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为研究钒钛磁铁矿-煤球团还原过程中挥发分作用,开展了N2气氛下分层试样与两类球团非等温热重还原实验.试样的还原度由失重测定.结果发现,煤粉中的挥发分于400℃左右开始挥发.钒钛磁铁矿-非焦煤球团还原过程非常复杂,可分为四个阶段:挥发分挥发产生CO、H2还原球团、挥发分挥发的CO、H2及其碳氢化合物分解产生的C、H2与固体C共同作用还原球团、C经由气化反应媒介作用还原球团、C直接还原球团.挥发分的挥发能提高球团的气孔率和还原性,但影响较小.分析表明,在四个还原阶段中,C的直接还原作用对球团的还原影响最强,球团的还原度提高率可达0.1748%·℃-1.

参考文献

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