介绍了利用配位、自组装和共价键作用合成二维高分子的研究新进展.配位二维高分子采用多齿有机配体和金属离子通过配位作用合成;自组装二维高分子利用氢键、静电、范德华力等非共价作用把分子亚单元组装成二维超分子结构；共价二维高分子采用可逆的共价键合作用,在热力学重组状况下产生二维结构.配位二维高分子和自组装二维高分子的合成路线复杂,骨架稳定性、反应的可靠性和重复性较难保证；而共价二维高分子骨架稳定,易实现多尺度的拓扑结构和孔隙结构.
参考文献
| [1] | Ratner S;Weinberg A;Wachtel E;Moret PM;Marom G .Phase transitions in UHMWPE fiber compacts studied by in situ synchrotron microbeam WAXS[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2004(12):1150-1154. |
| [2] | Kim Tae-il;Baek Jung-un et al.Arginine-conjugated polypropylenimine dendrimer as a non-toxic and efficient gene delivery carrier[J].Biomaterials,2007,28:2061. |
| [3] | JIAYIN YUAN;YOUYONG XU;ANDREAS WALTHER .Water-soluble organo-silica hybrid nanowires[J].Nature materials,2008(9):718-722. |
| [4] | Geim A K;Novoselov K S .Detection of individual gas molecules adsorbed on graphene[J].Nature Materials,2007,6:183. |
| [5] | Tang J B;Shen Y Q et al.Isothermal carbon dioxide sorption in poly(ionic liquid) s[J].Industrial and Engineering Chemistry Research,2009,48:9113. |
| [6] | Song C S .Global challenges and strategies for control,conversion and utilization of CO2 for sustainable development involving energy,catalysis,adsorption and chemical processing[J].Catalysis Today,2006,115:2. |
| [7] | 丁彩霞,曾凡花,汪成,倪佳,伍锡荣,解永树.双（二吡啶胺）配体的二维和三维超分子配位聚合物的合成与晶体结构[J].高等学校化学学报,2011(09):2204-2209. |
| [8] | 隋爱香,徐兴玲,唐宗薰.一类新型的多孔材料--多孔配位聚合物[J].大学化学,2006(04):1-10. |
| [9] | Susumu Kitagawa;Mitsuru Kondo .Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds[J].Bulletin of the Chemical Society of Japan,1998(8):1739-1753. |
| [10] | Kitagawa S;Kitaura R;Noro S .Functional porous coordi nation polymers[J].Angewandte Chemie International Edition,2004,43:2334. |
| [11] | 金强,赵娇,石鑫.3,5-吡啶二羧酸镍配位聚合物的合成与晶体结构[J].高等学校化学学报,2010(08):1496-1501. |
| [12] | 牛艳玲,李秀梅,王志涛.二维配位聚合物[Pb（suc）0.5（phen）2]2n·2nNO3的水热合成及晶体结构[J].通化师范学院学报,2010(08):24-25,30. |
| [13] | 李秀梅.二维配位聚合物[Cd（nicotinate）2（H2O）]n的水热合成、晶体结构及荧光性质[J].化学研究,2005(04):39-41,69. |
| [14] | 李彬,孙跃飞,苟少华,姚景才.间苯二甲酸连接的氢键导致的二维锌配位聚合物的合成及晶体结构[J].无机化学学报,2001(06):917-920. |
| [15] | 杨小丽,张俊,李一志,杜红宾,游效曾.两个二维层状4-双（咪唑基-1-甲基）-苯钴和镍配位聚合物的合成与表征[J].无机化学学报,2010(03):374-378. |
| [16] | 刘宏文,卢文贯.由咪唑-4,5-二羧酸和1,4-双（咪唑基-1-甲基）-苯配体构筑的一个三维镉（Ⅱ）配位聚合物的合成、晶体结构及荧光性质[J].无机化学学报,2011(01):152-156. |
| [17] | 王国平,蔡国强,朱龙观.具二维网格的氟喹诺酮类铜配合物的合成和晶体结构[J].无机化学学报,2000(06):987-990. |
| [18] | Holst JR;Gillan EG .From triazines to heptazines: Deciphering the local structure of amorphous nitrogen-rich carbon nitride materials[J].Journal of the American Chemical Society,2008(23):7373-7379. |
| [19] | Aharonovich, S.;Botoshansky, M.;Waymouth, R.M.;Eisen, M.S. .Chemoselectivity diversity in the reaction of LiNC_6F _5SiMe_3 with nitriles and the synthesis, structure, and reactivity of zirconium mono-and tris[2-(2-pyridyl)tetrafluorobenzimidazolate] complexes[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2010(20):9217-9229. |
| [20] | Bronisz R .1,4-Di(1,2,3-triazol-1-yl)butane as building block for the preparation of the iron(II) spin-crossover 2D coordination polymer[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2005(13):4463-4465. |
| [21] | 李巧铃,BüRGI Thomas,陈辉.金纳米粒子的制备及自组装[J].功能材料与器件学报,2007(06):580-587. |
| [22] | 刘光艳 .氢键诱导的羧酸-胺复合物的制备与结构研究[D].北京化工大学,2010. |
| [23] | 邢丽,张复实,向军辉,杨镜奎.自组装技术及其研究进展[J].世界科技研究与发展,2007(03):39-44. |
| [24] | Comrie J E;Wilhelm T;Huck S .Controlled bending of microscale Au-polyelectrolyte brush bilayers[J].Langmuir,2007,23:1569. |
| [25] | Stupp S I;Son S et al.Nanostructured anisotropic ion-con ductive films[J].Science,1993,259:59. |
