活性炭(AC)优良的物化性质不仅利于反应物分子的扩散与吸附,还利于过氧化氢(H2O2)催化分解产生羟基自由基(·OH),进而促进氧化反应的进行,在AC-H2O2体系中,二者甚至可以产生协同效应,增强难降解有机污染物的去除功效.综述了AC催化H2O2处理水中有机污染物的研究进展,分析了AC-H2 O2、AC-Fe2+-H2O2(-微波/UV),以及AC作为载体的非均相Fenton催化剂体系影响因素,探讨了它们的反应机制,并总结与展望了AC-H2 O2体系存在的问题及发展前景.
参考文献
| [1] | 杨鑫,杨世迎,邵雪停,王雷雷,牛瑞.活性炭催化过氧化物高级氧化技术降解水中有机污染物[J].化学进展,2010(10):2071-2078. |
| [2] | Mezohegyi Gergo;van der Zee Frank P;Font Josep et al.Towards advanced aqueous dye removal processes:A short review on the versatile role of activated carbon[J].J Env Manage,2012,102:148. |
| [3] | 余国贤,陈辉,陆善祥,朱中南.活性炭在过氧化氢氧化脱除二苯并噻吩中的催化作用[J].华东理工大学学报（自然科学版）,2006(01):1-6. |
| [4] | Mahmoodi Niyaz Mohammad;Salehi Raziyeh;Arami Mokhtar .Binary system dye removal from colored textile wastewater using activated carbon:Kinetic and isotherm studies[J].Desalination,2011,272(1-3):187. |
| [5] | FJ. Rivas;M. Carbajo;F. Beltran;O. Gimeno;J. Frades .Comparison of different advanced oxidation processes (AOPs) in the presence of perovskites[J].Journal of hazardous materials,2008(3):407-414. |
| [6] | Aktas Ozgur;Cecen Ferhan .Bioregeneration of activated carbon: A review[J].International Biodeterioration & Biodegradation,2007(4):257-272. |
| [7] | Haw Kok-Giap;Bakar Wan Azelee Wan Abu;Ali Rusmidah et al.Catalytic oxidative desulfurization of diesel utilizing hydrogen peroxide and functionalized-activated carbon in a biphasic diesebacetonitrile system[J].Fuel Process Techn,2010,91(09):1105. |
| [8] | Ahmed Reda Yeddou;Boubakeur Nadjemi;Farid Halet .Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of activated carbon prepared from olive stones[J].Minerals Engineering,2010(1):32-39. |
| [9] | Georgi Anett;Kopinke Frank-Dieter .Interaction of adsorption and catalytic reactions in water decontamination processes part Ⅰ.Oxidation of organic contaminants with hydrogen peroxide catalyzed by activated carbon[J].Applied Catalysis B:Environmental,2005,58(1-2):9. |
| [10] | Khorramfar Shooka;Mahmoodi Niyaz Mohammad;Arami Mokhtar et al.Oxidation of dyes from colored wastewater using activated carbon/hydrogen peroxide[J].Desalination,2011,279(1-3):183. |
| [11] | Karthikeyan S;Titus A;Gnanamani A et al.Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes[J].Desalination,2011,281:438. |
| [12] | 涂勇,张洪玲,张龙,刘广兵,许明,张敏健.Fenton氧化-活性炭吸附耦合处理焦化废水生化尾水的研究[J].污染防治技术,2010(01):26-29. |
| [13] | Jiang Wenxin;Zhang Wei;Li Bingjing et al.Combined Fenton oxidation and biological activated carbon process for recycling of coking plant effluent[J].Journal of Hazardous Materials,2011,189(1-2):308. |
| [14] | Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions - A review[J].Applied clay science,2010(3/4):182. |
| [15] | Yu Yang;Peng Wang;Shujie Shi;Yuan Liu .Microwave enhanced Fenton-like process for the treatment of high concentration pharmaceutical wastewater[J].Journal of hazardous materials,2009(1):163-167. |
| [16] | 王杰,马溪平,唐凤德,杨春璐,李悦,郭斌.微波催化氧化法预处理垃圾渗滤液的研究[J].中国环境科学,2011(07):1166-1170. |
| [17] | Leticia F. Velasco;Isabel M. Fonseca;Jose B. Parra .Photochemical behaviour of activated carbons under UV irradiation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(1):249-258. |
| [18] | Kusvuran Erdal;Erbatur Oktay .Degradation of aldrin in adsorbed system using advanced oxidation processes:Comparison of the treatment methods[J].Journal of Hazardous Materials,2004,106(2-3):115. |
