采用常规水热合成法合成了系列MgAPO-11分子筛,考察了晶化时间、 P/Al投料比和Mg源对MgAPO-11分子筛的物相、酸性以及Pt/MgAPO-11催化正十二烷临氢异构化反应性能的影响. 分别用X射线衍射、 X射线荧光光谱和NH3程序升温脱附测定了样品的晶相、 Mg含量和酸性质. 结果表明,合成条件影响着合成产物的晶相组成、 Mg含量及酸性质,从而影响到Pt/MgAPO-11在正十二烷临氢异构化反应中的催化性能. 反应结果显示, Pt/MgAPO-11催化剂的催化活性与MgAPO-11分子筛的强酸位数目密切相关. 较短的晶化时间、合成凝胶的P/Al摩尔比为1.0以及使用Mg(NO3)2为Mg源有利于提高MgAPO-11的强酸位数目,从而提高Pt/MgAPO-11的催化活性.
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