采用粉末冶金工艺制备了高温稀土永磁Sm(CobalFexCu0.1Zr0.03)7.5 (x=0.09~0.21),研究了Fe含量对磁体磁性能的影响.结果表明:随着Fe含量的增加,剩磁Br和最大磁能积(BH)max逐渐增加,在x=0.21时获得最大值,分别为0.96 T和176.7 kJ/m3;内禀矫顽力Hci先增加后降低,在x=0.15时获得峰值2276.6 kA/m.最佳工艺制备(x=0.15)的磁体温度稳定性良好,B-H退磁曲线在温度为500 ℃时保持为直线;内禀矫顽力温度系数β为-0.16%/℃,最高使用温度(OT)max达到533 ℃.
The influence of Fe content on magnetic properties of high temperature rare earth permanent magnets Sm(CobalFexCu0.1Zr0.03)7.5 (x=0.09~0.21), prepared by the conventional powder metallurgy method, has been studied. The results show that: with increasing of Fe content, Br and (BH)max increased, the optimum value of Br and (BH)max reached to 0.96 T and 176.7 kJ/m3 while x=0.21; Hci increased first, then decreased with further increasing of Fe content; the optimum value of Hci reached to 2276.6 kA/m while x=0.15. The temperature stability of the magnet with x=0.15, prepared by optimum process, has been proved to be excellent, and the B-H demagnetization curve kept a straight line at 500 ℃; the intrinsic coercivity coefficient β was -0.16%/℃, and the maximum operating temperature was to 533 ℃.
参考文献
[1] | Liu S.;Kuhl G.E. .Temperature coefficients of rare earth permanent magnets[J].IEEE Transactions on Magnetics,1999(5):3271-3273. |
[2] | Liu S et al.[J].IEEE Transactions on Magnetics,1999,35(05):3325. |
[3] | Kim AS. .DESIGN OF HIGH TEMPERATURE PERMANENT MAGNETS[J].Journal of Applied Physics,1997(8 Pt.2b):5609-5611. |
[4] | Ma B.M.;Liang Y.L. .The effect of Fe on the temperature dependent magnetic properties of Sm(Co,Fe,Cu,Zr)/sub z/ and SmCo/sub 5/ sintered magnets at 450/spl deg/C[J].IEEE Transactions on Magnetics,1996(5):4377-4379. |
[5] | Liu J.F.;Ding Y.;Hadjipanayis G.C. .Effect of iron on the high temperature magnetic properties and microstructure of Sm(Co, Fe, Cu, Zr)_z permanent magnets[J].Journal of Applied Physics,1999(3):1670-0. |
[6] | 郭朝晖,李卫.Sm(CobalFexCu0.088Zr0.025)7.5(x=0-0.30)烧结永磁体的磁性及其高温特性[J].金属学报,2002(08):866-870. |
[7] | 彭龙,徐光亮,张明.烧结Sm(Co,Fe,Cu,Zr)z的矫顽力机制及其影响因素[J].材料导报,2006(07):38-42. |
[8] | Cataldo L et al.[J].Journal Alloys Compound,1996,241:216. |
[9] | Rong C B et al.[J].Journal of Applied Physics,2004,95(03):1351. |
[10] | Nagel H .[J].Journal of Applied Physics,1979,50(02):1026. |
[11] | 郭朝晖,潘伟,李岫梅,胡新建,秦英,李卫.2∶17型Sm-Co高温永磁体的研究[J].稀有金属,2003(05):552-554. |
[12] | 周寿增.稀土永磁材料及其应用[M].北京:冶金工业出版社,1995:158. |
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