<正> 非晶态金属在升温过程中体积膨胀、过剩自由体积减少及重新分配同时发生,在比较高的温度还出现玻璃转变和结晶过程,致使长度较一般金属材料发生更复杂的变化。非晶态金属的膨胀特点很像氧化物玻璃。为了进一步认识其膨胀规律,本文用拉伸法测量了6种Pd-Si基金属玻璃的膨胀过程。 非晶态合金条带在离心铜转鼓上获得,宽0.5mm左右,厚0.03mm左右。被测样品采取淬火态(经室温长期稳定化)和退火态(以10℃/min的速度升温至玻璃转变温度之后冷却到室温)。 因为非晶条带很薄,热膨胀需用拉伸法测量,装置如文献[5]中描述。样品的有效长度为30mm。用温度程序控制器控温,全部实验采用升温速率为10℃/min,流动氩气保护。拉伸负
The volume effect of 6 PdSi-base amorphous alloys on heating has been measured by a tension method. The fractional free volume of 3 ternary alloys at the glass transition temperature is calculated to be 0.02—0.03 which is approaching the value 0.025 of ordinary amorphous materials. The relationship between free volume increment of 6 materials in equilibrium state and relative viscosity is consistent with the viscous flow free volume model.
参考文献
| [1] | |
| [2] | |
| [3] | |
| [4] | |
| [5] | |
| [6] | |
| [7] | |
| [8] | |
| [9] | |
| [10] | |
| [11] | |
| [12] | |
| [13] | |
| [14] | |
| [15] | |
| [16] |
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