基于“点击化学”方法，以1，4-二苄基叠氮（XDA）和2，2-二（4．炔丙氧基苯基）丙烷（PBP）（双炔基单体）为单体，采用（Cu（I）从C）作为催化剂，通过高效和高选择性的1，3-环加成点击化学反应，研究一种新型可溶性聚三唑树脂的控制制备；采用红外光谱（FT-IR）、核磁（0H-NMR）、激光光散射（LLS）、X射线衍射（WAXD）、差示扫描量热（DSC）和热重分析（TGA）等方法对其结构与性能进行表征。结果表明，通过单体结构的设计，可以制备出易溶解于普通极性溶剂，玻璃化转变温度134．76℃，熔融温度246．77℃，起始分解温度349．3℃的聚三唑高分子，并对高分子溶解性和热性能的提高进行了讨论与分析。
Using "click chemistry" method, diazide (p-xylylene diazide, XDA) and 2, 2-bis (1, 4- propargyloxybenzeny) propane, PBP) were used as the monomers to prepare poly(1,2,3-triazole) (PTA) resin with high molecular weight using copper( I )-catalyzed azide-alkyne 1,3-dipolar cycloaddition (CuAAC) as catalyst. The structure of resin was characterized by FT-IR, 1H-NMR, GPC, laser light scattering (LLS), WAXD, DSC, DMA and TGA. The results show that the polytriazole has good solubility in common polar solvent, high molecular weight of 6.33 × 10^4 g/mol, glass transition temperature of 134.76℃, melting temperature of 246.77 ℃, and initial decomposition temperature of 349.3 ℃.
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