利用XRD及XRD极图技术表征了用激光剥离技术生长的VO2薄膜.结果表明:在衬底温度为500℃,氧气偏压6.67Pa的条件下,在Al2O3(1120)衬底上能实现VO2的二维外延生长.薄膜的结构除了与沉积工艺有关外,还和衬底的取向密切相关.在Al2O3(1120)衬底上,定向生长的(100)VO2在Millar指数<5时,除了[010]以外,不存在其他晶格矢量与衬底相匹配,从而不可能实现三维单晶薄膜的外延生长.电学特性的测试结果显示,在温度为65℃左右,VO2薄膜出现相交,薄膜的电阻率变化达4个数量级.
Vanadium Dioxide(VO2) thin films deposited on(1120) sapphire substrates by pulsed laser ablation were characterized by using the techniques of XRD,
XRD pole figure,RBS/channeling and electrical measurements.The results show that VO2 thin film on the (1120) sapphire grows epitaxially
with out-of-plane:(100)VO2//(1120)sapphire and in-plane: VO2[010]//sapphire[0001].Channeling cannot be found in RBS/Channeling analysis,indicating that the film
fails to single crystalline growth. The further analysis of the crystallography of the (100)VO2 reveals that within 5 1attice periods,no other lattice vector
exists in the (100) plane of VO2 to match the lattice of sapphire,therefore,it is impossible to deposit single
参考文献
[1] | Morin F J. Phys.Rev.Lett., 1959, 3: 4 2 Becker M F,Buckman A B, Walser R M. Appl. Phys. Lett., 1994, 65: 1507 3 Kuznetsov V A, Haneman G. J. App1. Phys., 1996, 79 (10): 8109 4 Roach W R, Balbery ? Solid State Conmmun., 1971, 9: 551 5 Lampert C M, Granquivist C G, ed, Large-area chromogenis?: Materials and Devices for Transmittance Control, 1990, 154: (SPIE Optical Engineeing Press Bu11ingham) 6 Manabe I,Fujimoto F,Yamaguchi I, et al. Thin Solid Films, 1998, 323: 99 7 Moon B K, Ishiwara H. App1. Phys. Lett., 1995, 67, 1996 8 Sambi M?Sangiovanni G,Granozzi G, et al. phys. Rev. B, 1997, 55: 7850 9 Borek M,Qian F, Nagabushnam V, et al. App1. Phys. Lett? 1993, 63: 3288 10 Kim D K, Kwok H S. App1. Phys. Lett., 1994, 65: 3188 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%