通过水热结合热处理法制备了N掺杂和未掺杂的表面粗糙的TiO2微球.结果表明,N掺杂将TiQ2微球的光谱吸收范围拓宽到了可见光区,光谱吸收能力增强和氧空位增多是提高TiO2微球光催化活性的主要积极因素,结晶度下降和孤立的N2p能级对光生载流子的捕获起着次要的负面作用.
参考文献
[1] | Asahi R;Morikawa T;Ohwaki T et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,392(5528):269. |
[2] | Li D;Haneda H J .Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition[J].Journal of Photochemistry and Photobiology A:Chemistry,2003,155(1-3):171. |
[3] | Asako Kasahara;Kota Nukumizu;Go Hitoki;Tsuyoshi Takata;Junko N. Kondo;Michikazu Hara;Hisayoshi Kobayashi;Kazunari Domen .Photoreactions on LaTiO_2N under Visible Light Irradiation[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2002(29):6750-6753. |
[4] | Trevor Douglas .A Bright Bio-Inspired Future[J].Science,2003(5610):1192-1193. |
[5] | Mills A;Hunte S L .An overview of semi-conductor photocatalysis[J].Journal of Photochemistry and Photobiology A:Chemistry,1997,108(01):1. |
[6] | KE DAI;TIANYOU PENG;HAO CHEN .Photocatalytic Degradation of Commercial Phoxim over La-Doped TiO2 Nanoparticles in Aqueous Suspension[J].Environmental Science & Technology: ES&T,2009(5):1540-1545. |
[7] | Strategies of making TiO_2 and ZnO visible light active[J].Journal of hazardous materials,2009(2/3):560. |
[8] | Im, J.S.;Yun, S.-M.;Lee, Y.-S. .Investigation of multielemental catalysts based on decreasing the band gap of titania for enhanced visible light photocatalysis[J].Journal of Colloid and Interface Science,2009(1):183-188. |
[9] | Wang Y W;Huang Y et al.Biomolecule-controlled hydrothermal synthesis of C-N-S-tridoped TiO2 nanocrystalline photocatalysts for NO removal under simulated solar light irradiation[J].Journal of Hazardous Materials,2009,169(1-3):77. |
[10] | Tianzhong Tong;Jinlong Zhang;Baozhu Tian;Feng Chen;Dannong He .Preparation of Fe~(3+)-doped TiO_2 catalysts by controlled hydrolysis of titanium alkoxide and study on their photocatalytic activity for methyl orange degradation[J].Journal of hazardous materials,2008(3):572-579. |
[11] | Chambers SA;Cheung SH;Shutthanandan V;Thevuthasan S;Bowman MK;Joly AG .Properties of structurally excellent N-doped TiO2 rutile[J].Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature,2007(1-3):43-56. |
[12] | Irie H;Watanabe Y;Hashimoto K .Nitrogen-concentration dependence on photocatalytic activity of TiO2-xOx powders[J].Journal of Physical Chemistry B,2003,107(23):5483. |
[13] | Horikawa T;Katoh M;Tomida T .Preparation and characterization of nitrogen-doped rnesoporous titania with high specific surface areas[J].Microporous and Mesoporous Materials,2008,110(2-3):397. |
[14] | Cong Y;Zhang J;Chen F et al.Synthesis and characterization of nitrogen-doped TiO2 nsnophotocatalysts with high visible light activity[J].Journal of Physical Chemistry C,2007,111(19):6976. |
[15] | Horst Kisch;Shanmugasundaram Sakthivel;Marcin Janczarek;Dariusz Mitoraj .A Low-Band Gap, Nitrogen-Modified Titania Visible-Light Photocatalyst[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(30):11445-11449. |
[16] | Jinwen L;Rong H;Yen Z et al.Enhanced photoactivity of V-N codoped TiO2 derived from a two-step hydrothermal procedure for the degradation of PCP-Na under visible light irradiation[J].Journal of Physical Chemistry C,2011,115(11):4507. |
[17] | C. Di Valentin;E. Finazzi;G. Pacchioni .Density Functional Theory and Electron Paramagnetic Resonance Study on the Effect of N-F Codoping of TiO2[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(11):3706-3714. |
[18] | Livraghi S;Paganini MC;Giamello E;Selloni A;Di Valentin C;Pacchioni G .Origin of photoactivity of nitrogen-doped titanium dioxide under visible light[J].Journal of the American Chemical Society,2006(49):15666-15671. |
[19] | Li, D;Haneda, H;Hishita, S;Ohashi, N .Visible-light-driven N-F-codoped TiO2 photocatalysts. 2. Optical characterization, photocatalysis, and potential application to air purification[J].Chemistry of Materials,2005(10):2596-2602. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%