采用水热法设计并合成了一个新颖的超分子网络化合物[Mn(phen)_2I_2],并对其进行了元素分析,红外光谱分析和X-射线单晶衍射分析.结果表明:该化合物属三斜晶系, P_1~-空间群,晶胞参数为:a=0.92705(19) nm,b=1.0370(2) nm,c=1.2775(3) nm,α=77.32(3) °,β=81.26 (3) °,γ=70.30(3) °,V=1.1240(4) nm~3,Z= 2.该化合物通过四种C-H...I氢键相互作用与两种π-π堆积相互作用把各个独立的结构单元连接成了超分子网络化合物.
A novel supramolecular network [Mn(phen)_2I_2] has been rationally designed and synthesized by hydrothermal method and the structure was characterized with elemental analysis, FT-IR spectrum and X-ray diffractometer. It crystallizes in the Triclinic, space group P_1~-, with a= 0.92705(19) nm,b= 1.0370 (2) nm, c=1.2775(3) nm,α=77.32(3) °, β=81.26(3)°,γ=70.30(3) °,V=1.1240(4) nm~3,Z=2. In the title compound [Mn(phen)_2I_2], the separated unit cells are constructed into a novel supramolecular network by four types of C-H…I hydrogen-bonded and two kinds of π-π interactions.
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