欢迎登录材料期刊网

材料期刊网

高级检索

活性炭(AC)及活性炭纤维(ACF)作为光催化剂载体具有较高的比表面积和较强的吸附性能,可以有效提高负载型光催化剂TiO2/AC和TiO2/ACF对有机污染物的光催化降解效率.首先介绍了TiO2光催化剂的结构特性以及各种掺杂改性方法,对负载型TiO2/AC及TiO2/ACF光催化剂的各种制备方法进行了详细评述.在此基础上,讨论了影响有机污染物光催化降解性能的重要因素,指出了负载型TiO2光催化材料研究中有待解决的问题和发展方向.

Activated carbon (AC) or activated carbon fiber (ACF) can be used as good catalyst support for its high specific surface area and strong adsorption capability.AC and ACF have been paid much attention by many researchers because they can enhance the photocatalytic degradation efficiency of TiO2 for organic contamination.The structure and characteristics of TiO2 photocatalyst and its doping modification method are introduced at first.And then a variety of preparation techniques for TiO2/AC (or TiO2/ACF) supported photocatalytic materials are summarized in detail.Based on this,several important influence factors on the photocatalytic degradation of various contaminations are discussed.The problem of supported TiO2 photocatalyst to be solved and its development direction are pointed out.

参考文献

[1] Tachikawa T;Fujitsuka M;Majima T .Mechanistic insight into the TiO2 photocatalytic reactions: Design of new photocatalysts[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(14):5259-5275.
[2] Tracy L.Thompson;John T. Yates Jr. .Surface Science Studies of the Photoactivation of TiO_2-New Photochemical Processes[J].Chemical Reviews,2006(10):4428-4453.
[3] Yanhui Ao;Jingjing Xu;Degang Fu;Xunwei Shen;Chunwei Yuan .Low Temperature Preparation Of Anatase Tio_2-activated Carbon composite Film[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2008(13):4001-4006.
[4] Liu Y;Yang S;Hong J et al.Low-temperature reparation and microwave photoactivity study of TiO2-mounted activated carbon[J].Journal of Hazardous Materials,2007,142:208.
[5] Xu JJ;Ao YH;Fu DG;Yuan CW .A simple route for the preparation of Eu, N-codoped TiO2 nanoparticles with enhanced visible light-induced photocatalytic activity[J].Journal of Colloid and Interface Science,2008(2):447-451.
[6] 宋绵新,周天亮,王峰.TiO2光催化剂改性掺杂与负载技术研究进展[J].材料导报,2006(08):16-20.
[7] 刘守新;刘鸿.光催化及光电催化基础与应用[M].北京:化学工业出版社,2006:77.
[8] Martra G. .Lewis acid and base sites at the surface of microcrystalline TiO2 anatase: relationships between surface morphology and chemical behaviour[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000(1/2):275-285.
[9] 梅长松,钟顺和.Cu/WO3-TiO2光催化剂的结构与吸光性能研究[J].无机材料学报,2005(06):1396-1402.
[10] 刘畅,暴宁钟,杨祝红,陆小华.过渡金属离子掺杂改性TiO2的光催化性能研究进展[J].催化学报,2001(02):215-218.
[11] 张彭义;余刚;蒋展鹏 .半导体光催化剂及其改性技术进展[J].环境工程学报,1997,5(03):1.
[12] 孙奉玉;吴鸣;李文钊 等.二氧化钛表面光学特性与光催化活性的关系[J].催化学报,1998,19(02):199.
[13] Choi W;Termin A;Hoffmann M R .The role metal ion dopants in quantum-sided TiO2:correlation between photo reactivity and charge carrier recombination dynamics[J].Journal of Physical Chemistry,1994,98(51):13669.
[14] Lin L;Lin W;Xie J et al.Photocatalytic properties of phosphor-doped titania nanoparticles[J].Applied Catalysis B:Environmental,2007,75(1-2):52.
[15] Asahi R;Morikawa T;Ohwaki T et al.Visible light photocatalysis in nitrogen-doped titanium dioxide[J].Science,2001,293:269.
[16] 丛野,肖玲,陈锋,张金龙.氮掺杂改性二氧化钛光催化剂的研究进展[J].感光科学与光化学,2007(02):147-155.
[17] Cong Y;Zhang J;Chen F et al.Preparation,photo catalytic activity,and mechanism of nano-TiO2 co-doped with nitrogen and iron(Ⅲ)[J].Journal of Physical Chemistry C,2007,111(28):10618.
