利用石墨烯纳米(GNs)片作为载体,将钛酸四正丁酯包裹Fe3O4纳米粒子的微乳液通过搅拌和超声负载于其表面或镶嵌于其二维结构的片层间,制备GNs/Fe3O4/TiO2磁性复合光催化材料.通过FrIR、SEM、TEM、EDX、XRD、VSM等手段对样品进行了表征,并对其光催化机理进行了分析.测试结果表明,TiO2含量对复合材料的光催化性能有显著影响,对对硝基苯酚和罗丹明B的光催化降解率最高分别可达96.0%和98.3%.
参考文献
[1] | Bitao Liu;Yongji Huang;Yan Wen.Highly dispersive {001} facets-exposed nanocrystalline TiO2 on high quality graphene as a high performance photocatalyst[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201215(15):7484-7491. |
[2] | Stuart Linley;YingYing Liu;Carol J. Ptacek.Recyclable Graphene Oxide-Supported Titanium Dioxide Photocatalysts with Tunable Properties[J].ACS applied materials & interfaces,20147(7):4658-4668. |
[3] | Xuan Pan;Yong Zhao;Shu Liu.Comparing Graphene-TiO2 Nanowire and Graphene-TiO2 Nanoparticle Composite Photocatalysts[J].ACS applied materials & interfaces,20128(8):3944-3950. |
[4] | Sergio Morales-Torres;Luisa M. Pastrana-Martinez;Jose L. Figueiredo.Design of graphene-based TiO_2 photocatalysts—a review[J].Environmental Science and Pollution Research,20129(9):3676-3687. |
[5] | Huilu Wu;Furong Shi;Xiaoli Wang.Synthesis, crystal structures, antioxidant activities and DNA-binding studies of two manganese(II) complexes with 1,3-bis(1-ethylbenzimidazol-2-yl)-2-oxopropane ligands[J].Transition Metal Chemistry,20143(3):261-270. |
[6] | WEN-KUI DONG;Y1N-X1A SUN;XIU-YAN DONG.Zinc(Ⅱ) and copper(Ⅱ) complexes containing asymmetrical Salamo-type ligands: syntheses, crystal structures, and spectroscopic behaviors[J].Journal of Coordination Chemistry,201317/18(17/18):3291-3304. |
[7] | Cao, Yuan-Cheng;Fu, Zhongtian;Wei, Wenjun;Zou, Linling;Mi, Tie;He, Dan;Yan, Chaolu;Liu, Xiyou;Zhu, Ying;Chen, Liuqing;Sun, Yuanjie.Reduced graphene oxide supported titanium dioxide nanomaterials for the photocatalysis with long cycling life[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2015Nov.15(Nov.15):1289-1294. |
[8] | Chun Zhang;Ruibin Guo;Zunli Mo.Synthesis of Fe3O4 Nanoparticles Using Controlled Ammonia Vapor Diffusion under Ultrasonic Irradiation[J].Industrial & Engineering Chemistry Research,20116(6):3534-3539. |
[9] | Wenling Li;Hao Liu;Jingyan Xu;Peng Zang;Qian Liu;Wenbo Li.Regioselective Biomimetic Oxidative Cyclization Strategy for the Synthesis of Aryldihydronaphthalene Lignans[J].European journal of organic chemistry,201416(16):3475-3482. |
[10] | Wan-Kuen Jo;Hyun-Jung Kang.Titanium dioxide-graphene oxide composites with different ratios supported by Pyrex tube for photocatalysis of toxic aromatic vapors[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2013:115-121. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%