欢迎登录材料期刊网

材料期刊网

高级检索

为了获得对三硝基甲苯(TNT)红水中有机物能有效富集的材料并研究其富集机理,通过对层间为碳酸根的MgFe层状双氢氧化物(MgFe-LDH)煅烧制备了镁铁氧化物复合物(MgFeO),而后在TNT红水中重构实现了对TNT红水中有机物的富集.并且MgFeO在以十二烷基苯磺酸钠(SDBS)、十二烷基磺酸钠(SDS)、对甲苯磺酸(PTS)、TNT水溶液为TNT红水模拟水中重构,研究其对有机物的富集机理.结果表明,TNT红水中有机物浓度越高,每克煅烧产物对TNT红水COD去除量越大,在研究范围内最高达到58 mg/g,且有机物疏水程度越高,越易于被富集,有机磺酸盐的长链结构有利于被富集,但此类物质强的表面活性会使重构产物表面形成FeOOH相.

参考文献

[1] Guo, X.;Zhang, F.;Evans, D.G.;Duan, X. .Layered double hydroxide films: Synthesis, properties and applications[J].Chemical communications,2010(29):5197-5210.
[2] Wang GA;Wang CC;Chen CY .The disorderly exfoliated LDHs/PMMA nanocomposite synthesized by in situ bulk polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(14):5065-5074.
[3] Crepaldi EL.;Tronto J.;Cardoso LP.;Valim JB. .Sorption of terephthalate anions by calcined and uncalcined hydrotalcite-like compounds[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(2/3):103-114.
[4] A. Rodriguez;G. Ovejero;J. L. Sotelo .Heterogeneous Fenton Catalyst Supports Screening for Mono Azo Dye Degradation in Contaminated Wastewaters[J].Industrial & Engineering Chemistry Research,2010(2):498-505.
[5] L.F. Liotta;M. Gruttadauria;G. Di Carlo;G. Perrini;V. Librando .Heterogeneous Catalytic Degradation Of Phenolic Substrates: Catalysts Activity[J].Journal of hazardous materials,2009(2/3):588-606.
[6] Liana Kentjono;J.C. Liu;W.C. Chang .Removal of boron and iodine from optoelectronic wastewater using Mg-Al (NO3) layered double hydroxide[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2010(1/3):280-283.
[7] Yoshioka T;Kameda T;Miyahara M et al.Removal of tetrafluoroborate ion from aqueous solution using magnesium-aluminum oxide produced by the thermal decomposition of a hydrotalcite-like compound[J].Chemosphere,2007,69(05):832-835.
[8] 周军,郭新超,金奇庭,黄永勤.生化法处理炸药废水研究进展[J].中国给水排水,2000(09):50-52.
[9] Kubota A;Maeda T;Nagafuchi N;Kadokami K;Ogawa HI .TNT biodegradation and production of dihydroxylamino-nitrotoluene by aerobic TNT degrader Pseudomonas sp. strain TM15 in an anoxic environment.[J].Biodegradation,2008(6):795-805.
[10] Octavio Cruz-Uribe;Donald P. Cheney;Gregory L. Rorrer .Comparison of TNT removal from seawater by three marine macroalgae[J].Chemosphere: Environmental toxicology and risk assessment,2007(8):1469-1476.
[11] Fangfang Wei;Yihe Zhang;Fengzhu Lv;Paul K. Chu;Zhengfang Ye.Extraction of organic materials from red water by metal-impregnated lignite activated carbon[J].Journal of hazardous materials,2011:352-360.
[12] Qingwei Zhu;Yihe Zhang;Fengshan Zhou .Preparation and characterization of Cu2O-ZnO immobilized on diatomite for photocatalytic treatment of red water produced from manufacturing of TNT[J].Chemical engineering journal,2011(1):61-68.
[13] Zhaoping Liu;Renzhi Ma;Minoru Osada;Nobuo lyi;Yasuo Ebina .Synthesis,Anion Exchange,and Delamination of Co-Al Layered Double Hydroxide:Assembly of the Exfoliated Nanosheet/Polyanion Composite Films and Magneto-Optical Studies[J].Journal of the American Chemical Society,2006(14):4872-4880.
[14] 黄军荣,陈进富,吴芳云.采油污水中化学药剂对COD的影响及可生化性研究[J].油气田环境保护,2002(04):1-3.
[15] 张慧,齐荣,段雪.镁铁和镁铝双羟基复合金属氧化物的结构和性能差异[J].无机化学学报,2002(08):833-838.
[16] Synthesis and transformation of iron-based layered double hydroxides[J].Applied clay science,2010(1/2):195.
[17] Chitrakar R;Sonoda A;Makita Y et al.Synthesis and bromate reduction ofsulfateintercalated Fe(II)-Al(Ⅲ) layered double hydroxides[J].Separation and Purification Technology,2011,80(03):652-657.
[18] 杨勇 .铁氧化物纳米粒子的结构、形貌调控及载药磁流体的制备和性质研究[D].华东师范大学,2008.
[19] Guo Y;Zhang H;Zhao L;Li GD;Chen JS;Xu L .Synthesis and characterization of Cd-Cr and Zn-Cd-Cr layered double hydroxides intercalated with dodecyl sulfate[J].International Journal of Quantum Chemistry,2005(6):1830-1836.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%