer, A.;Bach, F.-W.;Meyer-Lindenberg, A.;Denkena, B.;Windhagen, H..Biodegradable magnesium implants for orthopedic applications[J].Journal of Materials Science,20131(1):39-50. |
[2] | Sannakaisa Virtanen.Biodegradable Mg and Mg alloys: Corrosion and biocompatibility[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,201120(20):1600-1608. |
[3] | Garg,S.;Bourantas,C.;Serruys,P.W..New concepts in the design of drug-eluting coronary stents[J].Nature reviews. Cardiology,20135(5):248-260. |
[4] | Gu XN;Li N;Zhou WR;Zheng YF;Zhao X;Cai QZ;Ruan L.Corrosion resistance and surface biocompatibility of a microarc oxidation coating on a Mg-Ca alloy.[J].Acta biomaterialia,20114(4):1880-1889. |
[5] | Jin-Woo Park;Youn-Jeong Kim;Je-Hee Jang;Chang-Hyeon An.In vitro biocompatibility of magnesium-incorporated submicro-porous titanium oxide surface produced by hydrothermal treatment[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,20103(3):925-931. |
[6] | Tingting Yan;Lili Tan;Dangsheng Xiong;Xinjie Liu;Bingchun Zhang;Ke Yang.Fluoride treatment and in vitro corrosion behavior of an AZ31B magnesium alloy[J].Materials science & engineering, C. Biomimetic and supramolecular systems,20105(5):740-748. |
[7] | Zhang, J.;Dai, C.;Wei, J.;Wen, Z.;Zhang, S.;Chen, C..Degradable behavior and bioactivity of micro-arc oxidized AZ91D Mg alloy with calcium phosphate/chitosan composite coating in m-SBF[J].Colloids and Surfaces, B. Biointerfaces,2013:179-187. |
[8] | 徐丽萍;张二林;杨珂.磷酸钙表面改性镁合金的生物腐蚀性能及细胞相容性[J].中国有色金属学报(英文版),2012(8):2014-2020. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%