研究了Ce改性的Pt/γ-Al2O3对于富氢气氛下CO选择氧化反应的催化行为考察了制备条件(共沉积沉淀法、分步沉积沉淀法以及沉积沉淀温度)对催化活性的影响结果表明,在80℃时用共沉积沉淀方法制备的催化剂Pt-Ce/γ-Al2O3-CP-80对CO氧化反应表现出良好的活性和选择性,CO转化率在120℃时可以达到85%.利用氢气程序升温还原和原位漫反射红外光谱对不同条件下制备的催化剂进行了表征,分析了Ce的促进作用.
参考文献
[1] | Trimm DL .Minimisation of carbon monoxide in a hydrogen stream for fuel cell application[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1):1-11. |
[2] | Ayastuy JL;il-Rodriguez A;onzalez-Marcos M P;Gutierrez-Ortiz M A .[J].International Journal of Hydrogen Energy,2006,31(15):2231. |
[3] | Manasilp A;Gulari E .[J].Applied Catalysis B:Environmental,2002,37(01):17. |
[4] | Son I H;Shamsuzzoha M;Lane A M .[J].Journal of Catalysis,2002,210(02):460. |
[5] | Arena F;Famulari P;Interdonato N;Bonura G Frusteri F Spadaro L .[J].Catalysis Today,2006,116(03):384. |
[6] | 曲振平 .银催化剂上一氧化碳选择氧化反应的研究[D].中国科学院大连化学物理研究所,2003. |
[7] | Huang Y Q;Wang A Q;Wang X D;Zhang T .[J].International Journal of Hydrogen Energy,2007,32(16):3880. |
[8] | Luo MF;Ma JM;Lu JQ;Song YP;Wang YJ .High-surface area CuO-CeO2 catalysts prepared by a surfactant-templated method for low-temperature CO oxidation[J].Journal of Catalysis,2007(1):52-59. |
[9] | Minemura Y;Ito S;Miyao T;Naito S;Tomishige K;Kunimori K .Preferential CO oxidation promoted by the presence of H-2 over K-Pt/Al2O3[J].Chemical communications,2005(11):1429-1431. |
[10] | Liu X S;orotkikh O;Farrauto R .[J].Applied Catalysis A:General,2002,226(1-2):293. |
[11] | 唐晓兰,张保才,李勇,辛勤,申文杰.用于CO选择氧化反应的新型Pt-Fe/Al2O3催化剂[J].催化学报,2005(01):1-3. |
[12] | Sirijaruphan A;Goodwin J G Jr;Rice R W .[J].Journal of Catalysis,2004,224(02):304. |
[13] | Ko E Y;Park E D;Seo K W;Lee H C Lee D Kim S .[J].Catalysis Letters,2006,110(3-4):275. |
[14] | Yan J;Ma J X;Cao P;Li P .[J].Catalysis Letters,2004,93(1-2):55. |
[15] | 严菁,马建新,周伟,邬敏忠.钴和钾对Pt/γ-Al2O3上CO选择性氧化的助催化作用[J].催化学报,2005(06):489-496. |
[16] | Ince T;Uysal G;Akin A N;Yildirim R .[J].Applied Catalysis A:General,2005,292:71. |
[17] | Son I H;Lane A M .[J].Catalysis Letters,2001,76(3-4):151. |
[18] | Son I H .[J].Journal of Power Sources,2006,159(02):1266. |
[19] | Pozdnyakova O;Teschner D;Wootsch A;Krohnert J;Steinhauer B;Sauer H;Toth L;Jentoft FC;Knop-Gericke A;Paal Z .Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part I: Oxidation state and surface species on Pt/CeO2 under reaction conditions[J].Journal of Catalysis,2006(1):1-16. |
[20] | Nagai Y;Hirabayashi T;Dohmae K;Takagi N Minami T Shinjoh H Matsumoto S .[J].Journal of Catalysis,2006,242(01):103. |
[21] | Wootsch A;Descorme C;Duprez D .[J].Journal of Catalysis,2004,225(02):259. |
[22] | Kepinski L.;Okal J. .Occurrence and mechanism of formation of CeOCl in Pd/CeO2 catalysts[J].Journal of Catalysis,2000(1):48-53. |
[23] | Gracia F J;Miller J T;Kropf A J;Wolf E E .[J].Journal of Catalysis,2002,209(02):341. |
[24] | Rajaram R R;Hayes J W;Ansell G P;Hatcher H A .[P].US 5993762,1999. |
[25] | Tiernan M J;Finlayson O E .[J].Applied Catalysis B:Environmental,1998,19(01):23. |
[26] | Yeung C M;Yu K M;Fu Q J;Thompsett D Petch M I Tsang S C .[J].Journal of the American Chemical Society,2005,127(51):18010. |
[27] | Golunski S;Rajaram R;Hodge N;Hutchings G J Kiely C J .[J].Catalysis Today,2002,72(1-2):107. |
[28] | 辛勤;张慧;薛俊;郭燮贤 .[J].催化学报,1981,2(02):100. |
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