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In this paper, the effects of Sn and Hf additions on microstructures and room temperature mechanical properties of Nb-20Ti-5Cr-3Al-18Si alloy were investigated. The Sn addition has no significant effect on the microstructure of the alloy. Sn is preferentially partitioned in (Nb, Ti)ss rather than (Nb, Ti)(5)Si(3). The addition of Sn decreases the solubility of Cr in (Nb, Ti)ss. The addition of Hf causes coarsening of the eutectic structure of (Nb, Ti)ss and (Nb, Ti)(5)Si(3) and the formation of the Hf-rich gamma(Nb, Ti)(5)Si(3) along phase boundaries. With the addition of Sn the strength of the alloy decreases, while its ductility increases slightly. The Hf addition simultaneously improves strength and ductility of the alloy. The relationships between composition, microstructure and properties are discussed.

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