颗粒溶胶路线制备陶瓷膜是一种不使用有机溶剂的清洁工艺.以仲丁醇铝为前驱体,采用水作溶剂,调节pH为3～4,通过颗粒溶胶路线制备了平均粒径为16 nm稳定的勃姆石溶胶.通过浸浆法,在α-Al2O3微滤底膜上制备γ-Al2O3纳滤膜,并考察了热处理过程及涂膜时间的影响.控制涂膜时间为60 s,烧结温度为600℃,所制备的γ-Al2O3纳滤膜膜层厚度约为1.8μm,对PEG的截留分子量约1 000 Da,计算孔径为1.6 nm,其纯水通量约为20 L/(m2 h)(0.1 MPa).采用颗粒溶胶路线适合制备γ-Al2O3纳滤膜.
参考文献
| [1] | Pabby A K;Rizvi S S H;Sastre A M.Handbook of membrane separation:chemical pharmaceutical,food,and biotechnological applications[M].New York:CRC Press,2008 |
| [2] | Drioli E;Giorno L.Comprehensive membrane science and engineering[M].Holland:Elsevier,2010 |
| [3] | S. Chakrabortty;M. Roy;P. Pal.Removal of fluoride from contaminated groundwater by cross flow nanofiltration: Transport modeling and economic evaluation[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2013:115-124. |
| [4] | S.Benfer;U.Popp;H.Richter;C.Siewert;G.Tomandl .Development and characterization of ceramic nanofiltration membranes[J].Separation and Purification Technology,2001(0):231-237. |
| [5] | Berna Topuz;MuhsinCiftcioglu .Sol-gel derived mesoporous and microporous alumina membranes[J].Journal of Sol-Gel Science and Technology,2010(3):287-299. |
| [6] | Burggraf A J;Cot L.Fundamentals of inorganic membrane science and technology[M].Elsevier,1996 |
| [7] | Sakka S.Handbook of sol-gel science and technology:processing,characterization and applications[M].Holland:Kluwer Academic Publishers,2005 |
| [8] | 漆虹,李世大,江晓骆,韩静.TiO2纳滤膜的制备及其离子截留性能[J].无机材料学报,2011(03):305-310. |
| [9] | J.SEKULIC;J.E.TEN ELSHOF;D.H.A.BLANK .Synthesis and Characterization of Microporous Titania Membranes[J].Journal of Sol-Gel Science and Technology,2004(1/3):201-204. |
| [10] | Van Gestel T;Kruidhof H;Blank DHA;Bouwmeester HJM .ZrO2 and TiO2 membranes for nanofiltration and pervaporation - Part 1. Preparation and characterization of a corrosion-resistant ZrO2 nanofiltration membrane with a MWCO < 300[J].Journal of Membrane Science,2006(1/2):128-136. |
| [11] | Larbot A;YoungD;GuizardC et al.Aluminananofiltration membrane from sol-gel process[J].Key Engineering Materials,1991,61-62:395-398. |
| [12] | Larbot A;Alami Y S;Persin M et al.Preparation of a γ-alumina nanofdtration membrane[J].Journal of Membrane Science,1994,97:167-173. |
| [13] | Batide P;Kiefer C;Lakhchaf N et al.Salt filtration on γ-Al2O3 nanofiltration membranes fired at two different temperature[J].Journal of Membrane Science,1997,135(01):1-8. |
| [14] | Schaep J;Vandecasteele C;Peeters B et al.Characteristics and retention properties of a mesoporous γ-Al2O3 membrane for nanofiltration[J].Journal of Membrane Science,1999,163(02):229-237. |
| [15] | J. Sekulic;A. Magraso;J. E. ten Elshof;D. H. A. Blank .Influence of ZrO_2 addition on microstructure and liquid permeability of mesoporous TiO_2 membranes[J].Microporous and Mesoporous Materials,2004(1/3):49-57. |
| [16] | Andreas Krell;Hongwei Ma .Performance of Alumina Membranes from New Nanosynthesis in Ultrafiltration and Nanofiltration[J].Journal of the American Ceramic Society,2003(2):241-246. |
| [17] | Zhu Jin;Fan Yiqun;Xu Nanping.Modified dip-coating method for preparation of pinhole-free ceramic membranes[J].Journal of Membrane Science,2011 |
| [18] | P.Puhlfurb;A.Voigt;R.Weber;M.Morbe .Microporous TiO_2 membranes with a cut off < 500 Da[J].Journal of Membrane Science,2000(1):123-133. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%