Predbaration and properties of polymeric colloidal crystals containing rare earth complexes

稀土学报(英文版), 2008, 26(6): 932-934.

^1, , ^2, , ^3, , ^4, , ^5, , ^6, , ^7, , ^8, , ^9, , ^10,

1.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

2.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

3.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

4.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

5.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

6.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

7.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

8.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

9.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

10.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

基金项目: 国家重点基础研究发展计划(973计划)(2007CB936403) 国家自然科学基金(20674026;20504011;20534040) 教育部长江学者和创新团队发展计划基金

Predbaration and properties of polymeric colloidal crystals containing rare earth complexes

JIANG Yingnan ^1, , LI Hui ^2, , MENG Xuesong ^3, , ZHAO Dengfeng ^4, , WANG Yingyu ^5, , LIU Qi ^6, , ZHENG Jing ^7, , ZHANG Junhu ^8, , LIN Quan ^9, , YANG Bai ^10,

1.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

2.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

3.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

4.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

5.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

6.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

7.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

8.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

9.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

10.State Key laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China

Keywords： nanospheres

Rare earth organic complexes were introduced into the polymerization system, and the polymeric colloidal nanospheres containing rare earth complexes were prepared by emulsion copolymerization. The characterization results indicated that the polymeric spheres were small at nanometer size and the diameter was monodisperse, particularly the nanospheres possessed good fluorescent properties. Moreover, the polymeric nanospheres were self-assembled to fabricate the colloidal crystals, which were three-dimensional regular multilayer films. The polymeric colloidal crystal films exhibited excellent luminescent and novel optical properties.

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