稀有金属材料与工程, 2008, 37(6): 1092-1094.
BGA焊球表面状态与微观结构关系的研究
于洋 1, , 史耀武 2, , 夏志东 3, , 环氧树脂固化剂和9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物改性含磷环氧树脂,通过固化剂乳化含磷环氧树脂的方法,制备得到含磷-氮环氧树脂乳液.研究环氧树脂固化剂的中和度及用量对磷改性环氧树脂的乳化性能及形成乳液稳定性的影响,对环氧树脂乳液的阻燃性能和涂膜性能进行考察.实验结果表明,多元胺-环氧加成物水性环氧树脂固化剂在中和度为35％,与含磷环氧树脂混合体系的活泼氢与环氧基摩尔比为1.1∶1理论值时,可以制备得到稳定性良好的含磷氮环氧树脂乳液.当树脂体系磷的质量分数为1.78％,氮的质量分数为5.17％时,其阻燃性能通过UL-94 V0级测试,LOI值可以达到35.5.通过对树脂残炭的扫描电镜表征发现树脂体系是以凝聚相-气相复合阻燃机理,并且含磷-氮环氧树脂乳液涂膜具有优良的综合性能.","authors":[{"authorName":"袁天彪","id":"690a1818-46d9-4030-a4bb-5a39694c80ad","originalAuthorName":"袁天彪"},{"authorName":"徐桂龙","id":"737e1a1d-e797-44e3-8763-e723d1b98646","originalAuthorName":"徐桂龙"},{"authorName":"胡健","id":"2bfcc63a-4249-4bcd-8eb8-e84c25034145","originalAuthorName":"胡健"},{"authorName":"杨进","id":"b9473061-fd2e-4c95-ab15-d188108dd0ec","originalAuthorName":"杨进"}],"doi":"","fpage":"135","id":"0317a9ef-dccf-4fa4-8e4c-147ea3ef93e6","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"a88d7748-fb1d-4b81-9320-543335d77185","keyword":"含磷-氮环氧树脂","originalKeyword":"含磷-氮环氧树脂"},{"id":"132283c0-0398-49b5-9e7d-46c708d7538e","keyword":"乳液","originalKeyword":"乳液"},{"id":"2ff31fb5-79a7-466c-b3ae-8ca69068e2e6","keyword":"阻燃性能","originalKeyword":"阻燃性能"}],"language":"zh","publisherId":"gfzclkxygc201505025","title":"含磷-氮环氧树脂乳液的制备及性能","volume":"31","year":"2015"},{"abstractinfo":"考察了氢氧化铝改性磷-氮环氧树脂复合体系的阻燃性,分析了氢氧化铝的热分解温度和用量对氮-磷环氧树脂阻燃性的影响. 结果表明,氢氧化铝经过热处理,其热分解温度可从195.35 ℃提高到242.15 ℃;在氮-磷环氧树脂体系中,氢氧化铝与环氧树脂的质量比为(77.5～85)∶ 100;树脂中磷的质量分数为2.8%,氮的质量分数为1.6%时,树脂的燃烧等级(UL-94等级)可达到V0等级,氧指数可达36%～37%.","authors":[{"authorName":"李来丙","id":"17470177-b588-471f-a0ff-dc328db30650","originalAuthorName":"李来丙"},{"authorName":"何晓梅","id":"0ea49936-9dfd-4873-9c59-4521b2bcfc92","originalAuthorName":"何晓梅"}],"doi":"10.3969/j.issn.1000-0518.2005.06.016","fpage":"652","id":"0fa27de2-b4a3-4cd3-af59-863bb00f8ecf","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"af7c29e1-4071-43f5-b6d8-254dbbaace38","keyword":"正交试验","originalKeyword":"正交试验"},{"id":"424d9e1e-9455-4167-9264-4faa6ea7ef52","keyword":"阻燃性","originalKeyword":"阻燃性"},{"id":"a307047a-7d34-4592-8ecb-00a2797212dd","keyword":"燃烧等级","originalKeyword":"燃烧等级"},{"id":"689328d5-25b5-42b1-8856-a56158aa3f26","keyword":"氧指数","originalKeyword":"氧指数"}],"language":"zh","