通过加入十二烷基苯磺酸钠(SDBS)制备了可溶性的聚苯胺/聚乙烯醇掺杂氧化石墨烯导电复合材料.通过XRD、SEM、TEM、FT-IR、TGA、CV对合成的复合材料进行了表征和分析,结果表明聚苯胺/聚乙烯醇能够插入到氧化石墨烯的层间和包裹在氧化石墨烯的表面形成复合物.用十二烷基苯磺酸钠掺杂的聚苯胺/聚乙烯醇/氧化石墨烯材料具有很好的溶解性和导电性能,将复合物进行还原和再次用酸掺杂之后,发现复合材料的导电性得到进一步提升.
参考文献
[1] | Shirakawa H;Louis E J;Maediamid A G et al.Synthesis of dectrically conducting organic polymers:Halogen derivatives of polyacetylene,(CH)x[J].Journal of the Chemical Society,Chemical Communications,1977,16:578. |
[2] | 马利,汤琪.导电高分子材料聚苯胺的研究进展[J].重庆大学学报(自然科学版),2002(02):124-127. |
[3] | Lux F .Properties of electronically conductive polyaniline:A comparision between well-known literature data and some recent experimental findings[J].Polymer,1994,35(14):2915. |
[4] | 李永舫.导电聚合物的电化学性质[J].复旦学报(自然科学版),2004(04):468-476,481. |
[5] | Reghu M;Cao Y;Moses D et al.Metal-insulator transition in polyaniline doped with surfactant counterion[J].Synthetic Metals,1993,57(2-3):5020. |
[6] | 王杏,关荣锋,田大垒,赵文卿.聚苯胺/聚乙烯醇复合材料结构分析[J].辽宁化工,2008(10):701-702,705. |
[7] | 龚文化,曾黎明.聚合物基导电复合材料研究进展[J].化工新型材料,2002(04):38-40. |
[8] | Collins D.E.;Slamovich E.B. .Effect of processing temperature on the morphology of hydrothermally derived barium titanate/polymer thin films[J].Journal of Materials Research,2000(8):1834-1841. |
[9] | Boiteux G;FournierJ;Issotier D et al.Conductive thermoset composites:PTC effect[J].Synthetic Metals,1999,102(1-3):1234. |
[10] | Heng LP;Wang XY;Zhai J;Sun ZW;Jiang L .Fabrication of stable polyaniline foams and their photoelectric conversion behaviors[J].Chemphyschem: A European journal of chemical physics and physical chemistry,2008(11):1559-1563. |
[11] | P. Dutta;S. Biswas;M. Ghosh .The dc and ac conductivity of polyaniline-polyvinyl alcohol blends[J].Synthetic Metals,2001(2):455-461. |
[12] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[13] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atom ically thin carbon films[J].Science,2004,306(5696):666. |
[14] | K. S. Novoselov;D. Jiang;F. Schedin;T. J. Booth;V. V. Khotkevich;S. V. Morozov;A. K. Geim .Two-dimensional atomic crystals[J].Proceedings of the National Academy of Sciences of the United States of America,2005(30):10451-10453. |
[15] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS .Graphene-based composite materials[J].Nature,2006(7100):282-286. |
[16] | 杨永岗,陈成猛,温月芳,杨全红,王茂章.氧化石墨烯及其与聚合物的复合[J].新型炭材料,2008(03):193-200. |
[17] | 邹艳红,吴婧,刘洪波,陈宗璋.聚苯胺/氧化石墨的合成及其在DNA识别上的应用[J].新型炭材料,2005(04):360-364. |
[18] | Seredych M;Pietrzak R;Bandosz TJ .Role of graphite oxide (GO) and polyaniline (PANI) in NO2 reduction on GO-PANI composites[J].Industrial & Engineering Chemistry Research,2007(21):6925-6935. |
[19] | Halina Kaczmarek;Andrzej Podgorski .Photochemical and thermal behaviours of poly(vinyl alcohol)/graphite oxide composites[J].Polymer Degradation and Stability,2007(6):939-946. |
[20] | Bissessur R;Liu P K Y;Scully S F .Intercalation of polypyrrole into graphite oxide[J].Synthetic Metals,2006,156(16-17):1023. |
[21] | Schniepp H C;Li J L;McAllister M J et al.Functionalized single graphene sheets derived from splitting graphite oxide[J].Journal of Physical Chemistry B,2006,110(17):8535. |
[22] | Wang,Jingchao,Wang,Xianbao,Wan,Li,Yang,Yingkui,Wang,Shimin.An Effective Method for Bulk Obtaining Graphene Oxide Solids[J].中国化学(英文版),2010(10):1935-1940. |
[23] | 马文石,周俊文,程顺喜.石墨烯的制备与表征[J].高校化学工程学报,2010(04):719-722. |
[24] | 麻琪 .氧化石墨烯纳米复合膜研究[D].天津大学,2008. |
[25] | C. HONTORIA-LUCAS;A. J. LOPEZ-PEINADO;J. DE D. LOPEZ-GONZALEZ;M. L. ROJAS-CERVANTES;R. M. MARTIN-ARANDA .STUDY OF OXYGEN-CONTAINING GROUPS IN A SERIES OF GRAPHITE OXIDES: PHYSICAL AND CHEMICAL CHARACTERIZATION[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(11):1585-1592. |
[26] | 匡汀.聚苯胺与聚乙烯醇共混相容性研究[J].南华大学学报(自然科学版),2007(01):102-105. |
[27] | 马利,冯利军,甘孟瑜,杜新胜.复合酸掺杂导电聚苯胺的合成及性能[J].应用化学,2008(02):142-146. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%