针对微孔发泡气泡非等温长大过程,以PS/C02系统为例,考虑了温度对聚合物流变性质、亨利常数、扩散系数、表面张力的影响,基于细胞模型建立气泡非等温长大问题的数学模型,研究非等温条件下气泡长大情况的变化和不同工艺参数对气泡长大的影响.结果表明:冷却过程中亨利系数的增大和扩散系数的减小是导致气泡长大速度降低的主要因素;增加冷却速度是获得具有高密度、小尺寸泡孔形态微孔塑料的有效手段.这为微孔发泡气泡长大过程的控制提供了一定的理论依据.
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