研究了宏观整平剂、微观整平剂及电流密度对铜微凸点表面平整性的影响,探讨了2种整平剂和电流密度对铜微凸点表面的作用机制.镀液组成和工艺参数为:CuSO475 g/L,H2SO4100 g/L,Cl-50 mg/L,整平剂H和W0~10 mg/L,(25±2)℃,60 r/min,1~8A/dm2,35 min.结果表明,宏观整平剂可促进铜的沉积,微观整平剂则可抑制铜的沉积,二者相互配合可改变电镀过程中镀孔的电力线分布,使电流密度分布均匀.在一定范围内提高电流密度可加快铜微凸点的生长.在6 A/dm2下,2种整平剂的质量浓度均为5 mg/L时,可制得结晶细腻、表面平整的铜微凸点.
参考文献
[1] | K. M. Chen;T. S. Lin .Copper pillar bump design optimization for lead free flip-chip packaging[J].Journal of Materials Science. Materials in Electronics,2010(3):278-284. |
[2] | Pradeep Dixit;Chee Wee Tan;Luhua Xu;Nay Lin;Jianmin Miao;John H. L. Pang;Petra Backus;Robert Preisser .Fabrication and characterization of fine pitch on-chip copper interconnects for advanced wafer level packaging by a high aspect ratio through AZ9260 resist electroplating[J].Journal of Micromechanics and Microengineering,2007(5):1078-1086. |
[3] | EBERSBERGER B;LEE C.Cu pillar bumps as a lead-free drop-in replacement for solder-bumped,flip-chip interconnects[A].,2008:59-66. |
[4] | Hou jun Hsu;Jung Tang Huang;Pe Shan Chao;Sheng Hsiung Shih .Surface modification on plating-based Cu/Sn/0.7Cu lead-free copper pillars by using polishing[J].Microelectronic engineering,2008(7):1590-1596. |
[5] | HUANG M;YEOW O G;POO C Y.A study on copper pillar interconnect in flip-chip-on-module packaging[A].,2007:325-330. |
[6] | Mark Huang;Ong Gee Yeow;Chia Yong Poo;Tom Jiang .Intermetallic Formation of Copper Pillar With Sn-Ag-Cu for Flip-Chip-On-Module Packaging[J].IEEE transactions on components and packaging technologies: A publication of the IEEE Components, Packaging, and Manufacturing Technology Society,2008(4):767-775. |
[7] | KEIGLER A;WU B;ZHANG J.Pattern effects on electroplated copper pillars[A].,2006:1-21. |
[8] | LEE S;GUO Y X;ONG C K.Electromigration effect on Cu-pillar (Sn)bumps[A].,2005:7-9. |
[9] | PANG J H L;WONG S C K;NEO S K.Thermal cycling fatigue analysis of copper pillar-to-solder joint reliability[A].,2008:743-748. |
[10] | SAY K;YOO S;SHIN Y S.Joint properties of solder capped copper pillars for 3D packaging[A].,2010:2019-2024. |
[11] | TUMMALA R R;MARKONDEYA RAJ P;AGGARWAL A.Copper interconnections for high performance and fine pitch flip chip digital applications and ultra-miniaturized RF module applications[A].,2006:102-111. |
[12] | WANG T;TUNG F;FOO L.Studies on a novel flip-chip interconnect structure.Pillar bump[A].,2001:945-949. |
[13] | 刘忠安.光刻工艺参数的优化方法[J].半导体光电,2001(01):52-53,61. |
[14] | 邓涛,李平,邓光华.光刻工艺中缺陷来源的分析[J].半导体光电,2005(03):229-231. |
[15] | 来五星,轩建平,史铁林,杨叔子.微制造光刻工艺中光刻胶性能的比较[J].半导体技术,2004(11):22-25. |
[16] | T. P. Moffat;D. Wheeler;D. Josell .Electrodeposition of Copper in the SPS-PEG-Cl Additive System/I. Kinetic Measurements: Influence of SPS[J].Journal of the Electrochemical Society,2004(4):C262-C271. |
[17] | Wei-Ping Dow;Her-Shu Huang;Zack Lin .Interactions Between Brightener and Chloride Ions on Copper Electroplating for Laser-Drilled Via-Hole Filling[J].Electrochemical and solid-state letters,2003(9):C134-C136. |
[18] | Yang Cao;Premratn Taepbaisitphongse;Radek Chalupa .Three-Additive Model of Superfilling of Copper[J].Journal of the Electrochemical Society,2001(7):C466-C472. |
[19] | Min Tan;John N. Harb .Additive Behavior during Copper Electrodeposition in Solutions Containing Cl~- PEG, and SPS[J].Journal of the Electrochemical Society,2003(6):C420-C425. |
[20] | HEALY J P;PLETCHER D;GOODENOUGH M .The chemistry of the additives in an acid copper electroplating bath:Part Ⅰ.Polyethylene glycol and chloride ion[J].Journal of Electroanalytical Chemistry,1992,338(1/2):155-165. |
[21] | Andricacos PC.;Dukovic JO.;Horkans J.;Deligianni H.;Uzoh C. .Damascene copper electroplating for chip interconnections[J].IBM journal of research and development,1998(5):567-574. |
[22] | Tyler Osborn;Nefertari Galiba;Paul A. Kohl .Electroless Copper Deposition with PEG Suppression for All-Copper Flip-Chip Connections[J].Journal of the Electrochemical Society,2009(7):226-230. |
[23] | Aaron Frank;Allen J. Bard .The Decomposition of the Sulfonate Additive Sulfopropyl Sulfonate in Acid Copper Electroplating Chemistries[J].Journal of the Electrochemical Society,2003(4):C244-C250. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%