publisherId":"yyhx200506016","title":"氢氧化铝-氮-磷环氧树脂体系的阻燃性能","volume":"22","year":"2005"},{"abstractinfo":"本文综述了日本在含磷环氧树脂的研究进展,包括环状有机磷化合物的结构、合成、与环氧树脂反应的机理、含磷环氧树脂合成工艺、阻燃性能以在无卤化阻燃FR-4覆铜板中的应用.","authors":[{"authorName":"祝大同","id":"27decb30-4886-4ee4-b2f3-1ccb29bbfff9","originalAuthorName":"祝大同"}],"doi":"10.3969/j.issn.1009-9239.2004.05.020","fpage":"61","id":"0f1281be-8f75-4db1-8342-bbe1391dc2a8","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"274458f8-1bd4-42f3-86f2-3aa0ab80867c","keyword":"覆铜板","originalKeyword":"覆铜板"},{"id":"e2628b7c-cf00-4839-a9d4-7bc0b70c1d72","keyword":"含磷环氧树脂","originalKeyword":"含磷环氧树脂"},{"id":"be0145b8-6e32-4dbb-87da-50f2c0fdbfc0","keyword":"阻燃","originalKeyword":"阻燃"},{"id":"a04c7096-9c1b-4778-b319-5dba6e297f83","keyword":"无卤化","originalKeyword":"无卤化"}],"language":"zh","publisherId":"jycltx200405020","title":"含磷环氧树脂及其在无卤化覆铜板中的应用","volume":"37","year":"2004"},{"abstractinfo":"综述了含磷环氧树脂固化剂研究的新进展.主要包括胺类含磷固化剂、磷羟基类固化剂及二亚膦酸酯固化剂.介绍了这三类含磷固化剂的典型化学结构以及它们的合成.通过不含磷的环氧树脂比较的基础上,详细陈述了由含磷固化剂制备的环氧树脂的性能,尤其是阻燃性能和耐热性能.对含磷环氧树脂在电气电子领域的应用作了探讨,并对其在今后的研究作了展望.","authors":[{"authorName":"王红娟","id":"e74c468b-0294-4879-856b-35a12f5c8139","originalAuthorName":"王红娟"},{"authorName":"王新龙","id":"4b25b549-c00a-4ef3-ab6b-908c6c6ff185","originalAuthorName":"王新龙"},{"authorName":"王清华","id":"ab58b9bd-fada-4f3a-b67b-a12ee827226e","originalAuthorName":"王清华"}],"doi":"10.3969/j.issn.1009-9239.2005.02.002","fpage":"4","id":"91b7fb15-ab2c-4cbe-b4f9-9a9d8a6773cb","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"97df7fbd-f16d-422d-bb99-252be201a566","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"c440ef57-c02a-4f20-91bf-ee111f65f9b1","keyword":"含磷固化剂","originalKeyword":"含磷固化剂"},{"id":"261998b3-6889-4978-9c57-9a822fe7dcd8","keyword":"阻燃","originalKeyword":"阻燃"},{"id":"b935dc4f-3455-498c-92e6-e6e29f876bca","keyword":"耐热","originalKeyword":"耐热"}],"language":"zh","publisherId":"jycltx200502002","title":"环氧树脂含磷固化剂的合成和应用","volume":"38","year":"2005"},{"abstractinfo":"综述了添加型含磷阻燃改性和反应型含磷阻燃改性方法,重点介绍了反应型含磷阻燃改性方法包括DOPO类、 DOPO衍生物类、氧化磷或磷酸酯类环氧树脂改性及含磷胺类、含磷羟基类、亚磷酸酯固化剂改性.