在实验室条件下,系统研究了1380℃下,钒在FeO-SiO2-MnO渣系与铁液间的分配行为。结果表明:钒的提取率、钒在渣-金两相的分配比、渣的钒容量随渣中SiO2的质量分数升高而降低。在SiO2的质量分数较低时,以上参数随MnO质量分数的增加而升高。而在SiO2的质量分数较高(>20%)时,随MnO质量分数的增加呈现先升高后降低的趋势。FeO-SiO2-MnO三元渣系中,SiO2的质量分数为10%~20%、MnO的质量分数为13%~5%时,以上参数达到最大值,且该区域对应着FeO-SiO2-MnO渣系熔点最低的区域。V2O3在 FeO-SiO2-MnO渣系中活度系数的数量级为10-6~10-7。
Under laboratory conditions, the distribution behavior of vanadium between hot metal and slag system of FeO-SiO2-MnO slag at 1380℃ was studied. The results show:the extraction rate of vanadium from the hot metal, the distribution ratio of vanadium between slag and metal phases, and vanadium capacity of slag decrease with increasing SiO2 content;the parameters mentioned above increase with increasing MnO content in the condition of keeping SiO2 content at lower level, when the SiO2 content is larger than 20% they firstly increase and then decrease with increasing MnO content;in the slag system of FeO-SiO2-MnO, they reach the maximum value in the region of keeping w(SiO2) at 10%-20% and w(MnO) at 13%-25%, which is corresponding to the region of giving the lowest melting point; the magnitude of the activity coefficient of V2O3 in FeO-SiO2-MnO slag system is 10-6-10-7.
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