在总结具有光催化功能的无机半导体材料发展概况的基础上,综述了使用典型无机半导体材料,包括TiO2、ZnO和CdS,进行光引发高分子聚合反应的研究概况.并指出了目前对无机半导体光引发聚合反应的研究所存在的几个主要问题:只研究了少数具有紫外引发活性的无机半导体的引发反应;无机半导体引发剂的使用方式单一;聚合单体、聚合反应类型有待进一步扩展研究.最后针对这些问题提出了几点建议,并预言了其潜在的应用.
参考文献
| [1] | 潘祖仁.高分子化学[M].北京:化学工业出版社,1997 |
| [2] | Rajeshwar K;Chenthamarakshan C R .Semiconductorbased composite materials:preparation,properties,and performance[J].CHEMISTRY OF MATERIALS,2001,13:2765. |
| [3] | Hagfeldt A;Gratzel M .Light-induced redox reactions in nanocrystalline systems[J].Chemical Reviews,1995,95:49. |
| [4] | Fox M A;Dulay M T .Heterogeneous photocatalysis[J].Chemical Reviews,1995,83:341. |
| [5] | 高濂;郑珊;张青红.纳米氧化钛光催化材料及应用[M].北京:化学工业出版社,2002 |
| [6] | Asahi R;Morikawa T;Ohwaki T et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293(5528):269. |
| [7] | Mrowetz M;Balcerski W;Colussi A J et al.Oxidative power of nitrogen-doped TiO2 photocatalysts under visible illumination[J].Journal of Physical Chemistry B,2004,108(45):17269. |
| [8] | Irie H;Watanabe Y;Hashimoto K .Nitrogen-concentration dependence on photocatalytic activity of TiO2-xNx powders[J].Journal of Physical Chemistry B,2003,107:5483. |
| [9] | Kuriacose J C;Markham M C .Mechanism of the photo-initiated polymerization of methyl methacrylate at zinc oxide surface[J].Journal of Physical Chemistry,1961,65(12):2332. |
| [10] | Kraeutler B;Reiche H;Bard A J .Initiation of free radical polymerization by heterogeneous photocatalysis at semiconductor powders[J].Journal of Polymer Science Part C:Polymer Letters,1979,17(08):535. |
| [11] | Kamat P V;Basheer R A;Fox M A .Polymer-modified electrodes.electrochemical and photoelectrochemical polymerization of 1-vinylpyrene[J].Macromolecules,1985,18(07):1366. |
| [12] | Kamat P V;Todesco R V .Photoelectrochemistry in particulate systems.5.visible light-induced polymerization of 1-vinylpyrene in semiconductor suspensions[J].Journal of Polymer Science Part A:Polymer Chemistry,1987,25(04):1035. |
| [13] | Yoneyama H;Kitayama M .Relationship between electron sensitivity and chemical structures of polymers as EB resists:Poly(lactam thioether) as new positive EB resists[J].Polymer Engineering and Science,1986,26(10):653. |
| [14] | Yoneyama H;Kawai K;Kuwabata S .Electrochemical synthesis of polypyrrole films containing TiO2 powder particles[J].Journal of the Electrochemical Society,1990,137(06):1793. |
| [15] | Funt B L;Tan S R .Photoelectrochemical initiation of polymerization of styrene[J].Journal of Polymer Science Part A:Polymer Chemistry,1984,22(03):605. |
| [16] | Tada H;Hyodo M;Kawahara H .Photoinduced polymerization of 1,3,5,7-Tetramethylcyclotetraslloxane by TiO2particles[J].Journal of Physical Chemistry,1991,95:10185. |
| [17] | Hoffman A J;Yee H;Mills G et al.Photoinitiated polymerization of methacrylate using Q-sized ZnO colloids[J].Journal of Physical Chemistry,1992,96:5540. |
| [18] | Hoffman A J;Mills G;Yee H et al.Q-sized CdS:synthesis,characterization,and efficiency of photoinitiated of polymerization of several vinylic monomers[J].Journal of Physical Chemistry,1992,96:5546. |
| [19] | Huang Z Y;Barber T;Mills G et al.Heterogeneous photopolymerization of methyl metbacrylate initiated by small ZnO particles[J].Journal of Physical Chemistry,1994,98:12746. |
| [20] | 曲济方,张生万,宋晋虎,黄巍.TiO2/Na2SO3体系中日光催化聚合甲基丙烯酸甲酯的研究[J].高分子学报,2001(05):656-659. |
| [21] | 毛树红,方莉,曲济方.PMMA的聚合新方法[J].国外建材科技,2004(04):95-96,107. |
| [22] | 赵北征;李绍英;李铁山 等.高活性UV固化树脂的研究[J].河北轻化工学院学报,1998,19(44):70. |
| [23] | Farmer SC.;Patten TE. .Photoluminescent polymer/quantum dot composite nanoparticles[J].Chemistry of Materials,2001(11):3920-3926. |
| [24] | Zhang M.;Gao G.;Li CQ.;Liu FQ. .Titania-coated polystyrene hybrid microballs prepared with miniemulsion polymerization[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(4):1420-1424. |
| [25] | Yu Shuhong;Yoshimura M;Fujiwara T et al.In situ fabrication and optical properties of a novel polystyrene/semiconductor nanocomposite embedded with CdS nanowires by a soft solution processing route[J].Langmuir,2001,17:1700. |
| [26] | 姚超,丁永红,林西平,杨绪杰,陆路德,汪信.纳米TiO2有机表面改性的研究[J].无机化学学报,2005(05):638-642. |
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