采用两步氧化法制备了多孔氧化铝模板(AAO),并利用AAO结合用电化学诱导溶胶-凝胶法制备了锐钛矿型的TiO2纳米线阵列,探讨了形成TiO2纳米线阵列的生长机理.发现TiO2纳米线是由Au基底沿着孔洞逐步向上生长,直接生成纳米线,因而可以通过控制氧化铝模板的尺寸和电化学沉积的时间来控制纳米线的长径比.
参考文献
| [1] | Brinda B.Lakshmi;Peter K.Dorhout;Charles R.Martin .Sol-gel template synthesis of semiconductor nanostructures[J].Chemistry of Materials,1997(3):857-862. |
| [2] | Routkevitch D.;Tager A.A. .Nonlithographic nano-wire arrays: fabrication, physics, and device applications[J].IEEE Transactions on Electron Devices,1996(10):1646-1658. |
| [3] | Shahed U M .Khan, Tamanna Sultana Photoresponse of n-TiO2 thin film and nanowire electrodes[J].Solar Energy Materials and Solar Cells,2003,76:211. |
| [4] | Lei Y;Zhang L D et al.Preparation and photoluminescence of highly ordered TiO2 nanowire arrays[J].Applied Physics Letters,2001,78:1125. |
| [5] | Lei Y.;Fan JC.;Zhang LD. .Fabrication, characterization and Raman study of TiO2 nanowire arrays prepared by anodic oxidative hydrolysis of TiCl3[J].Chemical Physics Letters,2001(4-6):231-236. |
| [6] | Lin Y.;Wu GS.;Yuan XY.;Xie T.;Zhang LD. .Fabrication and optical properties of TiO2 nanowire arrays made by sol-gel electrophoresis deposition into anodic alumina membranes[J].Journal of Physics. Condensed Matter,2003(17):2917-2922. |
| [7] | Zheng Miao;Dongsheng Xu;Jianhua Ouyang;Guolin Guo;Xinsheng Zhao;Youqi Tang .Electrochemically Induced Sol-Gel Preparation of Single-Crystalline TiO_2 Nanowires[J].Nano letters,2002(7):717-720. |
| [8] | Masuda H;Fukuda K .[J].Science,1995,268:1446. |
| [9] | Bischoff B L;Anderson M A .Peptization process in the sol-gel preparation of porous anatase[J].Chemistry of Materials,1995,7:1772. |
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