A 3d-4f complex [La(DMF)6(H2O)3][Cr(CN)6]*2H2O (DMF=N,N-dimethylformamide) was prepared and characterized by single crystal structure analysis. Single-crystal X-ray diffraction analysis reveals that the present complex contains [Cr(CN)6]3- and [La(DMF)6(H2O)3]3+ ionic pairs. The La(Ⅲ) ion is nine-coordinate, and is coordinated by seven oxygen atoms of three water molecules and six DMF molecules. Each terminal CN ligand of the [Cr(CN)6]3- entity is hydrogen-bonded to oxygen atoms of the coordinated and lattice water molecules producing a three-dimensional network. Crystal data for [La(DMF)5(H2O)3][Cr(CN)6]*2H2O (C24H52CrLaN12O11=875.69): orthorhombic, space group Cmca, with lattice parameters of a=1.9346(2) nm, b=2.8902(2) nm, c=1.4825(2) nm, V=8.289(2) nm3, Z=8, S=1.074, ρcalc=1.403 g*cm-3, R1=0.046, wR2=0.117 based on 244 parameters for 5083 observed (I>2σ(I)) reflections.
参考文献
| [1] | Hulliger F;Landolt M;Vetsch H .Rare-earth ferricyanides and chromicyanides LnT(CN)6*nH2O[J].Journal of Solid State Chemistry,1976(18):283. |
| [2] | Sadaska Y;Traversa E;Sakamoto M.Preparation and characterization of heteromuclear hexacyano complexes LnxSm1-x[Co(CN)6]*nH2O (Ln=La Er and Yb)[J].Chemistry Letters,1996:177. |
| [3] | 石敬民,廖代正,程鹏,姜宗慧,王耕霖,姚心侃,王宏根.氰根桥联配合物GdFe（CN）6·4H2O的合成、结构及磁性研究[J].化学学报,1997(05):467-473. |
| [4] | Yan B;Chen ZD;Wang SX.A novel one-dimensional chain cyano-bridged complex [Sm(DMF)4(H2O)2Mn(CN)6*H2O]n: Long-range magnetic ordering Tc=18 K and coercive force Hc=600 Oe[J].Chemistry Letters,2001(04):350. |
| [5] | Kou HZ.;Liao DZ.;Cheng P.;Jiang ZH.;Yan SP.;Huang XY.;Wang GL.;Yang GM. .A dinuclear cyano-bridged complex based on hexacyanoferrate(III) and samarium(III) nitrate: synthesis and crystal structure[J].Journal of chemical crystallography,1998(4):303-307. |
| [6] | Kautz JA.;Cunningham BP.;Combs RA.;Farmer JM.;Mullica DF. .Synthesis, characterization, and structural analyses of two cyanide-bridged bimetallic complexes[J].Journal of Molecular Structure,2000(0):175-182. |
| [7] | Kou H Z;Gao S;Sun B W et al.Metamagnetism of the first cynao-bridged two-dimensional brick wall-like 4f-3d array[J].CHEMISTRY OF MATERIALS,2001,13:1431. |
| [8] | Kou HZ.;Jin XL.;Gao S. .Synthesis, crystal structure, and magnetic properties of two cyano-bridged bimetallic 4f-3d arrays with one-dimensional chain and two-dimensional brick wall molecular structures[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2001(24):6295-6300. |
| [9] | Combs R A;Farmer J M;Kautz J A .A cyanide-bridged bimetallic complex [CrPr(CN)6(C3H4NO)4(H2O)3]*H2O[J].Acta Crystallographica,2000,C56:1420. |
| [10] | 寇会忠,高松,金祥林.Synthesis and Crystal Structure of Two Cyano-Bridged dimeric 4f-3d Complexes[J].稀土学报(英文版),2002(05):363-365. |
| [11] | Kou HZ;Gao S;Wang RJ .A cyano-bridged dinuclear 4f-3d array.[J].Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications,2002(6):m325-326. |
| [12] | 杨春,郭国聪,马宏伟,刘家成,张星,郑发鲲,林善火,周国伟,毛江高,黄锦顺.一个新颖氰根桥联化合物SmFe（CN）6（DMSO）2·H2O的合成与结构[J].结构化学,2001(03):229-232. |
| [13] | Mascharak P K .Convenient synthesis of tris(te-traethylammonium) hexacyanoferrate(Ⅲ) and its use as an oxidant with tunable redox potential[J].Inorganic Chemistry,1986(25):245. |
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