对国内外关于Zr-Sn-Nb-Fe系新锆合金中第二相粒子的研究情况进行评述,并重点探讨不同种类Zr-Nb-Fe 析出相的成分、晶体结构及其形成机制和条件.合金中的Zr-Nb-Fe析出相有两种:一种为六方结构的MgZn2型Zr(Nb,Fe)2 Laves相,其形成与合金中作为杂质存在的Cr元素有关:另一种为立方结构的Ti2Ni型(Zr,Nb)2Fe相,与合金中普遍含有的O元素有关.对大量不同成分的Zr-Sn-Nb-Fe系合金的检测证实,可以用一个由合金中Nb 和Fe含量确定的R(·)参数来分析其成分变化时合金中可能出现的析出相类型.
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