其中,添加型含磷阻燃改性方法的阻燃效果明显且操作简单易行;反应型含磷阻燃改性方法的阻燃效率高、稳定性好,可使环氧树脂体系获得优良的阻燃性能.","authors":[{"authorName":"杨元","id":"3a3e715f-3f1f-4717-9fee-3b0024044f7d","originalAuthorName":"杨元"},{"authorName":"李玲","id":"75e278c0-e02a-4e14-a29d-0ec439003414","originalAuthorName":"李玲"}],"doi":"","fpage":"29","id":"fa263f67-f781-4848-8a91-0fb147b244e0","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"daefd258-fa45-45db-b811-4eeda7474d80","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"f962a3ec-c8fc-475f-8e41-e10c1d48eea8","keyword":"含磷","originalKeyword":"含磷"},{"id":"f4f34169-d0b2-4e26-9330-d60c6c6f49b8","keyword":"阻燃性","originalKeyword":"阻燃性"}],"language":"zh","publisherId":"jycltx201202009","title":"新型含磷阻燃环氧树脂体系的研究进展","volume":"","year":"2012"},{"abstractinfo":"合成了反应型阻燃剂9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO),与环氧树脂反应将阻燃元素磷引入到环氧树脂分子结构中,合成了阻燃的含磷环氧树脂.利用DTA研究了含磷环氧树脂/纳米氢氧化铝(ATH)等组成的阻燃环氧树脂体系的固化反应动力学,表观活化能△E为68.23kJ/mol,反应级数n为0.90.应用TGA初步评价了体系阻燃性能,700℃时成炭率15.73%,计算氧指数为24,初步表明有较好的阻燃效果.","authors":[{"authorName":"王新龙","id":"d768aebd-66df-4e24-a20f-4ba662fc560a","originalAuthorName":"王新龙"},{"authorName":"金花","id":"b81f6691-ab7e-4cec-99e6-b56d93ded225","originalAuthorName":"金花"},{"authorName":"张跃军","id":"df88be6c-d4ec-4011-a983-bd0f7c39cd6d","originalAuthorName":"张跃军"},{"authorName":"朱绪飞","id":"80a7a07c-6a71-48af-a871-a9366ebf76d1","originalAuthorName":"朱绪飞"}],"doi":"10.3969/j.issn.1009-9239.2005.01.005","fpage":"15","id":"64636fa2-5441-496e-8695-757a578c32b9","issue":"1","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"7850f317-99d0-4f4e-b447-8d48cf4125fe","keyword":"含磷环氧树脂","originalKeyword":"含磷环氧树脂"},{"id":"f010039f-f4b7-4a36-a1c8-29f582cb16b4","keyword":"纳米氢氧化铝","originalKeyword":"纳米氢氧化铝"},{"id":"b269aa24-1e3e-46af-a34a-fa0d59d94c5e","keyword":"阻燃","originalKeyword":"阻燃"}],"language":"zh","publisherId":"jycltx200501005","title":"含磷环氧树脂/纳米氢氧化铝阻燃体系的研究","volume":"38","year":"2005"},{"abstractinfo":"介绍了在环氧树脂中引入含硅组分来提高其耐热性和韧性、引入含磷组分改性环氧树脂提高其阻燃性方面的研究进展.","authors":[{"authorName":"季卫刚","id":"ddf1f62d-7ecd-4369-9b4d-0987af740754","originalAuthorName":"季卫刚"},{"authorName":"胡吉明","id":"0c7c579a-0076-4f1c-91b3-b83f3b78522d","originalAuthorName":"胡吉明"},{"authorName":"张鉴清","id":"71f38720-88b1-4325-8680-616700cc43fe","originalAuthorName":"张鉴清"},{"authorName":"曹楚南","id":"16605937-7d76-41e7-a429-6c0a22bffae1","originalAuthorName":"曹楚南"}],"doi":"","fpage":"1","id":"1aefdd09-31fa-48b5-8f36-097f71f232f8","