采用熔体发泡法制备孔隙率为71.5%~72.5%、孔结构均匀的泡沫Al-0.2Sc-0.17Zr合金.研究孔结构、胞壁显微组织以及等时时效对其压缩和能量吸收性能的影响.结果表明:泡沫铝合金的孔径约为1 mm,且多呈球形;初生Al3(Zr,Sc,Ti)相具有层状结构,并能有效细化铸态晶粒(尺寸约为50 μm);在200~600℃等时时效过程中,泡沫试样的压缩性能随温度升高呈现先升高后下降的趋势,325和425℃分别表现出由Sc和Zr大量析出引起的两个明显的强度峰;时效至425℃时试样的能量吸收能力最强,且峰值时效附近的试样能量吸收效率均得到提高,高效阶段更持久;TEM实验结果表明,时效至425℃的泡沫铝试样胞壁中弥散分布着大量细小、共格的二次Al3(Sc,Zr,Ti)相,其粒径为2.1~4.1 nm,这些相能钉扎晶界,阻碍位错运动,因而能显著提高泡沫铝合金的压缩和吸能性能.
参考文献
[1] | ASHBY M F;EVANS A G.Metal foams:A design guide[M].Boston:B-H Press,2000 |
[2] | BANHART J .Manufacture,characterization and application of cellular metal and metal foams[J].Progress in Materials Science,2001,46(06):559-632. |
[3] | Evans AG.;Hutchinson JW.;Ashby MF. .Multifunctionality of cellular metal systems [Review][J].Progress in materials science,1998(3):171-221. |
[4] | 范雪柳,陈祥,刘兴男,李言祥.吹气法制备泡沫铝的性能[J].中国有色金属学报,2011(06):1320-1327. |
[5] | DEGISCHER H P;KRISZT B.Handbook of cellular metals:production,processing,application[M].New Jersey:Wiley-VCH,2002 |
[6] | Li Huang;Hui Wang;Donghui Yang.Effects of scandium additions on mechanical properties of cellular Al-based foams[J].Intermetallics,2012:71-76. |
[7] | 尉海军,李兵,郭志强,姚广春.Al基和Al-6Si基闭孔泡沫铝的动态压缩性能[J].中国有色金属学报,2007(05):704-709. |
[8] | 刘欢,姚广春,曹卓坤,华中胜,史建超.泡沫铝表面镀镍及其性能[J].中国有色金属学报,2012(09):2572-2577. |
[9] | D.H. Yang;B.Y. Hur;D.P. He .Effect of decomposition properties of titanium hydride on the foaming process and pore structures of Al alloy melt foam[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(0):415-426. |
[10] | 王辉,周向阳,龙波,文康,李劼,蒋良兴,赖延清.渗流铸造法制备的开孔泡沫铝的声学性能[J].中国有色金属学报,2013(04):1034-1039. |
[11] | HE Yong-dong,ZHANG Xin-ming,YOU Jiang-hai.Effect of minor Sc and Zr on microstructure and mechanical properties of Al-Zn-Mg-Cu alloy[J].中国有色金属学会会刊(英文版),2006(05):1228-1235. |
[12] | 戴晓元,夏长清,龙春光,寇莉莉.Al-Zn-Mg-Cu-Zr-Sc合金铸态A13(Sc,Zr)相形貌的研究[J].稀有金属材料与工程,2011(02):265-268. |
[13] | ROYSET J;RYUM N .Scandium in aluminum alloys[J].International Materials Reviews,2005,50(01):19-44. |
[14] | Keith E. Knipling;David N. Seidman;David C. Dunand .Ambient- and high-temperature mechanical properties of isochronally aged Al-0.06Sc, Al-0.06Zr and Al-0.06Sc-0.06Zr (at.%) alloys[J].Acta materialia,2011(3):943-954. |
[15] | Keith E. Knipling;Richard A. Karnesky;Constance P. Lee;David C. Dunand;David N. Seidman .Precipitation evolution in Al-0.1Sc, Al-0.1 Zr and Al-0.1Sc-0.1Zr (at.%) alloys during isochronal aging[J].Acta materialia,2010(15):5184-5195. |
[16] | BOOTH-MORRISO C;DUNAND D C;SEIDMAN D N .Coarsening resistance at 400 ℃ of precipitation-strengthened Al-Zr-Sc-Er alloys[J].Acta Materialia,2011,59(18):7029-7042. |
[17] | DALEN M E;DUNAND D C;SEIDMAN D N .Creep-and coarsening properties of Al-0.06at.%Sc-0.06at.%Ti at 300-450 ℃[J].Acta Materialia,2008,56(16):4369-4377. |
[18] | Marsha E. van Dalen;David C. Dimand;David N. Seidman .Effects of Ti additions on the nanostructure and creep properties of precipitation-strengthened Al-Sc alloys[J].Acta materialia,2005(15):4225-4235. |
[19] | KNIPLING K E;DUNAND D C;SEIDMAN D N .Precipitation evolution in Al-Zr and Al-Zr-Ti alloys during isothermal aging at 375-425 ℃[J].Acta Materialia,2008,56(01):114-127. |
[20] | KNIPLING K E;DUNAND D C;SEIDMAN D N .Precipitation evolution in Al-Zr and Al-Zr-Ti alloys during aging at 450-600 ℃[J].Acta Materialia,2008,56(06):1182-1195. |
[21] | B. Forbord;W. Lefebvre;F. Danoix;H. Hallem;K. Marthinsen .Three dimensional atom probe investigation on the formation of Al_3(Sc,Zr)-dispersoids in aluminium alloys[J].Scripta materialia,2004(4):333-337. |
[22] | A. Tolley;V. Radmilovic;U. Dahmen .Segregation in Al_3(Sc,Zr) precipitates in Al-Sc-Zr alloys[J].Scripta materialia,2005(7):621-625. |
[23] | Yang, DH;Yang, SR;Ma, AB;Jiang, JH .Compression properties of cellular AlCu5Mn alloy foams with wide range of porosity[J].Journal of Materials Science,2009(20):5552-5556. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%