采用水热法合成了Na_5[B_2P_3O_(13)](NBP)和BaAlBO_3F_2(BABF),确定了合成NBP的最佳反应条件,确立并分析了合成纯相BABF时反应物浓度的适宜配比及其对产物的影响.同时对合成的NBP和BABF进行了XRD、SEM及倍频效应等性质的表征.
Na_5[B_2P_3O_(13)](NBP)and BaAlBO_3F_2(BABF)nonlinear optical crystals have been synthesized by hydrothermal method, the moderate reaction conditions have also been determined. The feasible initial charging ratio has been investigated in order to fabricate pure BABF. The as-synthesized NBP and BABF are characterized by XRD, SEM and second harmornic generation effect measurement, respectively.
参考文献
| [1] | Li Z H;Wu Y C;Fu P Z et al.Crystal Growth of Na_5[B_2P_3O_(13)][J].Chemistry Letters,2002,6:560. |
| [2] | Hu Z G;Yoshimura M;Muramatsu K et al.A New Nonlinear Optical Crystal-BaAlBO_3F_2(BABF)[J].Jpn J Appl Phsy,2002,41:L1131-L1133. |
| [3] | 李志华 .新型深紫外非线性光学晶体的探索和晶体生长的研究[D].北京:中国科学院研究生院,2003. |
| [4] | 侯碧辉,王雅丽,吴以成,陈华,汪力,傅佩珍,刘凤艳.5种硼酸盐单晶的THz光谱[J].科学通报,2007(16):1970-1972. |
| [5] | Zhihua Li;Yicheng Wu;Peizhen Fu;Shilie Pan;Zheshuai Lin;Chuangtian Chen .Czochralski crystal growth and properties of Na_5[B_2P_3O_(13)][J].Journal of Crystal Growth,2003(1/2):119-122. |
| [6] | 李志华,傅佩珍,吴以成,陈创天.Na5[B2P3O13]晶体双晶结构的研究[J].人工晶体学报,2003(06):644-647. |
| [7] | Hu ZG;Yoshimura M;Mori Y;Sasaki T .Design and growth of new NLO crystals for UV light generation[J].Journal of Crystal Growth,2005(1/2):232-239. |
| [8] | Hu Z G;Masashi Y;Yusuke M et al.Growth of a New Nonlinear Aptical Crystal-BaAlBO_3F_2[J].Journal of Crystal Growth,2004,260(3-4):287-290. |
| [9] | 李云阁,吴以成,纪丽娜,傅佩珍,胡章贵.BaAlBO3F2晶体的生长与形貌[J].硅酸盐学报,2005(08):954-958. |
| [10] | Yue YC;Hu ZG;Chen CT .Flux growth of BaAlBO3F2 crystals[J].Journal of Crystal Growth,2008(6):1264-1267. |
| [11] | Hauf C.;Kizilyalli M.;Kniep R.;Yilmaz A. .Borophosphates: Hydrothermal and microwave-assisted synthesis of Na-5[B2P3O13][J].International Journal of Quantum Chemistry,1998(1):154-156. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%