以硅藻土为载体,钛酸四丁酯为前驱体,采用溶胶-凝胶法制备了F掺杂纳米TiO2/硅藻土复合光催化材料.通过X射线衍射(XRD)、扫描电子显微镜(SEM)以及紫外-可见漫反射光谱(UV-Vis DRS)等手段对材料的晶体结构、微观形貌及光学性能进行了表征.结果表明与纯TiO2相比,硅藻土显著提高了材料的吸附能力,有效抑制了催化剂纳米粒子的团聚;F掺杂量为1%时,制备的F-TiO2/硅藻土样品在可见光下对罗丹明B降解效果最好.
参考文献
[1] | Miguel Pelaez;Armah A. de la Cruz;Elias Stathatos.Visible light-activated N-F-codoped TiO2 nanoparticles for the photocatalytic degradation of microcystin-LR in water[J].Catalysis Today,20091/2(1/2):19-25. |
[2] | Yu, J.;Li, Q.;Liu, S.;Jaroniec, M..Ionic-liquid-assisted synthesis of uniform fluorinated B/C-codoped TiO 2 nanocrystals and their enhanced visible-light photocatalytic activity[J].Chemistry: A European journal,20137(7):2433-2441. |
[3] | Huihui Li;Shu Yin;Yuhua Wang.Persistent Fluorescence-Assisted TiO_(2-x)N_y-Based Photocatalyst for Gaseous Acetaldehyde Degradation[J].Environmental Science & Technology: ES&T,201214(14):7741-7745. |
[4] | Jian Zheng;Zhongqing Liu;Xu Liu.Facile hydrothermal synthesis and characteristics of B-doped TiO_2 hybrid hollow microspheres with higher photo-catalytic activity[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20119(9):3771-3776. |
[5] | 徐春宏;郑水林;张广心;孙青.均匀沉淀法制备纳米TiO2/膨胀珍珠岩复合材料[J].人工晶体学报,2014(8):1991-1997. |
[6] | 陈天虎;史晓莉;彭书传;XU Huifang;Gao Huizhen.凹凸棒石-TiO2纳米复合材料制备和表征[J].硅酸盐通报,2005(1):112-114. |
[7] | 孙颖;刘浪;贾殿赠;刘锦昊.蛭石负载TiO2光催化剂的制备与性能[J].无机化学学报,2011(1):40-46. |
[8] | 传秀云;卢先春;卢先初.负载TiO2的硅藻土对亚甲基蓝的光降解性能研究[J].无机材料学报,2008(4):657-661. |
[9] | Yu, Wei;Liu, Xinjuan;Pan, Likun;Li, Jinliang;Liu, Junying;Zhang, Jing;Li, Ping;Chen, Chen;Sun, Zhuo.Enhanced visible light photocatalytic degradation of methylene blue by F-doped TiO2[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2014Nov.15(Nov.15):107-112. |
[10] | Bin Wang;Guangxin Zhang;Zhiming Sun.Synthesis of natural porous minerals supported TiO2 nanoparticles and their photocatalytic performance towards Rhodamine B degradation[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2014:1-8. |
[11] | Xi Li;Jian Zhu;Hexing Li.Influence of crystal facets and F-modification on the photocatalytic performance of anatase TiO2[J].Catalysis Communications,2012:20-24. |
[12] | Xiaohong Li;Haidong Zhang;Xuxu Zheng;Zhongyi Yin;Le Wei.Visible light responsive N-F-codoped TiO2 photocatalysts for the degradation of 4-chlorophenol[J].环境科学学报(英文版),2011(11):1919-1924. |
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