欢迎登录材料期刊网

材料期刊网

高级检索

以酚醛树脂、BJO-0930酚醛微球为原材料,与适量蒙脱土混合,采用模压成型法制备出酚醛泡沫前驱体,在Ar气保护下进行800℃炭化处理,得到蒙脱土改性闭孔微球型炭泡沫复合材料。探讨蒙脱土对炭泡沫微观结构、压缩强度和热导率的影响。结果表明,蒙脱土改性炭泡沫复合材料的基体相与微球相结合更紧密,孔隙率降低;压缩强度提高到25.54 MPa;热导率也明显降低,800℃下的热导率降为0.588 W/(m·K)。

Montmorillonite-modified carbon foams with a closed-pore structure were prepared by compressive molding of phenolic resin, phenolic hollow microspheres and montmorillonite, followed by thermosetting and carbonization at 800℃ under Ar flow. The effects of the montmorillonite content on the microstructure, compressive strength and thermal conductivity of the modified foams were investigated. Results show that the hollow microspheres, carbon matrix and montmorillonite combine more closely in the modi-fied carbon foams than the unmodified one. Their compressive strength increases and the porosity decreases with increasing montmo-rillonite content from 0 to 7 wt.%. The highest compressive strength is 25. 54 MPa and the lowest thermal conductivity at 800℃ is 0. 588 W/(m·K) when the montmorillonite content is 7 wt.%.

参考文献

[1] Ford W .Method of making cellular refractory thermal insulating material[P].US3121050 A,1964.
[2] Klett J.High thermal conductivity mesophase pitch-derived car-bon foam[A].,1998:745-755.
[3] Nidia C. Gallego;James W. Klett .Carbon foams for thermal management[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(7):1461-1466.
[4] 曹敏,张书,王永刚.制备条件对炭泡沫结构的影响[J].新型炭材料,2005(02):134-138.
[5] Klett J .Process for making carbon foam[P].US6033506 A,2000.
[6] 李凯,栾志强.中间相沥青基炭泡沫[J].新型炭材料,2004(01):77-78.
[7] 沈曾民,戈敏,迟伟东,刘辉.中间相沥青基炭泡沫体的制备、结构及性能[J].新型炭材料,2006(03):193-201.
[8] T. -Q. Li;C. -Y. Wang;B. -X. An .Preparation of graphitic carbon foam using size-restriction method under atmospheric pressure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(9):2030-2032.
[9] Jie Yang;Zeng-min Shen;Zi-biao Hao .Microwave characteristics of sandwich composites with mesophase pitch carbon foams as core[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(8/9):1882-1885.
[10] Bruneton E;Tallaron C;Gras-Naulin N et al.Evolution of the structure and mechanical behavior of a carbon foam at very high temperatures[J].CARBON,2002,40(11):1919-1927.
[11] 田卓,李克智,李贺军,石振海.碳泡沫导热性能及力学性能研究[J].无机材料学报,2008(06):1171-1174.
[12] Luo, R.;Ni, Y.;Li, J.;Yang, C.;Wang, S. .The mechanical and thermal insulating properties of resin-derived carbon foams reinforced by K_2Ti_6O_(13) whiskers[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2011(4/5):2023-2027.
[13] Li, W.Q.;Zhang, H.B.;Xiong, X.;Xiao, F. .Influence of fiber content on the structure and properties of short carbon fiber reinforced carbon foam[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2010(27/28):7274-7278.
[14] 郭亚林,崔红,田建团,刘毅佳,滕会平.蒙脱土对炭/酚醛树脂复合材料性能的影响[J].宇航学报,2009(06):2398-2402.
[15] Xinying Wang;Jiming Zhong;Yimin Wang .A study of the properties of carbon foam reinforced by clay[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(8):1560-1564.
[16] Erwin M. Wouterson;Freddy Y.C. Boey;Xiao Hu .Specific properties and fracture toughness of syntactic foam: Effect of foam microstructures[J].Composites science and technology,2005(11/12):1840-1850.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%