| [19] | A. Rodriguez;G. Ovejero;J. L. Sotelo .Heterogeneous Fenton Catalyst Supports Screening for Mono Azo Dye Degradation in Contaminated Wastewaters[J].Industrial & Engineering Chemistry Research,2010(2):498-505. |
| [20] | Fontecha-Cámara M A;(A)lvarez-Merinoa M A et al.Heterogeneous and homogeneous Fenton processes using activated carbon for the removal of the herbicide amitrole from water[J].Applied Catalysis B:Environmental,2011,101(3-4):425. |
| [21] | 李建旭,韩永忠,吴晓根,许垚艺.Fe2+/活性炭非均相Fenton试剂氧化法降解苯酚[J].化工环保,2011(04):361-364. |
| [22] | Santos V P;Pereira M F R et al.Decolourisation of dye solutions by oxidation with H2O2 in the presence of modified activated carbons[J].Journal of Hazardous Materials,2009,162(2-3):736. |
| [23] | Gomes Helder T;Machado Bruno F;Ribeiro Andreia et al.Catalytic properties of carbon materials for wet oxidation of aniline[J].Journal of Hazardous Materials,2008,159(2-3):420. |
| [24] | 孙大贵,陶长元,刘作华,杜军,刘仁龙.活性炭-Fenton组合法去除水中PAEs的研究[J].环境科学,2007(12):2734-2739. |
| [25] | Ramirez JH;Maldonado-Hodar FJ;Perez-Cadenas AF;Moreno-Castilla C;Costa CA;Madeira LM .Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalysts[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(3/4):312-323. |
| [26] | Dantas T L P et al.Treatment of textile wastewater by heterogeneous Fenton process using a new composite Fe2O3/carbon[J].Chemical Engineering Journal,2006,118(1-2):77. |
| [27] | Cinthia S. Castro;Mario C. Guerreiro;Maraisa Goncalves;Luiz C.A. Oliveira;Alexandre S. Anastacio .Activated carbon/iron oxide composites for the removal of atrazine from aqueous medium[J].Journal of hazardous materials,2009(2/3):609-614. |
| [28] | Liao, Q;Sun, J;Gao, L .Degradation of phenol by heterogeneous Fenton reaction using multi-walled carbon nanotube supported Fe2O3 Catalysts[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2009(1/3):95-100. |
| [29] | Nguyen Thi Dung;Phan Ngoc Hoa;Do Manh Huy et al.Magnetic Fe2 MO4 (M:Fe,Mn) activated carbons:Fabrication,characterization and heterogeneous Fenton oxidation of methyl orange[J].Journal of Hazardous Materials,2011,185(2-3):653. |
| [30] | Rey A;Zazo J A;Casas J A et al.Influence of the structural and surface characteristics of activated carbon on the catalytic decomposition of hydrogen peroxide[J].Applied Catalysis A:General,2011,402(1-2):146. |
| [31] | Song Wei;Li Yong;Guo Xiaohui et al.Selective surface modification of activated carbon for enhancing the catalytic performance in hydrogen peroxide production by hydroxylamine oxidation[J].Journal of Molecular Catalysis A:Chemical,2010,328(1-2):53. |
| [32] | Altai Bach;Raphael Semiat .The role of activated carbon as a catalyst in GAC/iron oxide/H2O2 oxidation process[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2011(1):57-63. |
| [33] | Gomes Helder T;Miranda Sandra M;Sampaio Maria J et al.Activated carbons treated with sulphuric acid:Catalysts for catalytic wet peroxide oxidation[J].Catalysis Today,2010,151(1-2):153. |
| [34] | Rivera-Utrilla J;Sánchez-Polo M et al.Activated carbon modifications to enhance its water treatment applications.An overview[J].Journal of Hazardous Materials,2011,187(1-3):1. |
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