通过两相界面反应制备出小尺寸银纳米颗粒,用喷墨打印技术和热处理工艺在柔性PET基材表面制备导电薄膜.用紫外-可见光吸收光谱、透射电镜和能谱研究了银颗粒粒径、微结构和成分,结果表明所合成的颗粒为多晶结构,粒径为2~5nm.用扫描电镜和四探针薄膜电阻率测量法研究了热处理温度、时间与薄膜形貌、电阻率之间的关系,结果表明柔性PET塑料表面的银颗粒在150℃条件下处理30min,可获得表面平整、无明显裂纹、电阻率~6.4μΩ·cm的导电薄膜.
参考文献
[1] | E.Menard;K.J.Lee;D.-Y.Khang;R.G.Nuzzo,J.A.Rogers .A printable form of silicon for high performance thin film transistors on plastic substrates[J].Applied Physics Letters,2004,84(26):5398-5400. |
[2] | Andres, C.M.;Kotov, N.A. .Inkjet deposition of layer-by-layer assembled films[J].Journal of the American Chemical Society,2010(41):14496-14502. |
[3] | 何军,李莎,王虹,邹竞.羧甲基纤维素钠对纳米银导电墨水性能的影响[J].化学工业与工程,2012(04):1-5. |
[4] | 钟发春,刘兰,郑敏侠,王晓川,张晓华.甲磺酸掺杂聚苯胺的制备和表征[J].材料科学与工程学报,2009(01):28-31. |
[5] | Perelaer J;de Gans BJ;Schubert US .Ink-jet printing and microwave sintering of conductive silver tracks[J].Advanced Materials,2006(16):2101-2104. |
[6] | K.Murata.Proceedings of the international conference on MEMS,NANO and smart systems[M].Banff,Alberta,Canada,2003:346-349. |
[7] | N.Zhao;M.Chiesa;H.Sirringhaus et al.Self-aligned inkjet printing of highly conducting gold electrodes with submicron resolution[J].Journal of Applied Physics,2007,101:064513. |
[8] | V.Subramanian;J.B.Chang;A.de la Fuente.Printed electronics for low-cost electronic systems:Technology status and application development[A]. |
[9] | Jai Joon Lee;Jin Chul Park;Min Hwan Kim .Silver complex inks for ink-jet printing: the synthesis and conversion to a metallic particulate ink[J].Journal of Ceramic Processing Research. (Text in English),2007(3):219-223. |
[10] | Madhusudan Singh;Hanna M. Haverinen;Parul Dhagat;Ghassan E. Jabbour .Inkjet Printing-Process and Its Applications[J].Advanced Materials,2010(6):673-685. |
[11] | H.Pan;S.H.Ko;C.P.Grigoropoulos .Thermal sintering of solution-deposited nanoparticle silver ink films characterized by spectroscopic ellipsometry[J].Applied Physics Letters,2008,93:234104. |
[12] | Z.Yang;Vestal NY;H.Wang;Potomac MD,Z.Xu,Houghton MI .Nanoparticles,methods of making and applications using same[P].US Patent:US 7850933B2 |
[13] | Lin XZ.;Teng XW.;Yang H. .Direct synthesis of narrowly dispersed silver nanoparticles using a single-source precursor[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(24):10081-10085. |
[14] | 王晨,古宏晨.金、银纳米粒子包覆核壳结构微球的制备与研究进展[J].材料科学与工程学报,2011(06):958-964. |
[15] | 卞亓,林健,覃爽,夏朝晖,马丽娜,李东卫.玻璃基片中银纳米晶图形电场诱导热转印[J].材料科学与工程学报,2009(01):54-57,61. |
[16] | 赖文忠,肖旺钏,蔡红茹,李星国.一步法合成富勒烯[60]-纳米银复合物[J].材料科学与工程学报,2010(04):486-489,485. |
[17] | Yamamoto M;Kashiwagi Y;Nakamoto M .Size-controlled synthesis of monodispersed silver nanoparticles capped by long-chain alkyl carboxylates from silver carboxylate and tertiary amine[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(20):8581-8586. |
[18] | Q.Jiang;S.Zhang;M.Zhao .Size-dependent melting point of noble metalsMater[J].Chem & Phys,2003,82:225-227. |
[19] | Ph.Buffat;J-P.Borel .Size effect on the melting temperature of gold particles[J].Physical Review A,1976,13:2287-2298. |
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