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c3b6c1d7-9ba9-4d07-a5e4-7cf487e998f2","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"dee657ce-3f52-44ba-98c7-efd06400820d","keyword":"改性","originalKeyword":"改性"},{"id":"d267fd39-d04a-4b13-b982-986f619e33e5","keyword":"硅试剂","originalKeyword":"硅试剂"},{"id":"61a1c5af-262e-4560-aaa1-dd29c3064f26","keyword":"磷试剂","originalKeyword":"磷试剂"},{"id":"e997e46f-317f-435f-ad01-2fd161912e1f","keyword":"耐热","originalKeyword":"耐热"},{"id":"729d8ec9-b010-453e-ae5e-82edbb3eba67","keyword":"阻燃","originalKeyword":"阻燃"}],"language":"zh","publisherId":"gfzclkxygc200602001","title":"环氧树脂的磷、硅改性","volume":"22","year":"2006"},{"abstractinfo":"合成了一种含磷阻燃剂2-(二苯基膦酰基)-1,4-苯二酚(DPO-HQ),通过红外光谱、核磁对其化学结构进行了表征.同时,以DPO-HQ和二氨基二苯砜(DDS)为固化剂,双酚A环氧树脂(EP)为基料,制备了不同磷含量的阻燃环氧树脂.利用极限氧指数(LOI)和垂直燃烧实验表征了所得环氧树脂的阻燃性能,通过热重分析,扫描电镜和热红联用分析研究了阻燃环氧树脂的热性能.结果表明,随着磷含量的增加,阻燃环氧树脂的初始降解温度略有降低,但燃烧后残炭率明显增加.阻燃剂的加入抑制了环氧树脂热分解时产生的可燃性气体和自由基,从而形成高温度下比较稳定的炭层.当磷的质量分数为1.5％时,其LOI值可达到30.8％,垂直燃烧性能通过UL 94 V-0等级,表明DPO-HQ可以作为环氧树脂的良好阻燃剂.","authors":[{"authorName":"田秀娟","id":"a329e0b5-552b-4df4-8a8b-92c9b81af0d3","originalAuthorName":"田秀娟"},{"authorName":"王忠卫","id":"689726e6-1f19-47ec-8ab3-f4ae7ec8ff6e","originalAuthorName":"王忠卫"},{"authorName":"于青","id":"14e4f92a-f853-4134-8cdc-28e147b66331","originalAuthorName":"于青"},{"authorName":"高军","id":"03976ec3-f5c1-496b-812c-d0efa92590d0","originalAuthorName":"高军"}],"doi":"","fpage":"31","id":"91a1a9e4-e4c0-4d70-85f2-65bab1974c22","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"8e55ca5d-e504-4bef-86de-1d68cc3a7e3e","keyword":"阻燃剂","originalKeyword":"阻燃剂"},{"id":"ad9648dd-51a8-40a2-8d62-28ca7e2e4c34","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"24eef14f-70c6-49bb-962a-ee895fb89be5","keyword":"固化剂","originalKeyword":"固化剂"},{"id":"a5fae9f2-e50d-4128-a6f4-a118bc928d56","keyword":"阻燃性能","originalKeyword":"阻燃性能"}],"language":"zh","publisherId":"gfzclkxygc201408007","title":"含磷阻燃剂的合成及对环氧树脂阻燃性能的影响","volume":"30","year":"2014"},{"abstractinfo":"分析了氢氧化铝的热分解温度和对氮-磷环氧树脂阻燃性的影响,讨论了氢氧化铝的用量对树脂胶液的燃烧等级、覆铜板抑烟效果的影响.结果表明:氢氧化铝经过特殊处理,其热分解温度从195.35℃提高到242.15℃;在氮-磷环氧树脂体系中,氢氧化铝的用量为20%～30%时树脂的燃烧等级(UL-94等级)可达到V0等级,LOI氧指数可达35%～36%以上,覆铜板的最大烟密度值降低到285.2以下,降低60%以上.