在工业氮气(N2)气氛条件下制备了锂掺杂铌酸钾钠(NKLN)无铅压电陶瓷,研究了Li掺杂量对陶瓷相结构、微观结构及电学性能的影响.结果表明,NKLN陶瓷具有钙钛矿结构,随Li含量的增加,陶瓷在室温下出现了从斜方相到四方相的转变;当Li含量为7%(摩尔分数)时,陶瓷具有优良的电学性能,压电常数(d33)、机电耦合系数(kp)和剩余极化强度(Pr)分别为223pC/N、38.2%和12.11μC/cm2;陶瓷的居里温度Tc随着Li含量的增加而升高,当Li含量为6%(摩尔分数)时为420℃,Li含量为8%(摩尔分数)时为480℃.
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