[18] Shuang Song;Jinjun Tu;Lejin Xu;Xing Xu;Zhiqiao He;Jianping Qiu;Jianguo Ni;Jianmeng Chen .Preparation Of A Titanium Dioxide Photocatalyst Codoped With Cerium And Iodine And Its Performance In The Degradation Of Oxalic Acid[J].Chemosphere: Environmental toxicology and risk assessment,2008(9):1401-1406.
[19] Su YL;Zhang XW;Han S;Chen XQ;Lei LC .F-B-codoping of anodized TiO2 nanotubes using chemical vapor deposition[J].Electrochemistry communications,2007(9):2291-2298.
[20] Wu Pingxiao;Tang Jianwen;Dang Zhi .Preparation and photocatalysis of TiO2 nanoparticles doped with nitrogen and cadmium[J].Materials Chemistry and Physics,2007(2/3):264-269.
[21] 邢朋飞,王金淑,金建新,张智强,王政红.S-N共掺杂纳米TiO2可见光光催化剂的制备及其性能研究[J].纳米科技,2007(02):29-33.
[22] Fernhndez A;Lassaletta G;Jimknez V M et al.Preparation and characterization of TiO2 photocatalysts supported on various rigid supports(glass,quartz and stainless steel):Comparative studies of photocatalytic activity in water purification[J].Appl Cataly B:Environmental,1995,7(1-2):49.
[23] A.K. Subramani;K. Byrappa;G.N. Kumaraswamy .Hydrothermal preparation and characterization of TiO_2:AC composites[J].Materials Letters,2007(26):4828-4831.
[24] 陈孝云,刘守新,张显权.活性炭负载N掺杂可见光型TiC2-xNy/AC光催化剂的制备及性能研究[J].无机材料学报,2008(03):464-470.
[25] Yanhui Ao;Jingjing Xu;Degang Fu .A novel magnetically separable composite photocatalyst:Titania-coated magnetic activated carbon[J].Separation and Purification Technology,2008(3):436-441.
[26] 刘守新,陈曦.TiO2/活性炭负载型光催化剂的溶胶-凝胶法合成及表征[J].催化学报,2008(01):19-24.
[27] Ting Guo;Zhipeng Bai;Can Wu .Influence of relative humidity on the photocatalytic oxidation (PCO) of toluene by TiO2 loaded on activated carbon fibers: PCO rate and intermediates accumulation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(2):171-178.
[28] Wang WD;Silva CG;Faria JL .Photocatalytic degradation of Chromotrope 2R using nanocrystalline TiO2/activated-carbon composite catalysts[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(26):470-478.
[29] 梁亮,贾瑛,任强富,张凌.ACF/TiO2复合材料的制备及光催化降解偏二甲肼废水[J].化学推进剂与高分子材料,2008(05):46-49.
[30] Yuan RS;Guan RB;Shen WZ;Zheng JT .Photocatalytic degradation of methylene blue by a combination of TiO2 and activated carbon fibers[J].Journal of Colloid and Interface Science,2005(1):87-91.
[31] B.Tryba;A.W.Morawski;M.Inagaki .A new route for preparation of TiO_2-mounted activated carbon[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):203-208.
[32] Xingwang Zhang;Minghua Zhou;Lecheng Lei .Enhancing the concentration of TiO_2 photocatalyst on the external surface of activated carbon by MOCVD[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2005(11):1899-1904.
[33] Zhang X;Lei L .Effect of preparation methods on the structure and catalytic performance of TiO2/AC photocatalysts[J].Journal of Hazardous Materials,2008,153(1-2):827.
[34] 姜洪泉,王鹏,卢丹丹,吴兰英.Gd3+掺杂TiO2纳米粉体的晶粒尺寸、表面特性和光催化活性[J].化工学报,2006(09):2194-2200.
[35] Xingyi Deng;Yinghong Yue;Zi Gao .Gas-phase photo-oxidation of organic compounds over nanosized TiO_2 photocatalysts by various preparations[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2002(2):135-147.
[36] 刘守新,陈孝云.活性炭孔结构对TiO2/AC复合光催化剂光催化活性的影响[J].物理化学学报,2008(03):533-538.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%