利用氢氧化铝的阻燃效果,研制出综合性能比传统的无卤化FR-4环氧树脂覆铜板更好的新一代绿色无卤化覆铜板.","authors":[{"authorName":"李来丙","id":"a9f6e266-08f5-4897-b7fa-7332f906f575","originalAuthorName":"李来丙"},{"authorName":"黄可龙","id":"3a5afd18-531e-4bac-83a4-3b227472c5b2","originalAuthorName":"黄可龙"},{"authorName":"龚必珍","id":"02af5ffb-97f9-4a46-ab76-a24e5c33c54a","originalAuthorName":"龚必珍"}],"doi":"10.3969/j.issn.1000-3738.2005.08.018","fpage":"52","id":"566a8e78-5202-45f1-bf22-3b42ac108085","issue":"8","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"abb341e4-fa27-439a-90f3-39da0e2932e1","keyword":"阻燃性","originalKeyword":"阻燃性"},{"id":"4b38abde-3d28-4ba9-8db0-1bc75b020d6f","keyword":"燃烧等级","originalKeyword":"燃烧等级"},{"id":"21e4af5c-9321-49bf-a036-2f3b4712b7b4","keyword":"LOI氧指数","originalKeyword":"LOI氧指数"},{"id":"f7552872-68c6-40f6-9fc6-105287baf6d7","keyword":"覆铜板","originalKeyword":"覆铜板"}],"language":"zh","publisherId":"jxgccl200508018","title":"氢氧化铝改性氮-磷环氧树脂阻燃性的研究与应用","volume":"29","year":"2005"},{"abstractinfo":"以含磷环氧树脂、甲苯2,4-二异氰酸酯(TDI)、聚醚 N403和端羟基聚丁二烯(HTPB)为反应组分,乙酸乙酯(EA)为溶剂,采用预聚体法合成了不同组分比的含磷环氧树脂/聚氨酯材料。利用全反射红外光谱(ATR-FT-IR)、扫描电子显微镜(SEM-EDS)分别研究了材料的组分含量、相形态和元素分布。结果显示：当含磷环氧树脂质量分数为3.0%时,其结合聚氨酯硬段,以分散相粒子(0~15μm)分布在聚氨酯基体中,并且粒子的含量沿厚度方向梯度递增。进一步通过表面水接触角法(SCA)和拉伸试验测定了材料的表面亲水性和力学性能。结果表明,当材料具有梯度相形态时,上下表面的亲水性差异较大,底表面亲水性更强；并且材料具有相对较高的拉伸强度和断裂伸长率。","authors":[{"authorName":"张学军","id":"752b3c2a-5aef-4e7c-8f6a-3ae6d33ce1b6","originalAuthorName":"张学军"},{"authorName":"陈连喜","id":"1b1df960-56a5-4488-a81e-3291050a9e39","originalAuthorName":"陈连喜"},{"authorName":"任乐","id":"c8d0bfe4-f575-4ce7-9ddf-fc2f318bf874","originalAuthorName":"任乐"},{"authorName":"李曦","id":"20c7d51a-031d-40f3-9a0a-3ba3d48f27be","originalAuthorName":"李曦"}],"doi":"10.11896/j.issn.1005-023X.2015.16.009","fpage":"40","id":"8ac9385d-1219-4a67-84e7-9c5ad422d1d0","issue":"16","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"745eed80-e015-4d37-8a57-4debb6e82adf","keyword":"梯度材料","originalKeyword":"梯度材料"},{"id":"7ce9e227-6413-44ec-82b7-bf77f8a20159","keyword":"含磷环氧树脂","originalKeyword":"含磷环氧树脂"},{"id":"53894c9d-d0bf-4a33-b85f-1de67b3422aa","keyword":"聚氨酯","originalKeyword":"聚氨酯"},{"id":"067e373b-120d-437c-a2b8-8a1fbd90fec3","keyword":"相容性","originalKeyword":"相容性"}],"language":"zh","publisherId":"cldb201516010","title":"含磷环氧树脂/聚氨酯梯度材料的合成与表征?","volume":"","year":"2015"}],"totalpage":2411,"totalrecord":24110}