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通过PCT设备和SEM分析方法研究了Gd2O3和Nd2O3对LiAlH4放氢性能的影响.结果表明,在相同的条件下,掺杂Gd2O3和Nd2O3的LiAlH4显示了非常好的放氢性能.有关掺杂量(0.5,1,2,3,4,5,6)mol%的研究发现,Gd2O3和Nd2O3对LiAlH4放氢量的影响是非常相似的.其影响趋势为:随着掺杂量的增加,LiAlH4放氢量逐步下降,并且试样的放氢起始时间被明显地缩短了.此外,有关掺杂试样的显微组织研究表明,掺杂Gd2O3和Nd2O3对LiAlH4的显微组织的影响不明显.

参考文献

[1] Zhu Ma;M.Y. Chou .First-principles investigation of sodium and lithium alloyed alanates[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):678-683.
[2] Mirna Resan;Michael D. Hampton;Janice K. Lomness;Darlene K. Slattery .Effects of various catalysts on hydrogen release and uptake characteristics of LiAlH_4[J].International journal of hydrogen energy,2005(13/14):1413-1416.
[3] Yoshitsugu Kojima;Yasuaki Kawai;Mitsuru Matsumoto .Hydrogen release of catalyzed lithium aluminum hydride by a mechanochemical reaction[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):275-278.
[4] Zheng Xueping;Li Ping;Islam S. Humail;An Fuqiang;Wang Guoqing;Qu Xuanhui .Effect of catalyst LaCl_3 on hydrogen storage properties of lithium alanate (LiAlH_4)[J].International journal of hydrogen energy,2007(18):4957-4960.
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