| [26] | STUPP S. I.;LEBONHEUR V.;WALKER K.;LI L. S.;HUGGINS K. E.;KESER M.;AMSTUTZ A. .SUPRAMOLECULAR MATERIALS - SELF-ORGANIZED NANOSTRUCTURES[J].Science,1997(5311):384-389. |
| [27] | 李亿保,曾庆祷,汪志辉,戚桂村,关丽,范小林,王琛.利用氢键构筑超分子纳米结构[J].科学通报,2008(07):851-853. |
| [28] | Chen Y;Lu W .Photoresponsive supramolecular organometallic nanosheets induced by Ptπ…Ptπ and C-H…p interactions[J].Angewandte Chemie International Edition,2009,48:9909. |
| [29] | Jorg Schuster;Ralf Kohn;Andreas Keilbach .Two-Dimensional-Hexagonal Periodic Mesoporous Polymer Resin Thin Films by Soft Templating[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(24):5754-5762. |
| [30] | Dai, F.;Dou, J.;He, H.;Zhao, X.;Sun, D. .Self-assembly of metal-organic supramolecules: From a metallamacrocycle and a metal-organic coordination cage to 1D or 2D coordination polymers based on flexible dicarboxylate ligands[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2010(9):4117-4124. |
| [31] | Wei YL;Hou HW;Li LK;Fan YT;Zhu Y .From dicarboxylic acid to tetranuclear metallamacrocyclic complex and 1D and 2D polymers[J].Crystal growth & design,2005(4):1405-1413. |
| [32] | Ding X S;Jiang D L et al.Synthesis of metallophthalocyanine covalent organic frameworks that exhibit high carrier mobility and photoconductivity[J].Angewandte Chemie International Edition,2011,50:1289. |
| [33] | Wan S;Guo J et al.A photoconductive covalent organic framework:Self-condensed arene cubes composed of eclipsed 2D polypyrene sheets for photocurrent generation[J].Angewandte Chemie,2009,12:5547. |
| [34] | Liu, G.;Niu, P.;Sun, C.;Smith, S.C.;Chen, Z.;Lu, G.Q.;Cheng, H.-M. .Unique electronic structure induced high photoreactivity of sulfur-doped graphitic C_3N_4[J].Journal of the American Chemical Society,2010(33):11642-11648. |
| [35] | Sattler, A;Pagano, S;Zeuner, M;Zurawski, A;Gunzelmann, D;Senker, J;Muller-Buschbaum, K;Schnick, W .Melamine-Melem Adduct Phases: Investigating the Thermal Condensation of Melamine[J].Chemistry: A European journal,2009(47):13161-13170. |
| [36] | Jun Y S;Hong W H et al.Mesoporous,2D hexagonal carbon nitride and titanium nitride/carbon composites[J].Advanced Materials,2009,21:4270. |
| [37] | Lin Liu;Ding Ma;Heng Zheng .Synthesis and characterization of microporous carbon nitride[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2008(2/3):216-222. |
| [38] | Miller DR;Holst JR;Gillan EG .Nitrogen-rich carbon nitride network materials via the thermal decomposition of 2,5,8-triazido-s-heptazine[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(7):2767-2774. |
| [39] | Kuhn P;Forget A et al.From microporous regular frameworks to mesoporous materials with ultrahigh surface area:Dynamic reorganization of porous polymer networks[J].Journal of the American Chemical Society,2008,130:13333. |
| [40] | Bojdys, M.J.;Wohlgemuth, S.A.;Thomas, A.;Antonietti, M. .Ionothermal route to layered two-dimensional polymer-frameworks based on heptazine linkers[J].Macromolecules,2010(16):6639-6645. |
| [41] | Bojdys M J;Jeromenok J et al.Rational extension of the family of layered,covalent,triazine-based frameworks with regular porosity[J].Advanced Materials,2010,22:2202. |
| [42] | Bojdys MJ;Muller JO;Antonietti M;Thomas A .Ionothermal Synthesis of Crystalline, Condensed, Graphitic Carbon Nitride[J].Chemistry: A European journal,2008(27):8177-8182. |
| [43] | Holst JR;Gillan EG .From triazines to heptazines: Deciphering the local structure of amorphous nitrogen-rich carbon nitride materials[J].Journal of the American Chemical Society,2008(23):7373-7379. |
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