欢迎登录材料期刊网

材料期刊网

高级检索

分别以天然气和丙烯为前驱体制备了C/C复合材料.考察了密度和密度分布,借助偏光显微镜观察了沉积炭的显微结构,研究表明,天然气制备的C/C复合材料的密度大于丙烯制备的C/C复合材料的密度;在前60h以天然气为前驱体时C/C复合材料的致密化速率比以丙烯为前驱体时低,60h后致密化速率发生逆转;以天然气为前驱体所得C/C复合材料的密度梯度小,结构为单一的粗糙层;而以丙烯为前驱体所得C/C复合材料的密度梯度大,结构为光滑层.

参考文献

[1] 程永宏,罗瑞盈,王天民.化学气相沉积(CVD)炭/碳复合材料(C/C)研究现状[J].炭素技术,2002(05):26-32.
[2] 熊翔,汤中华,张红波,熊杰,浦继强.载气对CVI C/C材料密度和热解炭结构分布的影响[J].中国有色金属学报,2006(03):385-391.
[3] Lieberman M L;Pierson H O .Effect of gas phase conditions on resultant matrix pyrocarbons in carbon/carbon composites[J].Carbon,1974,12:233.
[4] 张福勤,黄启忠,黄伯云,巩前明,陈腾飞,熊翔.C/C复合材料结构显微激光喇曼光谱研究[J].复合材料学报,2003(03):113-117.
[5] Delhaes P .Chemical vapor deposition and infiltration pro-cess of carbon materials[J].Carbon,2002,40(05):641.
[6] 孙万昌,李贺军,白瑞成,卢锦花,黄勇.沉积温度对碳/碳复合材料密度均匀性的影响[J].硅酸盐学报,2005(06):780-783.
[7] Savage G.Carbon-carbon composites[M].London:Champ-man & Hall,1993:91.
[8] Bird R B;Stward W E;Lightfoot E N.Transport phenomena[M].New York:wiley,1960:554.
[9] W. BENZINGER;K. J. HUETTINGER .CHEMICAL VAPOUR INFILTRATION OF PYROCARBON: Ⅰ. SOME KINETIC CONSIDERATIONS[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(12):1465-1471.
[10] Becker A.;Huttinger KJ. .Chemistry and kinetics of chemical vapor deposition of pyrocarbon - IV - Pyrocarbon deposition from methane in the low temperature regime[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(3):213-224.
[11] Becker A.;Huttinger KJ. .Chemistry and kinetics of chemical vapor deposition of pyrocarbon - III - Pyrocarbon deposition from propylene and benzene in the low temperature regime[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(3):201-211.
[12] Hu ZJ.;Huttinger KJ.;Schoch G. .Chemistry and kinetics of chemical vapor infiltration of pyrocarbon - VII: infiltration of capillaries of equal size[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(7):1059-1065.
[13] Norinaga K et al.Analysis of gas phase compounds in chemical vapor deposition of carbon from light hydrocarbons[J].Carbon,2006,44:1790.
[14] Li H et al.Numerical simulation of chemical vapor infiltration of propylene into C/C composites with reduced multi-step kinetic models[J].Carbon,2005,43:2937.
[15] 李晋,崔红,李瑞珍.影响C/C复合材料中热解炭结构的工艺因素[J].炭素,2008(02):11-17.
[16] Bokros J C.Chemistry and physics of carbon[M].New York,USA:Marcel Dekker,Inc,1969
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%