以2,2-二羟甲基丙酸(DMPA)为亲水扩链剂,聚四氢呋喃二醇(PTMG)和聚己二酯1,4-丁二醇酯(PBA)为软链段,异佛尔酮二异氰酸酯(IPDI)为硬链段,成功制备了固含量50%以上低黏度γ-氨丙基三乙氧基硅烷(KH-550)改性的水性聚氨酯(WPU)乳液.对乳液和胶膜进行了物性表征和研究,分析了KH-550改性WPU的作用机理.实验发现当KH-550加入量为预聚体质量分数2%时,其改性的WPU的综合物性最佳,此时乳液固含量在50%左右,乳液粒径小于130 nm,黏度低于400mPa·s;胶膜的拉伸强度大于35 MPa,断裂伸长率大于750%,吸水率低于5%.
参考文献
[1] | Liu, X.;Xu, K.;Liu, H.;Cai, H.;Su, J.;Fu, Z.;Guo, Y.;Chen, M..Preparation and properties of waterborne polyurethanes with natural dimer fatty acids based polyester polyol as soft segment[J].Progress in Organic Coatings: An International Review Journal,20114(4):612-620. |
[2] | Li, Junpei;Zhang, Xingyuan;Liu, Zheng;Li, Weihu;Dai, Jiabing.Studies on waterborne polyurethanes based on new medium length fluorinated diols[J].Journal of Fluorine Chemistry,2015:12-17. |
[3] | Hou Lijie;Ding Yongtao;Zhang Zhiliang;Sun Zhongsheng;Shan Zhihua.Synergistic effect of anionic and nonionic monomers on the synthesis of high solid content waterborne polyurethane[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2015:46-56. |
[4] | Liang Lei;Zhengbin Xia;Gaohua Cao.Synthesis and adhesion property of waterborne polyurethanes with different ionic group contents[J].Colloid and polymer science,20142(2):527-532. |
[5] | Sauer BB.;Thomas RR.;McLean RS..Tapping mode AFM studies of nano-phases on fluorine-containing polyester coatings and octadecyltrichlorosilane monolayers[J].Langmuir: The ACS Journal of Surfaces and Colloids,199811(11):3045-3051. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%